Works (9)

Updated: July 5th, 2023 15:58

2008 review

Chemistry surrounding Group 7 complexes that possess Poly(pyrazolyl)borate ligands

[Review of ]. Organotransition metal chemistry of poly(pyrazolyl)borates, pt 1, 56, 95–153.

By: M. Lail, K. Pittard & T. Gunnoe

Source: NC State University Libraries
Added: August 6, 2018

2007 journal article

Combined experimental and computational study of TpRu{P(pyr)(3)}(NCMe)Me (pyr = N-pyrrolyl): Inter- and intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins

ORGANOMETALLICS, 26(23), 5507–5516.

Source: Web Of Science
Added: August 6, 2018

2007 journal article

Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3): Impact of ancillary ligand L on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(21), 6765–6781.

TL;DR: Kinetic studies, isotopic labeling, and other experimental evidence suggest that the mechanism of benzene C-H activation involves reversible dissociation of acetonitrile, reversible benzene coordination, and rate-determining C-h activation of coordinated benzene. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2006 journal article

Hydrogen-deuterium exchange between TpRu( PMe3)(L)X (L) = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: Evidence for metal-mediated processes

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(24), 7982–7994.

By: Y. Feng n, M. Lail n, N. Foley n, T. Gunnoe n, K. Barakat n, T. Cundari n, J. Petersen n

MeSH headings : Cadmium Compounds / chemistry; Deuterium / chemistry; Hydrogen / chemistry; Ligands; Mesylates / chemistry; Metals / chemistry; Microscopy, Electron; Organometallic Compounds / chemistry; Ruthenium / chemistry; Selenium Compounds / chemistry; Solvents / chemistry; Spectrum Analysis; Temperature
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Reactions of TpRu(CO)(NCMe)(Ph) with electron-rich olefins: examples of stoichiometric C-S, C-O and C-H bond cleavage

Chemical Communications (Cambridge, England), (9), 982–984.

By: L. Goj, M. Lail, K. Pittard, K. Riley, T. Gunnoe & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2005 journal article

Conversions of ruthenium(III) alkyl complexes to ruthenium(II) through Ru-C-alkyl bond homolysis

ORGANOMETALLICS, 24(6), 1301–1305.

By: M. Lail n, T. Gunnoe n, K. Barakat n & T. Cundari n

Source: Web Of Science
Added: August 6, 2018

2005 journal article

Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127(41), 14174–14175.

By: Y. Feng n, M. Lail n, K. Barakat n, T. Cundari n, T. Gunnoe n & J. Petersen n

MeSH headings : Crystallography, X-Ray; Hydroxides / chemistry; Models, Molecular; Molecular Conformation; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Ruthenium / chemistry
TL;DR: Mechanistic and computational studies suggest that a likely reaction pathway for the H/D exchange involves loss of PMe3 to produce {TpRu(PMe3)(OH2)(OH)}, followed by the net addition of a benzene C-H(D) bond across the Ru-OH bond to form the putative complex. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2004 journal article

Experimental and computational studies of ruthenium(II)-catalyzed addition of arene C-H bonds to olefins

ORGANOMETALLICS, 23(21), 5007–5020.

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2003 journal article

Radical polymerization of styrene and methyl methacrylate with Ruthenium(II) complexes

ORGANOMETALLICS, 22(23), 4692–4698.

By: B. Arrowood n, M. Lail n, T. Gunnoe n & P. Boyle n

Source: Web Of Science
Added: August 6, 2018

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