Works (9)
Updated: July 5th, 2023 15:58
2008 review
Chemistry surrounding Group 7 complexes that possess Poly(pyrazolyl)borate ligands
[Review of ]. Organotransition metal chemistry of poly(pyrazolyl)borates, pt 1, 56, 95–153.
Source: NC State University Libraries
Added: August 6, 2018
2007 journal article
Combined experimental and computational study of TpRu{P(pyr)(3)}(NCMe)Me (pyr = N-pyrrolyl): Inter- and intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins
ORGANOMETALLICS, 26(23), 5507–5516.
open access via digital.library.unt.edu (repository)
Source: Web Of Science
Added: August 6, 2018
2007 journal article
Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3): Impact of ancillary ligand L on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(21), 6765–6781.
TL;DR:
Kinetic studies, isotopic labeling, and other experimental evidence suggest that the mechanism of benzene C-H activation involves reversible dissociation of acetonitrile, reversible benzene coordination, and rate-determining C-h activation of coordinated benzene.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2006 journal article
Hydrogen-deuterium exchange between TpRu( PMe3)(L)X (L) = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: Evidence for metal-mediated processes
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(24), 7982–7994.
MeSH headings : Cadmium Compounds / chemistry; Deuterium / chemistry; Hydrogen / chemistry; Ligands; Mesylates / chemistry; Metals / chemistry; Microscopy, Electron; Organometallic Compounds / chemistry; Ruthenium / chemistry; Selenium Compounds / chemistry; Solvents / chemistry; Spectrum Analysis; Temperature
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
12. Responsible Consumption and Production
(Web of Science)
Source: Web Of Science
Added: August 6, 2018
2006 journal article
Reactions of TpRu(CO)(NCMe)(Ph) with electron-rich olefins: examples of stoichiometric C-S, C-O and C-H bond cleavage
Chemical Communications (Cambridge, England), (9), 982–984.
Source: NC State University Libraries
Added: August 6, 2018
2005 journal article
Conversions of ruthenium(III) alkyl complexes to ruthenium(II) through Ru-C-alkyl bond homolysis
ORGANOMETALLICS, 24(6), 1301–1305.
UN Sustainable Development Goal Categories
12. Responsible Consumption and Production
(Web of Science)
Source: Web Of Science
Added: August 6, 2018
2005 journal article
Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127(41), 14174–14175.
MeSH headings : Crystallography, X-Ray; Hydroxides / chemistry; Models, Molecular; Molecular Conformation; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Ruthenium / chemistry
TL;DR:
Mechanistic and computational studies suggest that a likely reaction pathway for the H/D exchange involves loss of PMe3 to produce {TpRu(PMe3)(OH2)(OH)}, followed by the net addition of a benzene C-H(D) bond across the Ru-OH bond to form the putative complex.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
12. Responsible Consumption and Production
(Web of Science)
Source: Web Of Science
Added: August 6, 2018
2004 journal article
Experimental and computational studies of ruthenium(II)-catalyzed addition of arene C-H bonds to olefins
ORGANOMETALLICS, 23(21), 5007–5020.
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
Source: Web Of Science
Added: August 6, 2018
2003 journal article
Radical polymerization of styrene and methyl methacrylate with Ruthenium(II) complexes
ORGANOMETALLICS, 22(23), 4692–4698.
Source: Web Of Science
Added: August 6, 2018
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