Works (22)

Updated: July 14th, 2023 21:18

2016 journal article

An approach towards tailoring interfacial structures and properties of multiphase renewable thermoplastics from lignin-nitrile rubber

GREEN CHEMISTRY, 18(20), 5423–5437.

Source: Web Of Science
Added: August 6, 2018

2016 journal article

Structural analysis of hardwood native lignins by quantitative C-13 NMR spectroscopy

HOLZFORSCHUNG, 70(2), 95–108.

By: M. Balakshin*, E. Capanema*, R. Santos n, H. Chang n & H. Jameel n

author keywords: C-13 NMR; hardwood; lignin structural analysis; milled wood lignin (MWL); S/G ratio
UN Sustainable Development Goal Categories
15. Life on Land (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2015 journal article

HOW WELL DO MWL AND CEL PREPARATIONS REPRESENT THE WHOLE HARDWOOD LIGNIN?

JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 35(1), 17–26.

By: E. Capanema n, M. Balakshin n, R. Katahira n, H. Chang n & H. Jameel n

author keywords: Lignin; lignin-carbohydrate complex (LCC); milled wood lignin (MWL); cellulolytic enzyme lignin (CEL); NMR spectroscopy
Source: Web Of Science
Added: August 6, 2018

2012 journal article

Lignin Structural Variation in Hardwood Species

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 60(19), 4923–4930.

By: R. Santos n, E. Capanema n, M. Balakshin n, H. Chang n & H. Jameel n

author keywords: S/G ratio; S/V ratio; lignin; hardwoods; C-13 NMR
MeSH headings : Lignin / chemistry; Magnetic Resonance Spectroscopy; Molecular Structure; Oxidation-Reduction; Trees / chemistry; Wood / chemistry
TL;DR: Significant variations in lignin structures, such as syringylpropane/guaiacylpropane ratio (S/G ratio), arylglycerol-β-aryl ether (β-O-4), degree of condensation, and elemental and methoxyl contents, were found among the hardwood species studied. (via Semantic Scholar)
UN Sustainable Development Goal Categories
15. Life on Land (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2011 journal article

Lignin Changes after Steam Explosion and Laccase-Mediator Treatment of Eucalyptus Wood Chips

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 59(16), 8761–8769.

author keywords: Eucalyptus globulus; steam explosion; laccase-mediator system; thermogravimetric analyses (TGA); milled wood lignin (MWL); 2D NMR; HSQC; quantitative C-13 NMR; lignin thermal properties; lignin chemistry
MeSH headings : Eucalyptus / chemistry; Laccase; Lignin / analysis; Pressure; Steam; Wood / chemistry
TL;DR: Thermogravimetic analyses of whole meal obtained from chips before and after steam explosion indicated an increase in lignin degradation temperature due to lignIn condensation, and application of LMS treatment caused a reduction in lIGNin and polysaccharide degradation temperatures. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2011 journal article

Quantification of lignin-carbohydrate linkages with high-resolution NMR spectroscopy

PLANTA, 233(6), 1097–1110.

By: M. Balakshin n, E. Capanema n, H. Gracz n, H. Chang n & H. Jameel n

author keywords: Lignin-carbohydrate complex; Benzyl ether LCC linkages; Phenyl glycoside linkages; Ester LCC linkages; Quantitative HSQC NMR technique
MeSH headings : Betula / chemistry; Betula / metabolism; Carbohydrate Conformation; Carbohydrate Metabolism; Carbohydrates / chemistry; Lignin / chemistry; Lignin / metabolism; Molecular Structure; Nuclear Magnetic Resonance, Biomolecular / methods; Pinus taeda / chemistry; Pinus taeda / metabolism; Wood / chemistry
TL;DR: The data obtained indicate that pinewood contains higher amounts of benzyl ether LCC linkages, but lower amounts of phenyl glycoside and γ-ester LCC moieties as compared to birch wood. (via Semantic Scholar)
Source: Web Of Science
Added: August 6, 2018

2009 journal article

Label-free in situ imaging of lignification in the cell wall of low lignin transgenic Populus trichocarpa

PLANTA, 230(3), 589–597.

By: M. Schmidt*, A. Schwartzberg*, P. Perera*, A. Weber-Bargioni*, A. Carroll*, P. Sarkar*, E. Bosneaga*, J. Urban* ...

author keywords: Populus trichocarpa (black cottonwood); Cell wall; Lignin; Microspectroscopy; Raman imaging; Transgenic
MeSH headings : Cell Wall / metabolism; Lignin / metabolism; Plants, Genetically Modified / cytology; Plants, Genetically Modified / metabolism; Populus / cytology; Populus / metabolism; Spectrum Analysis, Raman
TL;DR: Lignification in wild type and lignin-reduced 4CL transgenic Populus trichocarpa stem wood with spatial resolution that is sub-μm is compared, suggesting that transgenic approach may help overcome cell wall recalcitrance to wood saccharification. (via Semantic Scholar)
Source: Web Of Science
Added: August 6, 2018

2007 journal article

MWL fraction with a high concentration of lignin-carbohydrate linkages: Isolation and 2D NMR spectroscopic analysis

HOLZFORSCHUNG, 61(1), 1–7.

By: M. Balakshin n, E. Capanema n & H. Chang n

author keywords: 2D NMR; ester lignin-carbohydrate bonds; ether lignin-carbohyd rate bonds; lignin-carbohydrate complex (LCC); loblolly pine; milled wood lignin (MWL); phenyl glycoside linkages
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Oxidative ammonolysis of technical lignins. Part 4. Effects of the ammonium hydroxide concentration and pH

JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 26(1), 95–109.

By: E. Capanema n, M. Balakshin n, C. Chen n & J. Gratzl n

author keywords: technical lignins; oxidative ammonolysis; kinetics of ammonium hydroxide concentration
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2005 article

NMR studies on Fraser fir Abies fraseri (Pursh) Poir. Lignins (vol 59, 488, 2005)

HOLZFORSCHUNG, Vol. 59, pp. 706–706.

By: M. Balakshin n, E. Capanema n, B. Goldfarb n, J. Frampton n & J. Kadla n

Source: Web Of Science
Added: August 6, 2018

2005 journal article

Quantitative characterization of a hardwood milled wood lignin by nuclear magnetic resonance spectroscopy

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 53(25), 9639–9649.

By: E. Capanema n, M. Balakshin n & J. Kadla n

author keywords: correlation 2D NMR; hardwood; lignin; milled wood lignin (MWL); quantitative C-13 NMR
MeSH headings : Eucalyptus / chemistry; Lignin / chemistry; Magnetic Resonance Spectroscopy; Molecular Structure; Oxidation-Reduction; Wood
TL;DR: The combination of 2D NMR and quantitative 13C NMR spectroscopy of nonacetylated and acetylated lignin preparations allowed reliable identification and calculation of the amount of different lign in structures. (via Semantic Scholar)
Source: Web Of Science
Added: August 6, 2018

2005 journal article

Rapid screening of wood chemical component variations using transmittance near-infrared spectroscopy

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 53(9), 3328–3332.

By: T. Yeh n, T. Yamada n, E. Capanema n, H. Chang n, V. Chiang n & J. Kadla n

author keywords: Loblolly pine (Pinus taeda); aspen (Populus trichocarpa); transmittance near-infrared spectroscopy (NIR); increment cores; wood wafer; alpha-cellulose content; lignin content; screening
MeSH headings : Cellulose / analysis; Lignin / analysis; Pinus taeda / chemistry; Populus / chemistry; Spectroscopy, Near-Infrared / methods; Wood
TL;DR: A rapid transmittance near-infrared (NIR) spectroscopy method was developed to predict the variation in chemical composition of solid wood and correlations were obtained between laboratory wet chemistry values and the NIR-predicted values. (via Semantic Scholar)
Source: Web Of Science
Added: August 6, 2018

2004 journal article

A comprehensive approach for quantitative lignin characterization by NMR spectroscopy

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 52(7), 1850–1860.

By: E. Capanema n, M. Balakshin n & J. Kadla n

author keywords: lignin; milled wood lignin (MWL); quantitative C-13 NMR spectroscopy; HMQC NMR technique
MeSH headings : Acetylation; Lignin / analysis; Lignin / chemistry; Magnetic Resonance Spectroscopy / methods; Picea / chemistry; Wood
TL;DR: Comparison of the calculated results with known databases on spruce MWL structure shows that the suggested approach is rather informative and comparable with the information obtained from the combination of various wet chemistry methods. (via Semantic Scholar)
Source: Web Of Science
Added: August 6, 2018

2004 journal article

An improved procedure for isolation of residual lignins from hardwood kraft pulps

HOLZFORSCHUNG, 58(5), 464–472.

By: E. Capanema n, M. Balakshin n & C. Chen n

author keywords: cellulase; enzymatic hydrolysis; hardwood kraft pulp; hemicellulase; lignin-carbohydrate complex; residual lignin
Source: Web Of Science
Added: August 6, 2018

2004 conference paper

Tracking down the effects of a rare mutant gene in loblolly pine: a first report

2004 Paper Summit, Spring Technical and International Environmental Conference. CD-ROM published by TAPPI, Norcross, GA.

By: Q. Yu, E. Capanema, V. Batista, S. Josserand, G. Johnson, C. Nelson, S. McKeand, J. MacKay ...

Source: NC State University Libraries
Added: August 6, 2018

2003 journal article

Comparative studies on oxidation of lignin model compounds with hydrogen peroxide using Mn(IV)-Me(3)TACN and Mn(IV)-Me4DTNE as catalyst

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 206(1-2), 37–51.

By: V. Alves n, E. Capanema n, C. Chen n & J. Gratzl n

author keywords: lignin model compounds; binucleus Mn(IV) complexes; oxidation; hydrogen peroxide; catalysis; reaction kinetics; reaction mechanisms; catalytic cycle; epoxidation of conjugated double bonds
Source: Web Of Science
Added: August 6, 2018

2003 journal article

Comparative studies on the delignification of pine kraft-anthraquinone pulp with hydrogen peroxide by binucleus Mn(IV) complex catalysis

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 51(21), 6223–6232.

By: C. Chen n, E. Capanema n & H. Gracz n

author keywords: pine kraft-AQ pulp; binucleus Mn(IV) complex; hydrogen peroxide bleaching; catalysis; residual lignins; alkaline-soluble lignin; 2D HMQC NMR; epoxidation; oxidative cleavage
MeSH headings : Catalysis; Cellulase / metabolism; Hydrogen Peroxide / chemistry; Hydrogen-Ion Concentration; Hydrolysis; Lignin / chemistry; Magnetic Resonance Spectroscopy; Manganese / chemistry; Pinus / chemistry; Solubility; Solutions; Stilbenes / chemistry; Wood
TL;DR: The results showed that biphenyl (5-5) and stilbene structures of the residual lignin in the pulp are preferentially degraded in both the C1- and C2-catalyzed bleachings, whereas beta-O-4, beta-5, and beta-beta structures undergo degradation to a lesser extent. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2003 journal article

Elucidation of the structures of residual and dissolved pine kraft lignins using an HMQC NMR technique

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 51(21), 6116–6127.

By: M. Balakshin n, E. Capanema n, C. Chen n & H. Gracz n

author keywords: residual lignin; kraft lignin; kraft pulping; NMR; 2D HMQC technique; lignin-carbohydrate complex; condensation reactions; lignin degradation products
MeSH headings : Carbohydrate Conformation; Carbohydrates / analysis; Industry; Lignin / chemistry; Lignin / isolation & purification; Magnetic Resonance Spectroscopy / methods; Molecular Structure; Pinus / chemistry; Wood
TL;DR: Elucidation of the role of condensation reactions indicates that an increase in the degree of lignin condensation during pulping results from accumulation of original condensed lign in moieties rather than from the formation of new alkyl-aryl structures. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2003 journal article

Reaction mechanisms in delignification of pine Kraft-AQ pulp with hydrogen peroxide using Mn(IV)-Me4DTNE as catalyst

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 51(7), 1932–1941.

By: C. Chen n, E. Capanema n & H. Gracz n

author keywords: pine Kraft-AQ pulp; binucleus Mn(IV) complex; hydrogen peroxide bleaching; catalysis; residual lignins; alkaline soluble lignin; 2D HMQC NMR spectroscopic technique; epoxidation of conjugated double bonds
MeSH headings : Hydrogen Peroxide / chemistry; Lignin / analysis; Lignin / chemistry; Magnetic Resonance Spectroscopy; Organometallic Compounds / chemistry; Wood
TL;DR: The results showed that biphenyl (5-5) and stilbene structures are preferentially degraded in the bleaching process, while beta-O-4, beta-5, and beta-beta structures undergo degradation only to a lesser extent, which implies that hydrogen peroxide bleaching using the catalyst is more effective in delignification of softwood pulps than hard wood pulps. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2002 journal article

Oxidative ammonolysis of technical lignins - Part 3. Effect of temperature on the reaction rate

HOLZFORSCHUNG, 56(4), 402–415.

By: E. Capanema*, M. Balakshin*, C. Chen*, J. Gratzl* & A. Kirkman*

author keywords: technical lignins; oxidative ammonolysis of lignins; kinetics of ammonolysis; effect of temperature; nitrogen incorporation; lignin solubiliztion
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2001 journal article

Oxidative ammonolysis of technical lignins - Part 1. Kinetics of the reaction under isothermal condition at 130 degrees C

HOLZFORSCHUNG, 55(4), 397–404.

By: E. Capanema*, M. Balakshin*, C. Chen*, J. Gratzl* & A. Kirkman*

author keywords: technical lignins; oxidative ammonolysis; kinetics; isothermal condition; composition of N-modified lignins
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2001 journal article

Oxidative ammonolysis of technical lignins - Part 2. Effect of oxygen pressure

HOLZFORSCHUNG, 55(4), 405–412.

By: E. Capanema*, M. Balakshin*, C. Chen*, J. Gratzl* & A. Kirkman*

author keywords: technical lignins; oxidative ammonolysis; kinetics; oxygen; composition of N-modified lignins
Source: Web Of Science
Added: August 6, 2018

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