@misc{fan_manis_magnuson_wan_2006, title={Fire and corrosion resistant thermally stable electrodes and batteries and method for manufacturing same}, volume={7,078,129}, number={2006 Jul. 18}, publisher={Washington, DC: U.S. Patent and Trademark Office}, author={Fan, J. and Manis, D. and Magnuson, D. and Wan, L. T.}, year={2006} } @misc{khan_fedkiw_baker_fan_raghavan_hou_1999, title={Composite electrolyte containing surface modified fumed silica}, volume={5,965,299}, number={1999 Oct. 12}, publisher={Washington, DC: U.S. Patent and Trademark Office}, author={Khan, S. A. and Fedkiw, P. S. and Baker, G. L. and Fan, J. and Raghavan, S. R. and Hou, J.}, year={1999}, month={Oct} } @article{fan_raghavan_yu_khan_fedkiw_hou_baker_1998, title={Composite polymer electrolytes using surface-modified fumed silicas: conductivity and rheology}, volume={111}, ISSN={["0167-2738"]}, DOI={10.1016/S0167-2738(98)00151-9}, abstractNote={We report results from our studies on composite polymer electrolytes based on novel surface-modified fumed silicas. The electrolytes were prepared by dispersing fumed silica in a matrix formed by methyl-capped polyethylene glycol and lithium salt. Silicas with widely different surface chemistries were synthesized in order to study the effects of surface modification, with the attached surface groups ranging from non-polar alkyl moieties (C1 or C8) to polar polyethylene oxide (PEO) oligomers (MW∼200). We find, rather surprisingly, that the conductivity is independent of the type of surface group present on the silica. Moreover, the conductivity decreases only slightly on addition of fumed silica, even at high weight fraction of solids. In contrast, the rheological properties of the composites are strongly affected by both the silica surface chemistry and weight fraction. Dynamic rheology measurements reveal that fumed silicas with silanol and octyl coverage both flocculate into gels (networks). The resulting materials are mechanically stable, with the elastic modulus of the gel being strongly dependent upon weight fraction of solids. The PEO-modified silica, in contrast, gives rise to a low-viscosity suspension where the silica units exist as distinct, non-interacting species. The findings of this study have significant implications for future work on composite electrolytes, in that we can tailor the mechanical properties of the system without affecting the electrochemical behavior.}, number={1-2}, journal={SOLID STATE IONICS}, author={Fan, J and Raghavan, SR and Yu, XY and Khan, SA and Fedkiw, PS and Hou, J and Baker, GL}, year={1998}, month={Aug}, pages={117–123} } @article{fan_fedkiw_1998, title={Electrochemical impedance spectra of full cells: Relation to capacity and capacity-rate of rechargeable Li cells using LiCoO2, LiMn2O4, and LiNiO2 cathodes}, volume={72}, ISSN={["0378-7753"]}, DOI={10.1016/S0378-7753(97)02708-0}, abstractNote={Electrochemical impedance spectra (EIS) are reported for rechargeable lithium cells using cathodes LiMyOx (M=Co, Ni, and Mn) prepared from casting and high-pressure compacting. The composite cathodes were cast from a slurry mixture consisting of 30% NMP solvent and 70% solid (91% LiMyOx, 3% PVDF and 6% KS44 graphite) onto a 25-μm thick Al current collector. The compacted cathodes were made from the cast cathode using a laboratory press. The most compacted cathodes have the smallest impedance and the highest specific capacity and capacity-rate. Three equivalent circuits are proposed according to the effect of compaction pressure on our EIS results and work reported in the literature. The EIS results and relationship to the capacity and capacity-rate are discussed using these circuits. It appears that the ohmic resistance of the composite cathode is an important factor in the overall resistance of the cell and unfavorably affects the performance (capacity and capacity-rate) of the cathode.}, number={2}, journal={JOURNAL OF POWER SOURCES}, author={Fan, J and Fedkiw, PS}, year={1998}, month={Apr}, pages={165–173} }