Works (9)
Updated: July 5th, 2023 16:02
2003 journal article
Trends in exchange coupling for trimethylenemethane-type bis(semiquinone) biradicals and correlation of magnetic exchange with mixed valency for cross-conjugated systems
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(38), 11761–11771.
TL;DR:
The results suggest that delocalization in the cross-conjugated, mixed-valent radical anions is proportional to the ferromagnetic contribution to the exchange coupling in the biradical oxidation states.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
11. Sustainable Cities and Communities
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2003 journal article
Trends in metal-biradical exchange interaction for first-row M-II(nitronyl nitroxide-semiquinone) complexes
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(6), 1607–1617.
MeSH headings : Benzoquinones / chemistry; Catechols / chemistry; Crystallography, X-Ray; Magnetics; Metals, Heavy / chemistry; Molecular Structure; Nitrogen Oxides / chemistry
TL;DR:
It is shown that intraligand exchange coupling is of paramount importance in stabilizing high-spin states of mixed metal-biradical complexes.
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UN Sustainable Development Goal Categories
11. Sustainable Cities and Communities
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2002 journal article
Singlet-triplet gap in triplet ground-state biradicals is modulated by substituent effects
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 124(34), 10054–10061.
TL;DR:
Results of structural studies indicate that the biradical ligands of all three complexes have nearly identical conformations with average semiquinone ring torsions of 32 degrees +/- 2 degrees relative to the 5-substituted phenylene ring.
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UN Sustainable Development Goal Categories
11. Sustainable Cities and Communities
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2001 journal article
A bis-bidentate dioxolene ligand induces thermal hysteresis in valence tautomerism interconversion processes
Chemical Communications (Cambridge, England), (20), 2150–2151.
Source: NC State University Libraries
Added: August 6, 2018
2001 journal article
Molecular structure of and exchange coupling in a bis(semiquinone) complex
CHEMICAL COMMUNICATIONS, (01), 93–94.
UN Sustainable Development Goal Categories
11. Sustainable Cities and Communities
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2001 journal article
Molecular structures of carbonyl-linked bis(dioxolene) complexes: Can a carbonyl group act as an effective ferromagnetic coupler?
INORGANIC CHEMISTRY, 40(3), 546–549.
TL;DR:
Two bis(ZnIIdioxolene) complexes are described in which the two semiquinones are attached to a common carbonyl group and when reacted with PbO2, a labile S = 1, bis( ZnIIsemiquinone) complex is formed.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
11. Sustainable Cities and Communities
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2001 journal article
Spin robustness of a new hybrid inorganic-organic high-spin molecule
Journal of the American Chemical Society, 123(13), 3133–3134.
MeSH headings : Cations, Divalent; Circular Dichroism; Copper / chemistry; Electron Spin Resonance Spectroscopy / methods; Ferrous Compounds / chemistry; Models, Chemical; Spin Labels
UN Sustainable Development Goal Categories
11. Sustainable Cities and Communities
(Web of Science)
Sources: NC State University Libraries, NC State University Libraries
Added: August 6, 2018
2000 journal article
Synthesis and structure of a complex having a quartet ground state with three entirely different spin carriers: Nitronyl nitroxide, o-semiquinone, and Cu-II
INORGANIC CHEMISTRY, 39(26), 6091–6093.
TL;DR:
The results of X-ray structural characterization of the ZnII derivative suggest substantial interaction between the two spin carriers NN and o-SQ, and strong intramolecular exchange coupling has been determined by variable-temperature magnetic susceptibility studies.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
11. Sustainable Cities and Communities
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
1999 journal article
Both an oxidation/reduction sequence and deprotonation of a unique paramagnetic ligand lead to a mixed-valent complex
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 121(45), 10664–10665.
UN Sustainable Development Goal Categories
11. Sustainable Cities and Communities
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
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