@article{tanner_amin_kloxin_zanten_2011, title={Microviscoelasticity of soft repulsive sphere dispersions: Tracer particle microrheology of triblock copolymer micellar liquids and soft crystals}, volume={134}, ISSN={["1089-7690"]}, DOI={10.1063/1.3578183}, abstractNote={Tracer particle microrheology using diffusing wave spectroscopy-based microrheology is demonstrated to be a useful method to study the dynamics of aqueous Pluronic™ F108 solutions, which are viewed as solutions of repulsive soft spheres. The measured zero-shear microviscosity of noncrystallizing micellar dispersions indicates micelle corona dehydration upon increasing temperature. Colloidal sphere thermal motion is shown to be exquisitely sensitive to the onset of crystallization in these micellar dispersions. High temperature dynamics are dominated by an apparent soft repulsive micelle–micelle interaction potential indicating the important role played by lubrication forces and ultimately micelle corona interpenetration and compression at sufficiently high concentrations. The measured microscopic viscoelastic storage and loss moduli are qualitatively similar to those experimentally observed in mechanical measurements on colloidal dispersions and crystals, and calculated from mode coupling theory of colloidal suspensions. The observation of subdiffusive colloidal sphere thermal motion at short time-scales is strong evidence that the observed microscopic viscoelastic properties reflect the dynamics of individual micelles rather than a dispersion of micellar crystallites.}, number={17}, journal={JOURNAL OF CHEMICAL PHYSICS}, author={Tanner, Shaun A. and Amin, Samiul and Kloxin, Christopher J. and Zanten, John H.}, year={2011}, month={May} }
 @article{kloxin_zanten_2010, title={High Pressure Phase Diagram of an Aqueous PEO-PPO-PEO Triblock Copolymer System via Probe Diffusion Measurements}, volume={43}, ISSN={["1520-5835"]}, DOI={10.1021/ma902571h}, abstractNote={Phase diagrams of soft fragile materials are typically determined via static structural methods, such as small angle neutron scattering (SANS; Mortensen, K.; Pedersen, J. S. Macromolecules 1993, 26 (4), 805−812), small-angle X-ray scattering (Lodge, T. P.; Pudil, B.; Hanley, K. J. Macromolecules 2002, 35 (12), 4707−4717), or light scattering (Brown, W.; Schillen, K.; Almgren, M.; Hvidt, S.; Bahadur, P. J. Phys. Chem. 1991, 95 (4), 1850−1858). Dynamical methods, such as rheometry, can also be employed since the relaxation spectrum varies greatly from one phase to another. Unfortunately, mechanically disturbing these systems can alter the underlying fragile structures, precluding quiescent state determination. Here, a method for determining soft matter phase diagrams utilizing high-frequency tracer microrheology measurements is demonstrated for an aqueous PEO-PPO-PEO triblock copolymer system over a full range of temperatures and hydrostatic pressures. Since the tracer particle thermal motion reflects the u...}, number={4}, journal={MACROMOLECULES}, author={Kloxin, Christopher J. and Zanten, John H.}, year={2010}, month={Feb}, pages={2084–2087} }
 @article{kloxin_zanten_2009, title={Microviscoelasticity of adhesive hard sphere dispersions: Tracer particle microrheology of aqueous Pluronic L64 solutions}, volume={131}, number={13}, journal={Journal of Chemical Physics}, author={Kloxin, C. J. and Zanten, J. H.}, year={2009} }