@article{bello_shen_zhao_esancy_freeman_2000, title={Dyes based on 5,10-dihydrophenophosphazine. Part I: Disazo direct dyes}, volume={46}, ISSN={["0143-7208"]}, DOI={10.1016/S0143-7208(00)00044-9}, abstractNote={The synthesis of 2,8-diamino-5,10-dihydro-10-hydroxy-5-methylphenophosphazine 10-oxide as a possible replacement for the benzidine moiety in some disazo dyes and the use of this new diamine in the preparation of direct dyes were undertaken. The dyes obtained were applied to cotton to give purple to brilliant blue shades, and their structures were confirmed using negative ion electrospray mass spectrometry.}, number={3}, journal={DYES AND PIGMENTS}, author={Bello, KA and Shen, K and Zhao, D and Esancy, M and Freeman, H}, year={2000}, month={Sep}, pages={121–128} } @article{freeman_esancy_claxton_esancy_1991, title={Color, yes; cancer, no}, volume={21}, number={7}, journal={Chemtech}, author={Freeman, H. S. and Esancy, J. F. and Claxton, L. D. and Esancy, M. K.}, year={1991}, pages={438} } @article{freeman_hsu_esancy_esancy_1988, title={PROTON MAGNETIC-RESONANCE SPECTRA OF SOME NAPHTHALENE DERIVATIVES}, volume={9}, ISSN={["1873-3743"]}, DOI={10.1016/0143-7208(88)85005-8}, abstractNote={The chemical shifts of the ring protons of some monosubstituted naphthalenes were assigned from 250 MHz spectra, and the assignments were used to assist in the interpretation of the spectra of a number of naphthalene sulfonic acids which are commonly used as dyestuff intermediates. A table of parameters is presented which would assist in the identification of complex azo dyes that are derived from these naphthalene derivatives.}, number={1}, journal={DYES AND PIGMENTS}, author={FREEMAN, HS and HSU, WN and ESANCY, JF and ESANCY, MK}, year={1988}, pages={67–82} } @article{freeman_esancy_esancy_mills_whaley_dabney_1987, title={AN APPROACH TO THE DESIGN OF NONMUTAGENIC AZO DYES .1. THE IDENTIFICATION OF NONMUTAGENIC PRECURSORS AND POTENTIAL METABOLITES}, volume={8}, ISSN={["0143-7208"]}, DOI={10.1016/0143-7208(87)85034-9}, abstractNote={This paper describes a strategy for the development of non-mutagenic dyes by identifying and elaborating some non-genotoxic precursors. The approach presented makes use of the numerous published articles which describe the results of the mutagenicity and carcinogenicity testing of azo dyes and their intermediates. A number of chemical intermediates have been evaluated in this study as potential replacements for known carcinogenic dye intermediates which have been used in the past to produce dyes possessing good physical and chemical properties. Several of the intermediates examined were found to be non-mutagenic, and were converted to azo dyes which were themselves non-mutagenic. The results of this study suggest that the development of non-carcinogenic azo dyes could be accomplished by employing an approach which would utilize non-mutagenic intermediates and also take into consideration the potential genotoxicity of the metabolites resulting from reductive cleavage of the azo linkages.}, number={6}, journal={DYES AND PIGMENTS}, author={FREEMAN, HS and ESANCY, JF and ESANCY, MK and MILLS, KP and WHALEY, WM and DABNEY, BJ}, year={1987}, pages={417–430} }