2003 journal article

Trends in exchange coupling for trimethylenemethane-type bis(semiquinone) biradicals and correlation of magnetic exchange with mixed valency for cross-conjugated systems

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(38), 11761–11771.

TL;DR: The results suggest that delocalization in the cross-conjugated, mixed-valent radical anions is proportional to the ferromagnetic contribution to the exchange coupling in the biradical oxidation states. (via Semantic Scholar)
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Added: August 6, 2018

2003 journal article

Trends in metal-biradical exchange interaction for first-row M-II(nitronyl nitroxide-semiquinone) complexes

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(6), 1607–1617.

By: D. Shultz n, K. Vostrikova n, S. Bodnar n, H. Koo n, M. Whangbo n, M. Kirk n, E. Depperman n, J. Kampf n

MeSH headings : Benzoquinones / chemistry; Catechols / chemistry; Crystallography, X-Ray; Magnetics; Metals, Heavy / chemistry; Molecular Structure; Nitrogen Oxides / chemistry
TL;DR: It is shown that intraligand exchange coupling is of paramount importance in stabilizing high-spin states of mixed metal-biradical complexes. (via Semantic Scholar)
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2002 journal article

High-spin metal complexes containing a ferromagnetically coupled tris(semiquinone) ligand

INORGANIC CHEMISTRY, 41(5), 1086–1092.

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2001 journal article

Spin robustness of a new hybrid inorganic-organic high-spin molecule

Journal of the American Chemical Society, 123(13), 3133–3134.

By: E. Depperman n, S. Bodnar n, K. Vostrikova n, D. Shultz n & M. Kirk n

MeSH headings : Cations, Divalent; Circular Dichroism; Copper / chemistry; Electron Spin Resonance Spectroscopy / methods; Ferrous Compounds / chemistry; Models, Chemical; Spin Labels
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Added: August 6, 2018

2000 journal article

Synthesis and structure of a complex having a quartet ground state with three entirely different spin carriers: Nitronyl nitroxide, o-semiquinone, and Cu-II

INORGANIC CHEMISTRY, 39(26), 6091–6093.

By: D. Shultz n, S. Bodnar n, K. Vostrikova n & J. Kampf n

TL;DR: The results of X-ray structural characterization of the ZnII derivative suggest substantial interaction between the two spin carriers NN and o-SQ, and strong intramolecular exchange coupling has been determined by variable-temperature magnetic susceptibility studies. (via Semantic Scholar)
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Added: August 6, 2018

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