@article{munro-leighton_feng_zhang_alsop_gunnoe_boyle_petersen_2008, title={Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex}, volume={47}, DOI={10.1021/icS00843b}, number={14}, journal={Inorganic Chemistry}, author={Munro-Leighton, C. and Feng, Y. and Zhang, J. and Alsop, N. M. and Gunnoe, T. B. and Boyle, P. D. and Petersen, J. L.}, year={2008}, pages={6124–6126} } @article{zhang_gunnoe_peterson_2005, title={Reactions of (PCP)Ru(CO)(NHPh)(PMe3) (PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3) with substrates that possess polar bonds}, volume={44}, ISSN={["1520-510X"]}, DOI={10.1021/ic0483592}, abstractNote={The Ru(II) amido complex (PCP)Ru(CO)(PMe(3))(NHPh) (1) (PCP = 2,6-(CH(2)P(t)Bu(2))(2)C(6)H(3)) reacts with compounds that possess polar C=N, C triple bond N, or C=O bonds (e.g., nitriles, carbodiimides, or isocyanates) to produce four-membered heterometallacycles that result from nucleophilic addition of the amido nitrogen to an unsaturated carbon of the organic substrate. Based on studies of the reaction of complex 1 with acetonitrile, the transformations are suggested to proceed by dissociation of trimethylphosphine, followed by coordination of the organic substrate and then intramolecular N-C bond formation. In the presence of ROH (R = H or Me), the fluorinated amidinate complex (PCP)Ru(CO)(N(Ph)C(C(6)F(5))NH) (6) reacts with excess pentafluorobenzonitrile to produce (PCP)Ru(CO)(F)(N(H)C(C(6)F(5))NHPh) (7). The reaction with MeOH also produces o-MeOC(6)F(4)CN (>90%) and p-MeOC(6)F(4)CN (<10%). Details of the solid-state structures of (PCP)Ru(CO)(F)(N(H)C(C(6)F(5))NHPh) (7), (PCP)Ru(CO)[PhNC{NH(hx)}N(hx)] (8), (PCP)Ru(CO){N(Ph)C(NHPh)O} (9), and (PCP)Ru(CO){OC(Ph)N(Ph)} (10) are reported.}, number={8}, journal={INORGANIC CHEMISTRY}, author={Zhang, JB and Gunnoe, TB and Peterson, JL}, year={2005}, month={Apr}, pages={2895–2907} } @article{zhang_barakat_cundari_gunnoe_boyle_petersen_day_2005, title={Synthesis of the five-coordinate ruthenium(II) Complexes [(PCP)Ru(CO)(L)][BAr'(4)] {PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3, BAr'(4) 3,5-(CF3)(2)C6H3, L = eta(1)-ClCH2Cl, eta-N-2, or mu-Cl-Ru(PCP)(CO)}: Reactions with phenyldiazomethane and phenylacetylene}, volume={44}, DOI={10.1012/ic051074k}, number={23}, journal={Inorganic Chemistry}, author={Zhang, J. B. and Barakat, K. A. and Cundari, T. R. and Gunnoe, T. B. and Boyle, P. D. and Petersen, J. L. and Day, C. S.}, year={2005}, pages={8379–8390} } @article{zhang_gunnoe_boyle_2004, title={Ruthenium(II) anilido complex containing a bisphosphine pincer ligand: Reversible formation of amidinate ligands via intramolecular C-N bond formation}, volume={23}, ISSN={["1520-6041"]}, DOI={10.1021/om0497543}, abstractNote={The reaction of the octahedral anilido complex (PCP)Ru(CO)(NHPh)(PMe3) with acetonitrile produces the amidinate complex (PCP)Ru(CO){N(H)C(Me)N(Ph)}. Mechanistic studies indicate that the reaction proceeds through coordination of the nitrile to the Ru(II) metal center, followed by intramolecular nucleophilic addition of the amido ligand.}, number={13}, journal={ORGANOMETALLICS}, author={Zhang, J and Gunnoe, TB and Boyle, PD}, year={2004}, month={Jun}, pages={3094–3097} } @article{zhang_whitesell_fox_2003, title={Photophysical behavior of variously sized colloidal gold clusters capped with monolayers of an alkylstilbenethiolate}, volume={107}, ISSN={["1520-6106"]}, DOI={10.1021/jp027555w}, abstractNote={trans-4-(Mercaptoheptoxy)stilbene (S7-SH) was capped as a monolayer on colloidal gold clusters of diameters ranging from 1.4 to 5.2 nm. The resulting shell−core nanostructured composite showed emission from the metal and the appended arene. Differential surface area, rather than gold cluster size per se, accounted for the observed decreases in fluorescence intensity of the excited stilbene moiety upon shrinking the metal core size. Tight packing by an organic monolayer bound to the surface of the Au core was achieved most easily on large composite particles, whereas thiolatestilbene S7-SH groups bound to the surface of the smallest metal clusters were found to be conformationally more labile.}, number={25}, journal={JOURNAL OF PHYSICAL CHEMISTRY B}, author={Zhang, J and Whitesell, JK and Fox, MA}, year={2003}, month={Jun}, pages={6051–6055} }