Works (103)

Updated: August 29th, 2023 10:40

2022 article

Solvate Structures and Computational/Spectroscopic Characterization of LiClO4 Electrolytes

Daubert, J. S., Afroz, T., Borodin, O., Seo, D. M., Boyle, P. D., & Henderson, W. A. (2022, August 17). JOURNAL OF PHYSICAL CHEMISTRY C.

By: J. Daubert n, T. Afroz n, O. Borodin*, D. Seo n, P. Boyle n & W. Henderson n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: October 3, 2022

2019 journal article

Towards microbe-targeted photosensitizers: Synthesis, characterization and in vitro photodynamic inactivation of the tuberculosis model pathogen M. smegmatis by porphyrin-peptide conjugates

Journal of Porphyrins and Phthalocyanines, 23(11n12), 1414–1439.

By: E. Feese n, H. Gracz n, P. Boyle n & R. Ghiladi n

author keywords: antimicrobial; Mycobacterium smegmatis; peptide; photodynamic inactivation; porphyrin; tuberculosis
TL;DR: The ability of PPCs to maintain their antimicrobial photodynamic inactivation efficacy when possessing a short cationic peptides for enabling the potential targeting of pathogens in vivo is demonstrated. (via Semantic Scholar)
UN Sustainable Development Goal Categories
3. Good Health and Well-being (Web of Science; OpenAlex)
Sources: Web Of Science, ORCID, Crossref
Added: February 10, 2020

2017 journal article

Cationic rhenium ((III)) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes

Dalton Transactions (Cambridge, England : 2003), 46(14), 4609–4616.

By: D. Perez n, J. Smeltz n, R. Sommer n, P. Boyle n & E. Ison n

TL;DR: The catalytic efficiency for the hydrosilylation reaction of aldehydes using 4a has been demonstrated to be significantly more active than rhenium catalysts previously reported in the literature and the data suggest that electron-withdrawing substituents at the diamido amine ligand increase the catalysttic efficiency of the complexes. (via Semantic Scholar)
Sources: NC State University Libraries, ORCID
Added: August 6, 2018

2015 journal article

Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters

JOURNAL OF PHYSICAL CHEMISTRY C, 119(13), 7022–7027.

By: T. Afroz n, D. Seo n, S. Han n, P. Boyle n & W. Henderson n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2015 journal article

Synthesis and Reactivity of Oxorhenium(V) Methyl, Benzyl, and Phenyl Complexes with CO: Implications for a Unique Mechanism for Migratory Insertion

ORGANOMETALLICS, 34(13), 3152–3158.

By: L. Robbins n, C. Lilly n, J. Smeltz n, P. Boyle n & E. Ison n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2015 journal article

Synthesis and X-ray analysis of a perfluoroalkyl-substituted azobenzene dye

DYES AND PIGMENTS, 120, 245–250.

By: L. He n, H. Freeman n, M. Nakpathom n & P. Boyle n

author keywords: Perfluoroalkylazo dye; Aminoazobenzene dye; X-ray diffraction; Crystal structure; Torsion angle; Surface energy
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2015 journal article

Synthesis, Characterization, and Photophysical Studies of an Iron(III) Catecholate-Nitronylnitroxide Spin-Crossover Complex

INORGANIC CHEMISTRY, 54(9), 4466–4474.

By: C. Tichnell n, D. Shultz n, C. Popescu*, I. Sokirniy* & P. Boyle n

TL;DR: Although the effects of the NN radical are manifest in neither the spin-crossover nor the photophysics, the results lay the groundwork for future studies. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2014 journal article

Anion Coordination Interactions in Solvates with the Lithium Salts LiDCTA and LiTDI

JOURNAL OF PHYSICAL CHEMISTRY C, 118(15), 7781–7787.

By: D. McOwen*, S. Delp, E. Paillard*, C. Herriot, S. Han*, P. Boyle*, R. Sommer*, W. Henderson*

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2014 journal article

Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms

ENERGY & ENVIRONMENTAL SCIENCE, 7(1), 416–426.

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2014 journal article

Crystallization and Solid-State Characterization of the Hemihydrate of Albuterol Hemisulfate

CRYSTAL GROWTH & DESIGN, 14(2), 775–782.

By: J. Bis*, P. Boyle n, S. Carino*, D. Igo* & L. Katrincic*

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2014 journal article

Oxyfunctionalization with Cp*Ir-III(NHC)(Me)L Complexes

ORGANOMETALLICS, 33(19), 5081–5084.

By: M. Lehman n, P. Boyle n, R. Sommer n & E. Ison n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2014 journal article

Solvate Structures and Computational/Spectroscopic Characterization of LiBF4 Electrolytes

JOURNAL OF PHYSICAL CHEMISTRY C, 118(32), 18377–18386.

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2014 journal article

Solvate Structures and Spectroscopic Characterization of LiTFSI Electrolytes

JOURNAL OF PHYSICAL CHEMISTRY B, 118(47), 13601–13608.

By: D. Seo n, P. Boyle n, R. Sommer n, J. Daubert n, O. Borodin* & W. Henderson n

TL;DR: It is found, however, that significant difficulties may be encountered when identifying the distributions of specific forms of TFSI(-) anion coordination present in liquid electrolyte mixtures due to the wide range of T FS(-)···Li(+) cation interactions possible and the overlap of the corresponding spectroscopic data signatures. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2014 journal article

Structural Interactions within Lithium Salt Solvates: Cyclic Carbonates and Esters

JOURNAL OF PHYSICAL CHEMISTRY C, 118(45), 25884–25889.

By: D. Seo n, T. Afroz n, J. Allen n, P. Boyle n, P. Trulove*, H. De Long*, W. Henderson n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2013 journal article

Cp*Ir-III-Catalyzed Oxidative Coupling of Benzoic Acids with Alkynes

ACS CATALYSIS, 3(10), 2421–2429.

By: D. Frasco n, C. Lilly n, P. Boyle n & E. Ison n

author keywords: C-H functionalization; oxidative coupling; C-H activation; Cp*Ir-III; annulation
Sources: Web Of Science, ORCID
Added: August 6, 2018

2013 journal article

Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*Ir-III(L) Complexes

ACS CATALYSIS, 3(10), 2304–2310.

By: M. Lehman n, J. Gary*, P. Boyle n, M. Sanford* & E. Ison n

author keywords: H/D exchange; C-H activation; C-H functionalization; Cp*Ir-III catalysts; kinetics; isotope effects
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2013 journal article

Electronic and Exchange Coupling in a Cross-Conjugated D–B–A Biradical: Mechanistic Implications for Quantum Interference Effects

Journal of the American Chemical Society, 135(39), 14713–14725.

By: M. Kirk*, D. Shultz n, D. Stasiw n, D. Habel-Rodriguez*, B. Stein* & P. Boyle n

TL;DR: The results reveal important excited-state contributions to the ground-state singlet-triplet splitting in this cross-conjugated D-B-A biradical that contribute to the understanding of electronic coupling in cross- Conjugated molecules and specifically to quantum interference effects. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, Crossref, ORCID
Added: August 6, 2018

2013 journal article

Solvate Structures and Computational/Spectroscopic Characterization of Lithium Difluoro(oxalato)borate (LiDFOB) Electrolytes

JOURNAL OF PHYSICAL CHEMISTRY C, 117(11), 5521–5531.

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2013 journal article

Superexchange Contributions to Distance Dependence of Electron Transfer/Transport: Exchange and Electronic Coupling in Oligo(para-Phenylene)- and Oligo(2,5-Thiophene)-Bridged Donor–Bridge–Acceptor Biradical Complexes

Journal of the American Chemical Society, 135(45), 17144–17154.

By: M. Kirk*, D. Shultz n, D. Stasiw n, G. Lewis n, G. Wang n, C. Brannen n, R. Sommer n, P. Boyle n

TL;DR: The work provides a direct measurement of superexchange contributions to β, with no contribution from incoherent hopping, and offers unique insight into the intrinsic molecular factors that govern H(DA) and β, which are important for understanding the electronic origin of electron transfer and electron transport mediated by molecular bridges. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, Crossref
Added: August 6, 2018

2013 journal article

Synthesis, Structure, Photophysics, and a DFT Study of Phosphorescent C*(NN)-N-boolean AND- and (CNN)-N-boolean AND-N-boolean AND-Coordinated Platinum Complexes

INORGANIC CHEMISTRY, 52(20), 11711–11722.

By: C. Harris*, D. Vezzu*, L. Bartolotti*, P. Boyle n & S. Huo*

MeSH headings : Crystallography, X-Ray; Luminescent Agents / chemical synthesis; Luminescent Agents / chemistry; Models, Molecular; Molecular Structure; Organoplatinum Compounds / chemical synthesis; Organoplatinum Compounds / chemistry; Photochemical Processes; Quantum Theory
TL;DR: The calculations suggested that lowest singlet and triplet excited states are characteristic of a mixed state involving one or more charge-transfer transitions such as ILCT, MLCT, and LLCT. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2013 journal article

The Electronic Nature of Terminal Oxo Ligands in Transition-Metal Complexes: Ambiphilic Reactivity of Oxorhenium Species

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(25), 9433–9441.

By: J. Smeltz n, C. Lilly n, P. Boyle n & E. Ison n

TL;DR: These are the first examples of mono-oxo d(2) metal complexes in which the oxo ligand exhibits ambiphilic reactivity, and it is shown that stoichiometric reactions between 3 and triarylphosphine (PAr3) result in the formation of triaryl phosphine oxide (OPAr3). (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2012 journal article

A boronate prochelator built on a triazole framework for peroxide-triggered tridentate metal binding

INORGANICA CHIMICA ACTA, 393, 294–303.

author keywords: Chelation therapy; Iron; Oxidative stress; Fenton chemistry; Reactive oxygen species; Prodrug
TL;DR: The synthesis and characterization of this triazole-based, self-immolative prochelator, TIP, imply that the cytotoxicity of deferasirox may not derive exclusively from its iron withholding properties. (via Semantic Scholar)
UN Sustainable Development Goal Categories
16. Peace, Justice and Strong Institutions (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2012 journal article

An Alternative Ionic Conductivity Mechanism for Plastic Crystalline Salt-Lithium Salt Electrolyte Mixtures

ADVANCED ENERGY MATERIALS, 2(11), 1343–1350.

author keywords: batteries; charge transport; doping; structure-property relationships
Source: Web Of Science
Added: August 6, 2018

2012 conference paper

Delving into the properties and solution structure of nitrile-lithium difluoro(oxalato)borate (LiDFOB) electrolytes for Li-ion batteries

Rechargeable lithium and lithium ion batteries, 41(41), 47–51.

By: S. Han, J. Allen, P. Boyle & W. Henderson

Source: NC State University Libraries
Added: August 6, 2018

2012 journal article

Electrolyte Solvation and Ionic Association II. Acetonitrile-Lithium Salt Mixtures: Highly Dissociated Salts

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 159(9), A1489–A1500.

By: D. Seo n, O. Borodin*, S. Han n, P. Boyle n & W. Henderson n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2012 journal article

Electrolyte solvation and ionic association I. acetonitrile-lithium salt mixtures: Intermediate and highly associated salts

Journal of the Electrochemical Society, 159(5), A553–565.

By: D. Seo, O. Borodin, S. Han, Q. Ly, P. Boyle & W. Henderson

Source: NC State University Libraries
Added: August 6, 2018

2012 journal article

Li+ cation coordination by acetonitrile-insights from crystallography

RSC ADVANCES, 2(21), 8014–8019.

By: D. Seo n, P. Boyle n, O. Borodin* & W. Henderson n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2012 journal article

Role of Low-Valent Rhenium Species in Catalytic Hydrosilylation Reactions with Oxorhenium Catalysts

ORGANOMETALLICS, 31(17), 5994–5997.

By: J. Smeltz n, P. Boyle n & E. Ison n

Sources: Web Of Science, ORCID
Added: August 6, 2018

2012 conference paper

Solvent-LiBF4 phase diagrams, ionic association and solubility - cyclic carbonates and lactones

Rechargeable lithium and lithium ion batteries, 41(41), 41–45.

By: J. Allen, D. Seo, Q. Ly, P. Boyle & W. Henderson

Source: NC State University Libraries
Added: August 6, 2018

2012 journal article

Synthesis of Oxorhenium Acetyl and Benzoyl Complexes Incorporating Diamidopyridine Ligands: Implications for the Mechanism of CO Insertion

ORGANOMETALLICS, 31(11), 4295–4301.

By: C. Lilly n, P. Boyle n & E. Ison n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2011 journal article

Crystal structure and physical properties of lithium difluoro(oxalato)borate (LiDFOB or LiBF(2)Ox)

JOURNAL OF POWER SOURCES, 196(22), 9737–9742.

By: J. Allen*, S. Han*, P. Boyle n & W. Henderson*

author keywords: Lithium-ion battery; LiDFOB; Lithium salt; Electrolyte; Crystal structure
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2011 journal article

Electron-Deficient Aryl beta-Diketones: Synthesis and Novel Tautomeric Preferences

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2011(5), 936–941.

By: J. Sloop*, P. Boyle n, A. Fountain, W. Pearman* & J. Swann*

author keywords: Ketones; Enols; Tautomerism; Keto-enol equilibrium; 1,3-Diketones
UN Sustainable Development Goal Categories
13. Climate Action (Web of Science)
Source: Web Of Science
Added: August 6, 2018

2011 journal article

Highly Luminescent Tridentate (NC)-C-boolean AND*N Platinum(II) Complexes Featured in Fused Five-Six-Membered Metallacycle and Diminishing Concentration Quenching

INORGANIC CHEMISTRY, 50(17), 8261–8273.

By: D. Vezzu*, D. Ravindranathan*, A. Gamer, L. Bartolotti*, M. Smith*, P. Boyle n, S. Huo*

TL;DR: A series of cyclometalating ligands were synthesized to produce N^C*N-coordinated platinum(II) complexes featured in a fused five-six-membered metallacycle, 1-6, and the structures of 1, 3, 4, and 6 were determined by single crystal X-ray crystallography. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2011 journal article

Lithium difluoro(oxalato)borate tetramethylene sulfone disolvate

Acta Crystallographica. Section E, Structure Reports Online, 67, M533–305.

By: J. Allen, P. Boyle & W. Henderson

Source: NC State University Libraries
Added: August 6, 2018

2011 journal article

Mechanism for the Activation of Carbon Monoxide via Oxorhenium Complexes

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(34), 13288–13291.

By: J. Smeltz n, P. Boyle n & E. Ison n

TL;DR: An unprecedented mechanism is proposed: CO is activated by theMetal oxo complex 1 and inserted into the rhenium-methyl bond to yield acyl complex 2, after which subsequent migration of the acyl ligand to the metal oxo ligand yields acetate complex 3. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2011 journal article

Phase Behavior of Ionic Liquid-LiX Mixtures: Pyrrolidinium Cations and TFSI- Anions - Linking Structure to Transport Properties

CHEMISTRY OF MATERIALS, 23(19), 4331–4337.

By: Q. Zhou*, P. Boyle*, L. Malpezzi*, A. Mele*, J. Shin*, S. Passerini*, W. Henderson*

author keywords: ionic liquid; battery electrolyte; lithium; LiTFSI; phase behavior
Source: Web Of Science
Added: August 6, 2018

2011 journal article

Poly[[(acetonitrile)lithium(I)]-mu(3)-tetrafluoridoborato]

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67, M547–U443.

By: D. Seo n, P. Boyle n & W. Henderson n

TL;DR: The structure of the title compound, [Li(BF4)(CH3CN)]n, consists of a layered arrangement parallel to (100) in which the Li+ cations are coordinated by three F atoms from three tetrafluoridoborate anions and an N atom from an acetonitrile molecule. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Poly[bis(acetonitrile-kappa N)bis[mu(3)-bis(trifluoromethanesulfonyl)imido-kappa O-4,O ':O '':O ''']dilithium]

Acta Crystallographica. Section E, Structure Reports Online, 67, M534–317.

By: D. Seo, P. Boyle & W. Henderson

Source: NC State University Libraries
Added: August 6, 2018

2011 journal article

Poly[diacetonitrile[mu(3)-difluoro(oxalato)borato]sodium]

Acta Crystallographica. Section E, Structure Reports Online, 67, M678–388.

By: J. Allen, P. Boyle & W. Henderson

Source: NC State University Libraries
Added: August 6, 2018

2011 journal article

Pt(II) and Pt(IV) Amido, Aryloxide, and Hydrocarbyl Complexes: Synthesis, Characterization, and Reaction with Dihydrogen and Substrates that Possess C-H Bonds

INORGANIC CHEMISTRY, 50(9), 4195–4211.

By: J. Webb*, C. Munro-Leighton n, A. Pierpont*, J. Gurkin n, T. Gunnoe*, T. Cundari*, M. Sabat*, J. Petersen*, P. Boyle n

TL;DR: Kinetic studies indicate that the reaction of ((t)bpy)Pt(Me)(NHPh) and phenylacetylene occurs via a pathway that involves [TFA] as a catalyst, and solid-state X-ray diffraction studies of the Pt(IV) complexes reveal that 1,2-addition of dihydrogen across the Pt-NHPh bond is revealed. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2011 journal article

Synthesis and characterization of oxorhenium(V) diamido pyridine complexes that catalyze oxygen atom transfer reactions

DALTON TRANSACTIONS, 40(44), 11815–11821.

By: C. Lilly n, P. Boyle n & E. Ison n

TL;DR: The detailed syntheses of complexes 1-4 incorporating the diamido pyridine (DAP) ancillary ligand (2,6-bis((mesitylamino)methyl)pyridine) are described and shown to be effective catalysts for oxygen atom transfer (OAT) reactions of PyO to PPh(3). (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2011 journal article

Synthesis of and structure-property relationships in zinc complexes of bis-metaphenylene semiquinone biradical species

Journal of Physical Organic Chemistry, 25(4), 314–321.

By: J. Sloop*, D. Shultz n, T. Coote n, B. Shepler*, U. Sullivan n, J. Kampf*, P. Boyle n

author keywords: bis(metaphenylene) semiquinone biradicals; electron paramagnetic resonance; SQUID magnetometry; substituent effects
UN Sustainable Development Goal Categories
Sources: Web Of Science, Crossref, ORCID
Added: August 6, 2018

2011 journal article

Tetrakis(acetonitrile-kappa N) lithium hexafluoridophosphate acetonitrile monosolvate

Acta Crystallographica. Section E, Structure Reports Online, 67, M1148–1301.

By: D. Seo, P. Boyle & W. Henderson

Source: NC State University Libraries
Added: August 6, 2018

2010 journal article

Binding of Carboxylic Acids by Fluorescent Pyridyl Ureas

JOURNAL OF ORGANIC CHEMISTRY, 75(24), 8450–8456.

TL;DR: NMR titrations and DFT analyses indicate that trihaloacetic acids bind in ionized form to the receptors, and Pyridine protonation disrupts an intramolecular H-bond, thereby unfolding an array of ureido NH donors for recognition of the corresponding carboxylates. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2010 journal article

Goldilocks Effect in Magnetic Bistability: Remote Substituent Modulation and Lattice Control of Photoinduced Valence Tautomerism and Light-Induced Thermal Hysteresis

Journal of the American Chemical Society, 132(17), 6261–6273.

By: R. Schmidt n, D. Shultz n, J. Martin n & P. Boyle n

Contributors: R. Schmidt n, D. Shultz n, J. Martin n & P. Boyle n

TL;DR: The coordination geometry (trans-pyridines), pyridine substitution, and crystal packing forces conspire to create the comparatively thermally stable photogenerated hs-Co(II) tautomer, thus providing an excellent handle for molecular and crystal engineering studies. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (Web of Science; OpenAlex)
Sources: Web Of Science, Crossref, ORCID
Added: August 6, 2018

2010 journal article

Improvement in Phosphorescence Efficiency through Tuning of Coordination Geometry of Tridentate Cyclometalated Platinum(II) Complexes

INORGANIC CHEMISTRY, 49(19), 8922–8928.

By: D. Ravindranathan*, D. Vezzu*, L. Bartolotti*, P. Boyle n & S. Huo*

MeSH headings : Crystallography, X-Ray; Luminescence; Models, Molecular; Molecular Dynamics Simulation; Molecular Structure; Organoplatinum Compounds / chemical synthesis; Organoplatinum Compounds / chemistry; Stereoisomerism
TL;DR: A series of tridentate cyclometalated platinum(II) complexes (C(∧)N*N)PtL (L = Cl or acetylide) featuring a fused five-six-membered metallacycle featuring a fusion of platinum and nitrogen led to a substantial improvement in phosphorescence efficiency and photophysical properties of the complexes. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2010 journal article

Mixed Anion (Phosphate/Oxalate) Bonding to Iron(III) Materials

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(7), 2301–2308.

By: F. Kizewski n, P. Boyle n, D. Hesterberg n & J. Martin n

Contributors: F. Kizewski n, P. Boyle n, D. Hesterberg n & J. Martin n

TL;DR: The critical role of the templating amine to mediate whether or not the iron(III) is reduced by the organic acid is demonstrated, which will be invaluable for the evaluation of complex environmental systems. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2010 journal article

Net Hydrogenation of Pt-NHPh Bond Is Catalyzed by Elemental Pt

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(13), 4520-+.

By: J. Webb n, A. Pierpont n, C. Munro-Leighton n, T. Gunnoe n, T. Cundari n & P. Boyle n

MeSH headings : Catalysis; Hydrogen / chemistry; Hydrogenation; Models, Molecular; Molecular Structure; Organoplatinum Compounds / chemistry; Platinum / chemistry; Time Factors
TL;DR: Mechanistic studies reveal that 1,2-addition of dihydrogen across the Pt-anilido bond to initially produce ((t)bpy)Pt(Me)(H) and free aniline is catalyzed by elemental Pt rather than through a pathway that involves direct activation of H(2) by Pt and 1, 2-add addition acrossThe Pt-NHPh bond. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2010 journal article

Phase Behavior and Crystalline Phases of Ionic Liquid-Lithium Salt Mixtures with 1-Alkyl-3-methylimidazolium Salts

CHEMISTRY OF MATERIALS, 22(3), 1203–1208.

By: Q. Zhou n, K. Fitzgerald n, P. Boyle n & W. Henderson n

Source: Web Of Science
Added: August 6, 2018

2010 journal article

Structural studies of sparsely substituted synthetic chlorins and phorbines establish benchmarks for changes in the ligand core and framework of chlorophyll macrocycles

JOURNAL OF MOLECULAR STRUCTURE, 979(1-3), 27–45.

Contributors: M. Taniguchi n, O. Mass n, P. Boyle n, Q. Tang*, J. Diers*, D. Bocian*, D. Holten*, J. Lindsey n

author keywords: Chlorophyll; Chlorin; Phorbine; Isocyclic ring; Chiral volume; Aromaticity
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2009 journal article

Aminoisoquinolines as colorimetric Hg2+ sensors: the importance of molecular structure and sacrificial base

TETRAHEDRON, 65(22), 4293–4297.

By: Y. Wan n, W. Niu n, W. Behof n, Y. Wang n, P. Boyle n & C. Gorman n

Contributors: Y. Wan n, W. Niu n, W. Behof n, Y. Wang n, P. Boyle n & C. Gorman n

TL;DR: It is shown that 3-phenyl-2-amino isoquinoline acts as a simple mercury sensor and is simple to synthesize. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2009 journal article

Chlorination of Boron on a Ruthenium-Coordinated Hydridotris(pyrazolyl)borate (Tp) Ligand: A Caveat for the Use of TpRu(PPh3)(2)Cl

ORGANOMETALLICS, 28(1), 374–377.

By: N. Foley n, R. Abernethy n, T. Gunnoe n, A. Hill n, P. Boyle n & M. Sabat n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2009 journal article

Six-, Five-, and Four-Coordinate Ruthenium(II) Hydride Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones

ORGANOMETALLICS, 28(6), 1758–1775.

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2009 journal article

Synthesis of Oxorhenium(V) Complexes with Diamido Amine Ancillary Ligands and Their Role in Oxygen Atom Transfer Catalysis

INORGANIC CHEMISTRY, 48(23), 11058–11066.

By: Y. Feng n, J. Aponte n, P. Houseworth n, P. Boyle n & E. Ison n

MeSH headings : Amines / chemistry; Catalysis; Crystallography, X-Ray; Ligands; Models, Molecular; Molecular Structure; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Oxygen / chemistry; Rhenium / chemistry; Stereoisomerism
TL;DR: Although the Re(VII) intermediate could not be isolated, its activity in OAT reactions was probed by competition experiments with PPh(3) and four para-substituted triarylphosphines, suggesting that the OAT reaction in these five-coordinate complexes appears to be governed by isomerization of the starting complex. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2009 journal article

X-ray and molecular modelling studies of 4-[N-alkylamino]azobenzene dyes

DYES AND PIGMENTS, 82(3), 299–306.

By: L. He*, A. El-Shafei*, H. Freeman* & P. Boyle*

Contributors: L. He*, A. El-Shafei*, H. Freeman* & P. Boyle*

author keywords: Aminoazobenzene dyes; DFT calculations; Solvatochromism; X-ray diffraction; Polarizability; Asymmetric molecules
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2008 journal article

Activation of sp(3) carbon-hydrogen bonds complex and subsequent metal-mediated formation

Angewandte Chemie [International Edition in English], 47(4), 726–730.

By: N. Foley, T. Gunnoe, T. Cundari, P. Boyle & J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex

Inorganic Chemistry, 47(14), 6124–6126.

By: C. Munro-Leighton, Y. Feng, J. Zhang, N. Alsop, T. Gunnoe, P. Boyle, J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2008 journal article

Ruthenium(II) complexes possessing the eta(6)-p-cymene ligand

INORGANICA CHIMICA ACTA, 361(11), 3254–3262.

By: T. Sumiyoshi n, T. Gunnoe n, J. Petersen* & P. Boyle n

author keywords: p-cymene; ruthenium; acetylacetonate; half-sandwich complex
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2007 journal article

Addition of s-h bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes

INORGANIC CHEMISTRY, 46(7), 2365–2367.

By: S. Delp n, C. Munro-Leighton n, L. Goj n, M. Ramirez n, T. Gunnoe n, J. Petersen n, P. Boyle n

MeSH headings : Alkenes / chemistry; Catalysis; Copper / chemistry; Electrons; Hydrogen / chemistry; Ligands; Models, Molecular; Molecular Conformation; Sulfhydryl Compounds / chemistry; Sulfur / chemistry
TL;DR: A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2007 journal article

Combined experimental and computational study of TpRu{P(pyr)(3)}(NCMe)Me (pyr = N-pyrrolyl): Inter- and intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins

ORGANOMETALLICS, 26(23), 5507–5516.

Source: Web Of Science
Added: August 6, 2018

2007 journal article

Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. Part 3: Spectral and structural properties

TETRAHEDRON, 63(18), 3850–3863.

By: M. Taniguchi n, M. Ptaszek n, B. McDowell n, P. Boyle n & J. Lindsey n

Contributors: M. Taniguchi n, M. Ptaszek n, B. McDowell n, P. Boyle n & J. Lindsey n

author keywords: chlorin; NMR; absorption spectra; X-ray
TL;DR: The studies described herein report absorption spectra of diverse chlorins, comparative NMR features of chlorins bearing 0-3 meso-aryl substituents, and X-ray structures of the fully unsubstituted chlorin and the oxochlorin. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2007 journal article

Substituent Effects on Exchange Coupling:  5-Aryl-Substituted Semiquinones and Their Complexes with MnIIand CuII

Inorganic Chemistry, 46(1), 273–277.

By: D. Shultz n, J. Sloop n, T. Coote n, M. Beikmohammadi n, J. Kampf n & P. Boyle n

TL;DR: For the MnII complexes, electron-withdrawing substituents on the phenyl ring have greater ferromagnetic J values than the CuII complexes of SQ ligands with electron-donating substituent, which suggests a FM contribution from MLCT excited states in the copper complexes. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, Crossref, ORCID
Added: August 6, 2018

2007 journal article

Synthesis and structural properties of porphyrin analogues of bacteriochlorophyll c

TETRAHEDRON, 63(51), 12629–12638.

By: M. Ptaszek n, Z. Yao n, D. Savithri n, P. Boyle n & J. Lindsey n

Sources: Web Of Science, ORCID
Added: August 6, 2018

2006 journal article

Chemistry surrounding monomeric copper(I) methyl, phenyl, anilido, ethoxide, and phenoxide complexes supported by N-heterocyclic carbene ligands: Reactivity consistent with both early and late transition metal systems

Inorganic Chemistry, 45(22), 9032–9045.

By: L. Goj n, E. Blue n, S. Delp n, T. Gunnoe n, T. Cundari n, A. Pierpont n, J. Petersen n, P. Boyle n

TL;DR: DFT calculations suggest that the HOMO for the series of Cu anilido complexes is localized primarily on the amido nitrogen with some ppi(anilido)-dpi(Cu) pi-character. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Protonation of N-heterocyclic carbene ligand coordinated to copper(I): Coordination mode of imidazolium cation as a function of counterion as determined by solid-state structures

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691(26), 5988–5993.

By: E. Blue n, T. Gunnoe n, J. Petersen* & P. Boyle n

author keywords: copper; N-heterocyclic carbene; imidazolium
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Synthesis and Properties of Pyrazine-Pillared Ag3Mo2O4F7 and AgReO4 Layered Phases

Journal of Solid State Chemistry, 179(1), 217–225.

By: H. Lin n, B. Yan n, P. Boyle n & P. Maggard n

author keywords: pillared; layered; perrhenate; molybdate; optical properties; pyrazine; extended Huckel calculations
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2005 journal article

Chiroptical switching polyguanidine synthesized by helix-sense-selective polymerization using [(R)-3,3 '-dibromo-2,2 '-binaphthoxy](di-tert-butoxy)titanium(IV) catalyst

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127(7), 2136–2142.

By: H. Tang n, P. Boyle n & B. Novak n

TL;DR: Interestingly, poly-1b was found to undergo fast reversible chiroptical switching at +38.5 degrees C in toluene, and this is the first example of chiroPTical switching phenomenon occurring in a helical polymer possessing no chiral moieties in the polymer chains. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2005 journal article

Synthesis of the five-coordinate ruthenium(II) Complexes [(PCP)Ru(CO)(L)][BAr'(4)] {PCP=2,6-((CH2PBu2)-Bu-t)(2)C6H3, BAr'(4) 3,5-(CF3)(2)C6H3, L = eta(1)-ClCH2Cl, eta-N-2, or mu-Cl-Ru(PCP)(CO)}: Reactions with phenyldiazomethane and phenylacetylene

Inorganic Chemistry, 44(23), 8379–8390.

By: J. Zhang, K. Barakat, T. Cundari, T. Gunnoe, P. Boyle, J. Petersen, C. Day

Source: NC State University Libraries
Added: August 6, 2018

2004 journal article

Ethylene polymerization catalyzed by neutral nickel(II) complex with ON-chelating ligand

POLYMER JOURNAL, 36(2), 140–145.

By: M. Nodono*, B. Novak n & P. Boyle n

author keywords: neutral nickel complex; ethylene polymerization; oligomerization; polyethylene
Source: Web Of Science
Added: August 6, 2018

2004 journal article

Non-mutagenic organic pigment intermediates. II. Isomorphous 2,2 '-dichloro-5,5 '-dipropoxybenzidine and 2,2 '-dimethyl-5,5 '-dipropoxybenzidine

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 60(8), O569–O571.

By: A. El-Shafei n, D. Hinks n, P. Boyle n & H. Freeman n

Contributors: A. El-Shafei n, D. Hinks n, P. Boyle n & H. Freeman n

TL;DR: The title compounds, C 18 H 22 Cl 2 N2 O 2 and C 20 H 28 N 2 O 2 , respectively, are isomorphous and exhibit weak N-H...N hydrogen bonding, which is influenced by the differences in hybridization around the amine N atoms. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2004 journal article

Ruthenium(II) anilido complex containing a bisphosphine pincer ligand: Reversible formation of amidinate ligands via intramolecular C-N bond formation

ORGANOMETALLICS, 23(13), 3094–3097.

By: J. Zhang n, T. Gunnoe n & P. Boyle n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2004 journal article

Synthesis of [NH4]MnCl2(OAc) and [NH4](2)MnCl4(H2O)(2) by solvothermal dehydration and structure/property correlations in a one-dimensional antiferromagnet

INORGANIC CHEMISTRY, 43(10), 3242–3247.

By: J. Martin n, R. Hess n & P. Boyle n

Contributors: J. Martin n, R. Hess n & P. Boyle n

TL;DR: The utility of the solvothermal dehydration strategy whereby superheated acetonitrile reacts with water of hydration to form ammonium acetate is demonstrated in the synthesis of [NH(4)]MnCl(2)(OAc), I, and [NH (4)](2)Mn Cl(4)(H( 2)O)(2), II, from MnCl( 2).4H(1)O. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2003 journal article

Dynamic disorder and conformer exchange in the crystalline monomer of polycarbonate

JOURNAL OF PHYSICAL CHEMISTRY B, 107(48), 13293–13299.

By: J. Wolak n, J. Knutson n, J. Martin n, P. Boyle n, A. Sargent n & J. White n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2003 journal article

Excited-state energy-transfer dynamics in self-assembled triads composed of two porphyrins and an intervening bis(dipyrrinato)metal complex

INORGANIC CHEMISTRY, 42(21), 6629–6647.

TL;DR: Results indicate that bis(dipyrrinato)zinc(II) complexes can serve as self-assembling linkers that further function as secondary light-collection elements in porphyrin-based light-harvesting arrays. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2003 journal article

Mechanisms of Exchange Modulation in Trimethylenemethane-type Biradicals:  The Roles of Conformation and Spin Density

Journal of the American Chemical Society, 125(50), 15426–15432.

By: D. Shultz n, R. Fico n, H. Lee n, J. Kampf n, K. Kirschbaum n, A. Pinkerton n, P. Boyle n

TL;DR: Comparison of results obtained for the isostructural series of bis(semiquinone) biradicals shows that both the magnitude of J and the resistance of ferromagnetic J to bond torsions is proportional to the spin density adjacent to the exchange coupler. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2003 journal article

Non-mutagenic organic pigment intermediates. I. 3,3 '-Dipropoxybenzidine

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 59(2), O71–O73.

By: A. El-Shafei n, P. Boyle n, D. Hinks n & H. Freeman n

Contributors: A. El-Shafei n, P. Boyle n, D. Hinks n & H. Freeman n

MeSH headings : Benzidines / chemistry; Crystallography, X-Ray; Fourier Analysis; Hydrogen Bonding; Models, Molecular; Mutagens; Pigments, Biological / chemistry
TL;DR: Crystals of the title compound were grown from ethanol by slow evaporation and the structure has been determined, forming an infinite two-dimensional array of N-H interactions parallel to the (101) direction. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2003 journal article

Octahedral Ru(II) amido complexes TpRu(L)(L ')(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L ' = P(OMe)(3) or PMe3 or L = CO and L ' = PPh3; R = H, Ph, or Bu-t): Synthesis, characterization, and reactions with weakly acidic C-H bonds

INORGANIC CHEMISTRY, 42(15), 4759–4772.

By: D. Conner n, K. Jayaprakash n, M. Wells n, S. Manzer n, T. Gunnoe n & P. Boyle n

TL;DR: Kinetic studies indicate that the reaction of TpRu(PMe(3))(2)(NHPh) with phenylacetylene occurs via a pathway that involves Tp Ru(P me(3)(2)Ru[double bond]C[double Bond]C(H)Ph][OTf], and [TpRu (PMe (3)).[OTf] as catalyst. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2003 journal article

Radical polymerization of styrene and methyl methacrylate with Ruthenium(II) complexes

ORGANOMETALLICS, 22(23), 4692–4698.

By: B. Arrowood n, M. Lail n, T. Gunnoe n & P. Boyle n

Source: Web Of Science
Added: August 6, 2018

2003 journal article

Synthesis and properties of V6O16CU(C4H4N2)(2)(.)(H2O)(0.22(1)): Charge density matching of a metal-segregated layer structure

INORGANIC CHEMISTRY, 42(14), 4250–4252.

By: P. Maggard n & P. Boyle n

TL;DR: In contrast to the plethora of recently synthesized metal-oxide clusters, chains, and networks in the VO(x)/M/L system, this compound is a relatively rare example that contains two different metals distributed into distinct layers. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2003 journal article

Trends in exchange coupling for trimethylenemethane-type bis(semiquinone) biradicals and correlation of magnetic exchange with mixed valency for cross-conjugated systems

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(38), 11761–11771.

TL;DR: The results suggest that delocalization in the cross-conjugated, mixed-valent radical anions is proportional to the ferromagnetic contribution to the exchange coupling in the biradical oxidation states. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2002 journal article

An inexpensive carbohydrate derivative used as a chiral auxiliary in the synthesis of alpha-hydroxy carboxylic acids

TETRAHEDRON, 58(38), 7663–7679.

By: H. Yu n, C. Ballard n, P. Boyle n & B. Wang n

author keywords: chiral auxiliary; carbohydrate; asymmetric synthesis; hydroxy carboxylic acid; enolate alkylation; glycolate alkylation
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2002 journal article

Influence of filled d pi-manifold and L/L ' ligands on the structure, basicity, and bond rotations of the octahedral and d(6) amido complexes TpRu(L)(L ')(NHPh) (Tp = hydridotris(pyrazolyl)borate; L= L ' = PMe3 or P(OMe)(3), or L = CO and L ' = PPh3): Solid-state structures of [TpRu(PMe3)(2)(NH2Ph)][OTf], [TpRu{P(OMe)(3)}(2)(NH2Ph)][OTf], and TpRu{P(OMe)(3)}(2)(NHPh)

INORGANIC CHEMISTRY, 41(11), 3042–3049.

By: D. Conner n, K. Jayaprakash n, T. Gunnoe n & P. Boyle n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2002 journal article

Ruthenium(II) anilido complexes TpRuL(2)(NHPh): Oxidative 4,4 '-aryl coupling reactions (Tp = hydridotris(pyrazolylborate); L = PMe3, P(OMe)(3), or CO)

ORGANOMETALLICS, 21(24), 5265–5271.

By: D. Conner n, K. Jayaprakash n, T. Gunnoe n & P. Boyle n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2002 journal article

Synthesis and crystal structure of a dinuclear palladium complex containing C,O-bridging ester-enolato moieties

ORGANOMETALLICS, 21(7), 1462–1465.

By: G. Tian n, P. Boyle n & B. Novak n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2001 journal article

Observation of a hysteretic phase transition in a crystalline dinitroxide biradical that leads to magnetic bistability

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 123(42), 10403–10404.

By: D. Shultz n, R. Fico n, P. Boyle n & J. Kampf n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2001 journal article

Preparation of the octahedral d(6) amido complex TpRu(CO)(PPh3)(NHPh) (Tp = hydridotris(pyrazolyl)borate): Solid-state structural characterization and reactivity

INORGANIC CHEMISTRY, 40(25), 6481–6486.

By: K. Jayaprakash n, T. Gunnoe n & P. Boyle n

TL;DR: Variable temperature NMR studies have revealed a rotational barrier around the ruthenium-amido nitrogen bond of 3 of 12 kcal/mol (transformation of the major isomer to the minor isomer). (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2001 journal article

[(Zr6B)Cl11-xI2+x] (0 <= x <= 6): A new mixed-halide structure with zigzag chains of clusters in multiply twinned crystals

INORGANIC CHEMISTRY, 40(7), 1439–1444.

By: M. Kockerling*, J. Willems* & P. Boyle n

TL;DR: The new [(Zr6B)Cl11-xI2+x] phase (with 0 < or = x = or = 6) is obtained from reactions of ZrI4, ZrCl4, and elemental Zr and B for 2-4 weeks in sealed Ta tubing at 800-850 degrees C. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2000 journal article

Evidence for spontaneous, reversible paracyclophane formation. Aprotic solution structure of the boron neutron capture therapy drug, L-p-boronophenylalanine

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, (3), 557–561.

By: B. Shull*, D. Spielvogel, R. Gopalaswamy*, S. Sankar n, P. Boyle n, G. Head, K. Devito*

TL;DR: Variable temperature 1H NMR found that the two pairs of aromatic protons of the cyclophane dimer coalesce at Tc = 141 °C, corresponding to a ΔG‡ =–20.6 kcal mol−1.6, and it is proposed that this species is a paracyclophaneDimer of L-p-BPA in which one molecule of L/O chelates head-to-tail with another. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2000 journal article

Rational synthesis of beta-substituted chlorin building blocks

JOURNAL OF ORGANIC CHEMISTRY, 65(23), 7919–7929.

By: T. Balasubramanian n, J. Strachan n, P. Boyle n & J. Lindsey n

MeSH headings : Fluorescence; Porphyrins / chemical synthesis
TL;DR: A route pioneered by Battersby is adapted to gain access to chlorins that bear two meso substituents, a geminal dimethyl group to lock in the chlorin hydrogenation level, and no flanking meso and beta substituENTS. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

1999 journal article

Hybrid organic-inorganic, hexa-arm dendrimers based on an Mo6Cl8 core

CHEMICAL COMMUNICATIONS, (10), 877–878.

By: C. Gorman*, W. Su*, H. Jiang, C. Watson* & P. Boyle*

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

1999 journal article

Refined synthesis of 5-substituted dipyrromethanes

JOURNAL OF ORGANIC CHEMISTRY, 64(4), 1391–1396.

By: B. Littler n, M. Miller n, C. Hung n, R. Wagner n, . DF O'Shea, P. Boyle n, J. Lindsey n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

1999 journal article

The Pt-195 NMR of L2Pt(1,2-dithiolene) complexes

INORGANIC CHEMISTRY, 38(10), 2294–2302.

By: C. Keefer n, R. Bereman n, S. Purrington n, B. Knight n & P. Boyle n

Source: Web Of Science
Added: August 6, 2018

1999 journal article

The first systematic synthesis of heterobimetallic dithiolene-bridged complexes. Synthesis and characterization of metal complexes of 4-(1 ',2 '-ethylenedithiolate)-1,3-dithiole-2-one and dimeric metal complexes of 1,2,3,4-butadienetetrathiolate

INORGANIC CHEMISTRY, 38(23), 5437–5442.

By: C. Keefer n, S. Purrington n, R. Bereman n & P. Boyle n

Source: Web Of Science
Added: August 6, 2018

1998 journal article

Coordination chemistry of a tripodal S2ON ligand: Syntheses, structures, and reactivity of the molybdenum(VI) and nickel(II) complexes of bis(2-mercaptoethyl)-2-amino-4-methylphenol (H(3)btap) and comparison to (VO)-O-v(btap)

INORGANIC CHEMISTRY, 37(22), 5851–5855.

By: C. Cornman n, K. Jantzi n, J. Wirgau n, T. Stauffer n, J. Kampf n & P. Boyle n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

1998 journal article

Intramolecular photocycloaddition of a tethered bis-2,3-dihydro-4-pyridone: Stereochemistry and reactivity of the cycloadduct

TETRAHEDRON LETTERS, 39(3-4), 187–190.

By: D. Comins*, Y. Lee & P. Boyle*

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

1998 journal article

Methylxanthines. II. Anhydrous theobromine

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 54, 1980–1983.

By: K. Ford, Y. Ebisuzaki* & P. Boyle*

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

1998 journal article

Structural studies of a borane-modified phosphate diester linkage: Ab initio calculations on the dimethylboranophosphate anion and the single-crystal X-ray structure of its diisopropylammonium salt

INORGANIC CHEMISTRY, 37(17), 4158–4159.

By: J. Summers n, D. Roe n, P. Boyle n, M. Colvin n & B. Shaw n

TL;DR: The dimethylboranophosphate anion was characterized by ab initio calculations and by X-ray crystallography and the relevance of the structure to boranoph phosphate nucleotide analogues is discussed. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

1998 journal article

The synthesis and characterization of platinum monodithiolene complexes containing 1,3-dithiole-2-oxo-4,5-dithiolate (dmid(2-)) and 1,3-dithiole-2-thione-4,5-dithiolate (dmit(2-))

INORGANICA CHIMICA ACTA, 282(2), 200–208.

By: C. Keefer n, S. Purrington n, R. Bereman n, B. Knight n, D. Bedgood* & P. Boyle n

author keywords: crystal structures; platinum complexes; dithiolene complexes; platinum-195 NMR
Source: Web Of Science
Added: August 6, 2018

1998 journal article

alpha- and beta-CuAlCl4: Framework construction using corner-shared tetrahedral metal-halide building blocks

INORGANIC CHEMISTRY, 37(6), 1341–1346.

By: J. Martin n, B. Leafblad n, R. Sullivan n & P. Boyle n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

1997 journal article

Methylxanthines .1. Anhydrous theophylline

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 53, 777–779.

By: Y. Ebisuzaki*, P. Boyle* & J. Smith*

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

1997 journal article

Oxidation of a vanadium(V)-dithiolate complex to a vanadium(V)-eta(2),eta(2)-disulfenate complex

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 119(25), 5986–5987.

By: C. Cornman n, T. Stauffer n & P. Boyle n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

1997 journal article

Stabilization of the (pi-indenyl)-lead bond: The first structurally authenticated bis(eta(5)-indenyl) complex of a post-transition element, [Pb{1,3-(SiMe3)(2)C9H5}(2)]

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 36(21), 2378–2379.

By: J. Overby*, T. Hanusa* & P. Boyle n

author keywords: indenyl complexes; lead; sandwich complexes; structure elucidation
Source: Web Of Science
Added: August 6, 2018

1997 journal article

Structural and electron paramagnetic resonance studies of the square pyramidal to trigonal bipyramidal distortion of vanadyl complexes containing sterically crowded Schiff base ligands

INORGANIC CHEMISTRY, 36(27), 6401–6408.

By: C. Cornman n, K. Geiser-Bush n, S. Rowley n & P. Boyle n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

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