Excited-State Photodynamics of Perylene−Porphyrin Dyads. 5. Tuning Light-Harvesting Characteristics via Perylene Substituents, Connection Motif, and Three-Dimensional Architecture
Kirmaier, C., Song, H.-eun, Yang, E., Schwartz, J. K., Hindin, E., Diers, J. R., … Holten, D. (2010, January 29). The Journal of Physical Chemistry B, Vol. 114, pp. 14249–14264.
topics (OpenAlex): Porphyrin and Phthalocyanine Chemistry; Luminescence and Fluorescent Materials; Photochemistry and Electron Transfer Studies
TL;DR:
This study has identified suitable perylene-porphyrin constructs for use in light-harvesting applications and identified the monophenoxy perylene with an N-imide diphenylethyne linker is superior in providing rapid and essentially quantitative energy transfer from excited perylene to zinc porphyrin with minimal electron-transfer quenching in both toluene and benzonitrile.
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
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