2004 journal article

Helix-sense selective polymerization of carbodiimides: Building permanently optically active polymers from achiral monomers

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 126(13), 4082–4083.

By: G. Tian n, Y. Lu n & B. Novak n

TL;DR: Polymerization of chiral carbodiimides by achiral catalysts yields polymers that undergo mutorotation at elevated temperatures, thus illustrating that these chains are formed under kinetic rather than thermodynamic control. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2004 journal article

Stable helical polyguanidines: Poly{N-(1-anthryl)-N '-[(R)- and/or (S)-3,7-dimethyloctyl]guanidines}

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 126(12), 3722–3723.

By: H. Tang n, Y. Lu n, G. Tian n, M. Capracotta n & B. Novak n

TL;DR: Using chiral catalysts of (R)- and/or (S)-BINOL-Ti, the asymmetrical polymerization of achiral monomer, N-(1-anthryl)-N'-n-octadecylcarbodiimide, yielded soluble nonregioregular polyguanidines of Poly-R1 and Poly-S1. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

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