Works (1)
Updated: July 25th, 2023 21:16
2014 journal article
An unsupported metal hydroxide for the design of molecular mu-oxo bridged heterobimetallic complexes
CHEMICAL COMMUNICATIONS, 50(17), 2139–2141.
MeSH headings : Chromium / chemistry; Coordination Complexes / chemical synthesis; Coordination Complexes / chemistry; Crystallography, X-Ray; Electrochemical Techniques; Hydroxides / chemistry; Molecular Conformation; Oxidation-Reduction; Oxygen / chemistry; Solar Energy; Titanium / chemistry
TL;DR:
The terminal hydroxide is used to synthesize the first example of a heterobimetallic Ti-O-Cr compound containing an unsupported μ-oxo bridge and exhibits a new absorbance at 288 nm (4.32 eV), which is assigned to a metal-to-metal charge transfer (MMCT) transition.
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