Roger M. Sullivan

Works (4)

Updated: July 5th, 2023 16:02

2006 journal article

Sorptive reconstruction of CuMCl4 (M = Al and Ga) upon small-molecule binding and the competitive binding of CO and ethylene

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(41), 13463–13473.

By: M. Capracotta n, R. Sullivan n & J. Martin n 

Contributors: M. Capracotta n, R. Sullivan n & J. Martin n 

TL;DR: Comparison of the reactivity of CO and ethylene with these CuMCl(4) materials, as well as other copper(I) halide compounds that exhibit classical and nonclassical modes of bonding, demonstrates the ability to tune the reactsivity of the crystalline frameworks with selectivity for carbon monoxide or olefins, respectively. (via Semantic Scholar)
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Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2003 journal article

Sorptive reconstruction of the CuAlCl4 framework upon reversible ethylene binding

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(36), 11065–11079.

By: R. Sullivan n, H. Liu  n, D. Smith n, J. Hanson  n, D. Osterhout n, M. Ciraolo n, C. Grey  n, J. Martin n 

Contributors: R. Sullivan n, H. Liu  n, D. Smith n, J. Hanson  n, D. Osterhout n, M. Ciraolo n, C. Grey  n, J. Martin n 

TL;DR: Three ethylene adducts to CuAlCl(4) have been characterized by single crystal and/or powder X-ray diffraction, (13)C, (27)Al and (63)Cu MAS NMR and diffuse reflectance UV-vis spectroscopy, providing an atomistic picture of the sorptive reconstruction reactions. (via Semantic Scholar)
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Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2001 journal article

Kinetics and mechanism of the beta- to alpha-CuAlCl4 phase transition: A time-resolved Cu-63 MAS NMR and powder X-ray diffraction study

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 123(31), 7564–7573.

By: H. Liu  n, R. Sullivan n, J. Hanson  n, C. Grey  n & J. Martin n 

Contributors: H. Liu  n, R. Sullivan n, J. Hanson  n, C. Grey  n & J. Martin n 

TL;DR: A one-dimensional growth mechanism is proposed that involves a combination of Cu(+) ion self-diffusion and a translational reorganization of the close-packed anion layers imposed by the periodic rotations of [AlCl(4)](-) tetrahedra. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

1999 journal article

An illuminating framework: Understanding the photoluminescence of alpha-CuAlCl4

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 121(43), 10092–10097.

By: R. Sullivan n & J. Martin n 

Contributors: R. Sullivan n & J. Martin n 

UN Sustainable Development Goals Color Wheel
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

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