Works (2)
Updated: July 5th, 2023 15:58
2004 article
Helix-Sense Selective Polymerization of Carbodiimides: Building Permanently Optically Active Polymers from Achiral Monomers
Tian, G., Lu, Y., & Novak, B. M. (2004, March 11). Journal of the American Chemical Society.
topics (OpenAlex): Synthesis and Properties of Aromatic Compounds; Supramolecular Chemistry and Complexes; Axial and Atropisomeric Chirality Synthesis
TL;DR:
Polymerization of chiral carbodiimides by achiral catalysts yields polymers that undergo mutorotation at elevated temperatures, thus illustrating that these chains are formed under kinetic rather than thermodynamic control.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
3. Good Health and Well-being
(Web of Science)
Source: Web Of Science
Added: August 6, 2018
2004 article
Stable Helical Polyguanidines: Poly{N-(1-anthryl)-N‘-[(R)- and/or (S)-3,7-dimethyloctyl]guanidines}
Tang, H.-Z., Lu, Y., Tian, G., Capracotta, M. D., & Novak, B. M. (2004, March 1). Journal of the American Chemical Society.
topics (OpenAlex): Synthesis and Properties of Aromatic Compounds; Organoboron and organosilicon chemistry; Supramolecular Chemistry and Complexes
TL;DR:
Using chiral catalysts of (R)- and/or (S)-BINOL-Ti, the asymmetrical polymerization of achiral monomer, N-(1-anthryl)-N'-n-octadecylcarbodiimide, yielded soluble nonregioregular polyguanidines of Poly-R1 and Poly-S1.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
3. Good Health and Well-being
(Web of Science)
Source: Web Of Science
Added: August 6, 2018