Scot H. Bodnar

Works (9)

Updated: July 5th, 2023 16:02

2003 journal article

Trends in exchange coupling for trimethylenemethane-type bis(semiquinone) biradicals and correlation of magnetic exchange with mixed valency for cross-conjugated systems

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(38), 11761–11771.

By: D. Shultz n , R. Fico  n, S. Bodnar n, R. Kumar  n, K. Vostrikova n, J. Kampf  n, P. Boyle n

TL;DR: The results suggest that delocalization in the cross-conjugated, mixed-valent radical anions is proportional to the ferromagnetic contribution to the exchange coupling in the biradical oxidation states. (via Semantic Scholar)
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Added: August 6, 2018

2003 journal article

Trends in metal-biradical exchange interaction for first-row M-II(nitronyl nitroxide-semiquinone) complexes

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(6), 1607–1617.

By: D. Shultz n , K. Vostrikova n, S. Bodnar n, H. Koo n, M. Whangbo n, M. Kirk  n, E. Depperman n, J. Kampf  n

MeSH headings : Benzoquinones / chemistry; Catechols / chemistry; Crystallography, X-Ray; Magnetics; Metals, Heavy / chemistry; Molecular Structure; Nitrogen Oxides / chemistry
TL;DR: It is shown that intraligand exchange coupling is of paramount importance in stabilizing high-spin states of mixed metal-biradical complexes. (via Semantic Scholar)
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Added: August 6, 2018

2002 journal article

Singlet-triplet gap in triplet ground-state biradicals is modulated by substituent effects

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 124(34), 10054–10061.

By: D. Shultz n , S. Bodnar n, H. Lee n, J. Kampf  n, C. Incarvito n & A. Rheingold  n

TL;DR: Results of structural studies indicate that the biradical ligands of all three complexes have nearly identical conformations with average semiquinone ring torsions of 32 degrees +/- 2 degrees relative to the 5-substituted phenylene ring. (via Semantic Scholar)
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Added: August 6, 2018

2001 journal article

A bis-bidentate dioxolene ligand induces thermal hysteresis in valence tautomerism interconversion processes

Chemical Communications (Cambridge, England), (20), 2150–2151.

By: S. Bodnar, A. Caneschi, A. Dei, D. Shultz  & L. Sorace

Source: NC State University Libraries
Added: August 6, 2018

2001 journal article

Molecular structure of and exchange coupling in a bis(semiquinone) complex

CHEMICAL COMMUNICATIONS, (01), 93–94.

By: D. Shultz n , S. Bodnar n & J. Kampf *

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2001 journal article

Spin robustness of a new hybrid inorganic-organic high-spin molecule

Journal of the American Chemical Society, 123(13), 3133–3134.

By: E. Depperman n, S. Bodnar n, K. Vostrikova n, D. Shultz n  & M. Kirk  n

MeSH headings : Cations, Divalent; Circular Dichroism; Copper / chemistry; Electron Spin Resonance Spectroscopy / methods; Ferrous Compounds / chemistry; Models, Chemical; Spin Labels
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Added: August 6, 2018

2000 journal article

Molecular structures of carbonyl-linked bis(dioxolene) complexes: Can a carbonyl group act as an effective ferromagnetic coupler?

INORGANIC CHEMISTRY, 40(3), 546–549.

By: D. Shultz n , S. Bodnar n, R. Kumar  n, H. Lee  n & J. Kampf  n

TL;DR: Two bis(ZnIIdioxolene) complexes are described in which the two semiquinones are attached to a common carbonyl group and when reacted with PbO2, a labile S = 1, bis( ZnIIsemiquinone) complex is formed. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2000 journal article

Synthesis and structure of a complex having a quartet ground state with three entirely different spin carriers: Nitronyl nitroxide, o-semiquinone, and Cu-II

INORGANIC CHEMISTRY, 39(26), 6091–6093.

By: D. Shultz n , S. Bodnar n, K. Vostrikova n & J. Kampf  n

TL;DR: The results of X-ray structural characterization of the ZnII derivative suggest substantial interaction between the two spin carriers NN and o-SQ, and strong intramolecular exchange coupling has been determined by variable-temperature magnetic susceptibility studies. (via Semantic Scholar)
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Added: August 6, 2018

1999 journal article

Both an oxidation/reduction sequence and deprotonation of a unique paramagnetic ligand lead to a mixed-valent complex

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 121(45), 10664–10665.

By: D. Shultz n , S. Bodnar n, R. Kumar  n & J. Kampf  n

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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

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