2024 article
Width-Dependent Growth of Atomically Thin Quantum Nanoribbons
Harutyunyan, A., Li, X., Wyss, S., Yanev, E., Li, Q.-J., Wu, S., … Schuck, P. J. (2024, May 23).
open access via doi.org (repository)
Source: ORCID
Added: August 14, 2024
<title>Abstract</title> Nanoribbons (NRs) of atomic layer transition metal dichalcogenides (TMDs) can boost the rapidly emerging field of quantum materials owing to their width-dependent phases and electronic properties. However, the controllable downscaling of width by direct growth and the underlying mechanism remain elusive. Here, we demonstrate the vapor-liquid-solid growth of single crystal of single layer NRs of a series of TMDs (MeX<sub>2</sub>: Me=Mo, W; X=S, Se) under chalcogen vapor atmosphere, seeded by pre-deposited and respective transition metal-alloyed nanoparticles that also control the NR width. We found linear dependence of growth rate on supersaturation, known as a criterion for continues growth mechanism, which decreases with decreasing of NR width driven by the Gibbs-Thomson effect. The NRs show width-dependent photoluminescence and strain-induced quantum emission signatures with up to ~90% purity of single photons. We propose the path and underlying mechanism for width-controllable growth of TMD NRs for applications in quantum optoelectronics.