Works (9)

Updated: July 5th, 2023 15:58

2008 review

Chemistry surrounding Group 7 complexes that possess Poly(pyrazolyl)borate ligands

[Review of ]. Organotransition metal chemistry of poly(pyrazolyl)borates, pt 1, 56, 95–153.

By: M. Lail, K. Pittard & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2007 article

Combined Experimental and Computational Study of TpRu{P(pyr)3}(NCMe)Me (pyr = N-pyrrolyl):  Inter- and Intramolecular Activation of C−H Bonds and the Impact of Sterics on Catalytic Hydroarylation of Olefins

Foley, N. A., Lail, M., Gunnoe, T. B., Cundari, T. R., Boyle, P. D., & Petersen, J. L. (2007, October 4). Organometallics.

topics (OpenAlex): Organometallic Complex Synthesis and Catalysis; Catalytic Cross-Coupling Reactions
Source: Web Of Science
Added: August 6, 2018

2007 article

Comparative Reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3):  Impact of Ancillary Ligand L on Activation of Carbon−Hydrogen Bonds Including Catalytic Hydroarylation and Hydrovinylation/Oligomerization of Ethylene

Foley, N. A., Lail, M., Lee, J. P., Gunnoe, T. B., Cundari, T. R., & Petersen, J. L. (2007, May 1). Journal of the American Chemical Society, Vol. 129, pp. 6765–6781.

topics (OpenAlex): Organometallic Complex Synthesis and Catalysis; Coordination Chemistry and Organometallics; Catalytic Cross-Coupling Reactions
TL;DR: Kinetic studies, isotopic labeling, and other experimental evidence suggest that the mechanism of benzene C-H activation involves reversible dissociation of acetonitrile, reversible benzene coordination, and rate-determining C-h activation of coordinated benzene. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2006 article

Hydrogen−Deuterium Exchange between TpRu(PMe3)(L)X (L = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and Deuterated Arene Solvents:  Evidence for Metal-Mediated Processes

Feng, Y., Lail, M., Foley, N. A., Gunnoe, T. B., Barakat, K. A., Cundari, T. R., & Petersen, J. L. (2006, May 24). Journal of the American Chemical Society.

By: Y. Feng n, M. Lail n, N. Foley n, T. Gunnoe n, K. Barakat n, T. Cundari n, J. Petersen n

MeSH headings : Cadmium Compounds / chemistry; Deuterium / chemistry; Hydrogen / chemistry; Ligands; Mesylates / chemistry; Metals / chemistry; Microscopy, Electron; Organometallic Compounds / chemistry; Ruthenium / chemistry; Selenium Compounds / chemistry; Solvents / chemistry; Spectrum Analysis; Temperature
topics (OpenAlex): Coordination Chemistry and Organometallics; Catalytic Cross-Coupling Reactions; Chemical Reactions and Isotopes
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6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Reactions of TpRu(CO)(NCMe)(Ph) with electron-rich olefins: examples of stoichiometric C-S, C-O and C-H bond cleavage

Chemical Communications (Cambridge, England), (9), 982–984.

By: L. Goj, M. Lail, K. Pittard, K. Riley, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2005 article

Conversions of Ruthenium(III) Alkyl Complexes to Ruthenium(II) through Ru−Calkyl Bond Homolysis

Lail, M., Gunnoe, T. B., Barakat, K. A., & Cundari, T. R. (2005, February 12). Organometallics.

By: M. Lail n, T. Gunnoe n, K. Barakat n & T. Cundari n

topics (OpenAlex): Organometallic Complex Synthesis and Catalysis; Metal complexes synthesis and properties; Asymmetric Hydrogenation and Catalysis
Source: Web Of Science
Added: August 6, 2018

2005 article

Evidence for the Net Addition of Arene C−H Bonds across a Ru(II)−Hydroxide Bond

Feng, Y., Lail, M., Barakat, K. A., Cundari, T. R., Gunnoe, T. B., & Petersen, J. L. (2005, September 27). Journal of the American Chemical Society.

By: Y. Feng n, M. Lail n, K. Barakat n, T. Cundari n, T. Gunnoe n & J. Petersen n

MeSH headings : Crystallography, X-Ray; Hydroxides / chemistry; Models, Molecular; Molecular Conformation; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Ruthenium / chemistry
topics (OpenAlex): Catalytic Cross-Coupling Reactions; Chemical Reactions and Isotopes; Coordination Chemistry and Organometallics
TL;DR: Mechanistic and computational studies suggest that a likely reaction pathway for the H/D exchange involves loss of PMe3 to produce {TpRu(PMe3)(OH2)(OH)}, followed by the net addition of a benzene C-H(D) bond across the Ru-OH bond to form the putative complex. (via Semantic Scholar)
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Source: Web Of Science
Added: August 6, 2018

2004 article

Experimental and Computational Studies of Ruthenium(II)-Catalyzed Addition of Arene C−H Bonds to Olefins

Lail, M., Bell, C. M., Conner, D., Cundari, T. R., Gunnoe, T. B., & Petersen, J. L. (2004, September 10). Organometallics.

topics (OpenAlex): Catalytic Cross-Coupling Reactions; Organometallic Complex Synthesis and Catalysis
UN Sustainable Development Goals Color Wheel
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2003 article

Radical Polymerization of Styrene and Methyl Methacrylate with Ruthenium(II) Complexes

Arrowood, B. N., Lail, M., Gunnoe, T. B., & Boyle, P. D. (2003, October 2). Organometallics.

By: B. Arrowood n, M. Lail n, T. Gunnoe n & P. Boyle n

topics (OpenAlex): Organometallic Complex Synthesis and Catalysis; Carbon dioxide utilization in catalysis; Synthetic Organic Chemistry Methods
Source: Web Of Science
Added: August 6, 2018

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