Works (8)
Updated: July 5th, 2023 15:56
2008 journal article
Activation of sp(3) carbon-hydrogen bonds complex and subsequent metal-mediated formation
Angewandte Chemie [International Edition in English], 47(4), 726–730.
Source: NC State University Libraries
Added: August 6, 2018
2008 journal article
Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)(3)CEt}(NCMe)Ph
ORGANOMETALLICS, 27(13), 3007–3017.
open access via digital.library.unt.edu (repository)
Source: Web Of Science
Added: August 6, 2018
2008 journal article
Chlorination of Boron on a Ruthenium-Coordinated Hydridotris(pyrazolyl)borate (Tp) Ligand: A Caveat for the Use of TpRu(PPh3)(2)Cl
ORGANOMETALLICS, 28(1), 374–377.
UN Sustainable Development Goal Categories
12. Responsible Consumption and Production
(Web of Science)
Source: Web Of Science
Added: August 6, 2018
2008 journal article
Hydroarylation of unactivated olefins catalyzed by platinum(II) complexes
ORGANOMETALLICS, 27(16), 4031–4033.
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2007 journal article
Combined experimental and computational studies on the nature of aromatic C-H activation by octahedral ruthenium(II) complexes: Evidence for sigma-bond metathesis from Hammett studies
ORGANOMETALLICS, 26(26), 6604–6611.
UN Sustainable Development Goal Categories
12. Responsible Consumption and Production
(Web of Science)
Source: Web Of Science
Added: August 6, 2018
2007 journal article
Combined experimental and computational study of TpRu{P(pyr)(3)}(NCMe)Me (pyr = N-pyrrolyl): Inter- and intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins
ORGANOMETALLICS, 26(23), 5507–5516.
Source: Web Of Science
Added: August 6, 2018
2007 journal article
Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3): Impact of ancillary ligand L on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129(21), 6765–6781.
TL;DR:
Kinetic studies, isotopic labeling, and other experimental evidence suggest that the mechanism of benzene C-H activation involves reversible dissociation of acetonitrile, reversible benzene coordination, and rate-determining C-h activation of coordinated benzene.
(via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2006 journal article
Hydrogen-deuterium exchange between TpRu( PMe3)(L)X (L) = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and deuterated arene solvents: Evidence for metal-mediated processes
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(24), 7982–7994.
MeSH headings : Cadmium Compounds / chemistry; Deuterium / chemistry; Hydrogen / chemistry; Ligands; Mesylates / chemistry; Metals / chemistry; Microscopy, Electron; Organometallic Compounds / chemistry; Ruthenium / chemistry; Selenium Compounds / chemistry; Solvents / chemistry; Spectrum Analysis; Temperature
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation
(OpenAlex)
12. Responsible Consumption and Production
(Web of Science)
Source: Web Of Science
Added: August 6, 2018
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