@article{thamyongkit_yu_padmaja_jiao_bocian_lindsey_2006, title={Porphyrin dyads bearing carbon tethers for studies of high-density molecular charge storage on silicon surfaces}, volume={71}, ISSN={["1520-6904"]}, DOI={10.1021/jo0522761}, abstractNote={Redox-active molecules that afford high charge density upon attachment to an electroactive surface are of interest for use in molecular-based information-storage applications. One strategy for increasing charge density is to covalently link a second redox center to the first in an architecture that uses the vertical dimension in essentially the same molecular footprint. Toward this end, a set of four new porphyrin dyads have been prepared and characterized. Each dyad consists of two zinc porphyrins, an intervening linker (p-phenylene or 4,4'-diphenylethyne), and a surface attachment group (ethynyl or triallyl group). The porphyrin dyads were attached to an electroactive Si(100) surface and interrogated via electrochemical and FTIR techniques. The charge density obtainable for the ethynyl-functionalized porphyrin dyads is approximately double that observed for an analogously functionalized monomer, whereas that for the triallyl-functionalized dyads is at most 40% larger. These results indicate that the molecular footprint of the former dyads is similar to that of a monomer while that of the latter dyads is larger. For both the ethynyl- and triallyl-functionalized porphyrin dyads, higher charge densities (smaller molecular footprints) are obtained for the molecules containing the 4,4'-diphenylethyne versus the p-phenylene linker. This feature is attributed to the enhanced torsional flexibility of the former linker compared with that of the latter, which affords better packed monolayers. The FTIR studies indicate that the adsorption geometry of all the dyads is qualitatively similar and similar to that of monomers. However, the dyads containing the 4,4'-diphenylethyne linker sit somewhat more upright on the surface than those containing the p-phenylene linker, generally consistent with the smaller molecular footprint for the former dyads. Collectively, the high surface charge density (34-58 muC.cm(-)(2)) of the porphyrin dyads makes these constructs viable candidates for molecular-information-storage applications.}, number={3}, journal={JOURNAL OF ORGANIC CHEMISTRY}, author={Thamyongkit, P and Yu, LH and Padmaja, K and Jiao, JY and Bocian, DF and Lindsey, JS}, year={2006}, month={Feb}, pages={1156–1171} }
 @article{padmaja_youngblood_wei_bocian_lindsey_2006, title={Triple-decker sandwich compounds bearing compact triallyl tripods for molecular information storage applications}, volume={45}, ISSN={["1520-510X"]}, DOI={10.1021/ic060387s}, abstractNote={The design of redox-active molecules that afford multistate operation and high charge density is essential for molecular information storage applications. Triple-decker sandwich compounds composed of two lanthanide metal ions and three porphyrinic ligands exhibit a large number of oxidation states within a relatively narrow electrochemical window. High charge density requires a small footprint upon tethering triple deckers to an electroactive surface. All triple deckers examined to date for information storage have been tethered via the terminal ligand and have exhibited large footprints (approximately 670 A2). Five new homonuclear (Eu or Ce) triple deckers have been prepared (via statistical or rational methods) to examine the effect of tether attachment site on molecular footprint. Three triple deckers are tethered via the terminal ligand (porphyrin) or central ligand (porphyrin or imidazophthalocyanine), whereas two triple deckers each bear two tethers, one at each terminal ligand. The tether is a compact triallyl tripod. Monolayers of the triple deckers on Si(100) were examined by electrochemical and FTIR techniques. Each triple decker exhibited the expected four resolved voltammetric waves, owing to formation of the mono-, di-, tri-, and tetracations. The electrochemical studies of surface coverage (gamma, obtained by integrating the voltammetric waves) reveal that coverages approaching 10(-10) mol cm(-2), corresponding to a molecular footprint of approximately 170 A2, are readily achieved for all five of the triple deckers. The surface coverage observed for the tripodal functionalized triple deckers is approximately 4-fold higher than that obtained for monopodal-functionalized triple deckers (carbon, oxygen, or sulfur anchor atoms) attached to either Si(100) or Au(111). The fact that similar, relatively high, surface coverages can be achieved regardless of the location (or number) of the tripodal tether indicates that the tripodal functionalization, rather than the location of the tether, is the primary determinant of the packing density.}, number={14}, journal={INORGANIC CHEMISTRY}, author={Padmaja, Kisari and Youngblood, W. Justin and Wei, Lingyun and Bocian, David F. and Lindsey, Jonathan S.}, year={2006}, month={Jul}, pages={5479–5492} }