2011 article

Overcoming challenges in the palladium-catalyzed synthesis of electron deficient ortho-substituted aryl acetonitriles

Brannock, M. C., Behof, W. J., Morrison, G., & Gorman, C. B. (2011, January 1). Organic & Biomolecular Chemistry, Vol. 9, pp. 2661–2666.

By: M. Brannock n, W. Behof n, G. Morrison n & C. Gorman n

Contributors: M. Brannock n, W. Behof n, G. Morrison n & C. Gorman n

topics (OpenAlex): Catalytic Cross-Coupling Reactions; Sulfur-Based Synthesis Techniques
TL;DR: Highly electron deficient monoaryl, di-aryl and bis-diaryl acetonitriles were effectively synthesized using either a nucleophilic aromatic substitution (NAS) or a palladium-mediated coupling pathway, indicating the sensitivity of the reaction to steric and ligand electronic effects. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2010 article

Cascade Cyclization To Produce a Series of Fused, Aromatic Molecules

Behof, W. J., Wang, D., Niu, W., & Gorman, C. B. (2010, April 8). Organic Letters, Vol. 12, pp. 2146–2148.

By: W. Behof n, D. Wang n, W. Niu n & C. Gorman n

Contributors: W. Behof n, D. Wang n, W. Niu n & C. Gorman n

MeSH headings : Aza Compounds / chemistry; Cyclization; Hydrogen Bonding; Models, Molecular; Nitrogen / chemistry; Spectrum Analysis / methods
topics (OpenAlex): Supramolecular Chemistry and Complexes; Chemical Reaction Mechanisms; Synthesis and Properties of Aromatic Compounds
TL;DR: An efficient synthesis of fully aromatic, fused-ring, monoaza-acenes through a nucleophile initiated cascading cyclization is illustrated and Photophysical properties of the resulting molecules are reported. (via Semantic Scholar)
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Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

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