Roger M. Sullivan

Works (4)

Updated: July 5th, 2023 16:02

2006 article

Sorptive Reconstruction of CuMCl4 (M = Al and Ga) upon Small-Molecule Binding and the Competitive Binding of CO and Ethylene

Capracotta, M. D., Sullivan, R. M., & Martin, J. D. (2006, September 15). Journal of the American Chemical Society, Vol. 128, pp. 13463–13473.

By: M. Capracotta n, R. Sullivan n & J. Martin n 

Contributors: M. Capracotta n, R. Sullivan n & J. Martin n 

topics (OpenAlex): Metal-Organic Frameworks: Synthesis and Applications; Ionic liquids properties and applications; Machine Learning in Materials Science
TL;DR: Comparison of the reactivity of CO and ethylene with these CuMCl(4) materials, as well as other copper(I) halide compounds that exhibit classical and nonclassical modes of bonding, demonstrates the ability to tune the reactsivity of the crystalline frameworks with selectivity for carbon monoxide or olefins, respectively. (via Semantic Scholar)
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Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2003 article

Sorptive Reconstruction of the CuAlCl4 Framework upon Reversible Ethylene Binding

Sullivan, R. M., Liu, H., Smith, D. S., Hanson, J. C., Osterhout, D., Ciraolo, M., … Martin, J. D. (2003, August 14). Journal of the American Chemical Society, Vol. 125, pp. 11065–11079.

By: R. Sullivan n, H. Liu  n, D. Smith n, J. Hanson  n, D. Osterhout n, M. Ciraolo n, C. Grey  n, J. Martin n 

Contributors: R. Sullivan n, H. Liu  n, D. Smith n, J. Hanson  n, D. Osterhout n, M. Ciraolo n, C. Grey  n, J. Martin n 

topics (OpenAlex): Ionic liquids properties and applications; Mesoporous Materials and Catalysis; Metal-Organic Frameworks: Synthesis and Applications
TL;DR: Three ethylene adducts to CuAlCl(4) have been characterized by single crystal and/or powder X-ray diffraction, (13)C, (27)Al and (63)Cu MAS NMR and diffuse reflectance UV-vis spectroscopy, providing an atomistic picture of the sorptive reconstruction reactions. (via Semantic Scholar)
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Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2001 article

Kinetics and Mechanism of the β- to α-CuAlCl4Phase Transition:  A Time-Resolved63Cu MAS NMR and Powder X-ray Diffraction Study

Liu, H., Sullivan, R. M., Hanson, J. C., Grey, C. P., & Martin, J. D. (2001, July 14). Journal of the American Chemical Society, Vol. 123, pp. 7564–7573.

By: H. Liu  n, R. Sullivan n, J. Hanson  n, C. Grey  n & J. Martin n 

Contributors: H. Liu  n, R. Sullivan n, J. Hanson  n, C. Grey  n & J. Martin n 

topics (OpenAlex): X-ray Diffraction in Crystallography; Semiconductor materials and interfaces; Copper-based nanomaterials and applications
TL;DR: A one-dimensional growth mechanism is proposed that involves a combination of Cu(+) ion self-diffusion and a translational reorganization of the close-packed anion layers imposed by the periodic rotations of [AlCl(4)](-) tetrahedra. (via Semantic Scholar)
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Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

1999 article

An Illuminating Framework:  Understanding the Photoluminescence of α-CuAlCl4

Sullivan, R. M., & Martin, J. D. (1999, November 1). Journal of the American Chemical Society, Vol. 121, pp. 10092–10097.

By: R. Sullivan n & J. Martin n 

Contributors: R. Sullivan n & J. Martin n 

topics (OpenAlex): Advanced Photocatalysis Techniques; Metal-Organic Frameworks: Synthesis and Applications; Luminescence Properties of Advanced Materials
UN Sustainable Development Goals Color Wheel
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

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