@article{roberts_marquez_mccutchen_haney_shin_1997, title={High-temperature slurry reactors for synthesis gas reactions .1. Liquid thermal stability}, volume={36}, ISSN={["0888-5885"]}, DOI={10.1021/ie970136e}, abstractNote={The use of slurry reactors has been limited to reactions that take place at temperatures below about 573 K because many of the liquids that have been used to suspend the solid catalyst are not stable above this temperature. The thermal stability of a number of organic liquids was evaluated at temperatures between 648 and 698 K and at H2 partial pressures of about 7 MPa. Certain saturated and partially-saturated, fused-ring compounds with no alkyl groups or bridges are quite stable at these conditions. Of the compounds tested, tetrahydronaphthalene, tetrahydroquinoline, and decahydronaphthalene were the most stable. Analysis of the liquids at the end of the thermal stability evaluation supports some speculation concerning possible degradation reactions.}, number={10}, journal={INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, author={Roberts, GW and Marquez, MA and McCutchen, MS and Haney, CA and Shin, ID}, year={1997}, month={Oct}, pages={4143–4154} }