@article{zhang_wei_kopanski_shiue_fedkiw_2011, title={Single-Ion Conductors for Lithium Batteries via Surface-Initiated Atom Transfer Radical Polymerization}, volume={4}, ISSN={["1936-6612"]}, DOI={10.1166/asl.2011.1254}, number={2}, journal={ADVANCED SCIENCE LETTERS}, author={Zhang, Hanjun and Wei, Xuedong and Kopanski, Khalid and Shiue, Eric and Fedkiw, Peter S.}, year={2011}, month={Feb}, pages={488–491} } @article{zhang_maitra_wunder_2008, title={Preparation and characterization of composite electrolytes based on PEO(375)-grafted fumed silica}, volume={178}, ISSN={["1872-7689"]}, DOI={10.1016/j.ssi.2007.11.021}, abstractNote={Recent developments in polymer electrolytes have focused on preparation of composites using nano/micron size ceramic particles such as SiO2, TiO2, Al2O3, BaTiO3, and MgO. We report here the preparation and characterization of an all-solid state polyethylene oxide (PEO) composite electrolyte from PEO(375)–SiO2, high molecular weight PEO (MW = 600 K) and LiClO4 (O/Li = 16/1). Oligomeric PEOs, with ethylene oxide (EO) repeat units 6–9 ( = 375 g/mol), were chemically grafted (~ 30 wt.%) to fumed silica (A380) using a trimethoxy PEO(375)-silane. The surface grafted PEO chains were disordered (no crystallization) and less mobile than the free chains, with the glass transition temperature (Tg) increasing from − 90 °C [PEO(375)-silane] to − 54 °C [PEO(375)–SiO2]; addition of LiClO4 (O/Li = 8/1) further raised Tg to − 34 °C. Nanocomposite electrolytes with good dimensional stability were obtained by blending 14-wt.% PEO(375)–SiO2 with semicrystalline PEO(600 K)/LiClO4 (O/Li = 16/1). Conductivities (σ) were 10 to 4 times greater [between 10 °C (σ = 2.1 × 10− 8 S/cm) and 40 °C (σ = 1.1 × 10− 5 S/cm), respectively] than for neat PEO(600 K) or for composite electrolytes having the same amount of native fumed silica, SiO2. No conductivity improvements were observed above Tm or for amorphous PEO(600 K)/LiClO4 (O/Li = 8/1) with addition of SiO2 or PEO(375)–SiO2.}, number={39-40}, journal={SOLID STATE IONICS}, author={Zhang, Hanjun and Maitra, Prithwiraj and Wunder, Stephanie L.}, year={2008}, month={Mar}, pages={1975–1983} } @article{zhang_zhang_shiue_fedkiw_2008, title={Single-ion conductors for lithium batteries via silica surface modification}, volume={177}, ISSN={["0378-7753"]}, url={https://publons.com/publon/7178337/}, DOI={10.1016/j.jpowsour.2007.11.064}, abstractNote={Single-ion conductors (SICs) have been prepared by free-radical polymerization of sulfonic acid-containing monomer on high-purity silica surface that was first tailored with unsaturated functionality using a silanation reaction. It was found that steric effects limited polyelectrolyte surface loading even when large amount of silane molecules were grafted by forming a cross-linked structure. The results indicate that large surface area is an important factor to achieve high-surface loading of ionic moieties. Composite electrolytes were prepared by dispersing these SICs in aprotic solvents. The effects of filler content and solvent on ionic conductivity were investigated.}, number={2}, journal={JOURNAL OF POWER SOURCES}, author={Zhang, Hanjun and Zhang, Xiangwu and Shiue, Eric and Fedkiw, Peter S.}, year={2008}, month={Mar}, pages={561–565} }