Works (38)

Updated: April 4th, 2024 08:39

2024 journal article

Creep and recovery in dense suspensions of smooth and rough colloids

JOURNAL OF RHEOLOGY, 68(2), 205–217.

By: Y. Saraswat n, E. Kerstein n & L. Hsiao n

author keywords: Surface roughness; Particle jamming; Colloidal suspensions; Yielding; Creep; Recovery
Sources: ORCID, Web Of Science, NC State University Libraries
Added: February 5, 2024

2024 article

Isothermal Titration Calorimetry Reveals Entropy-Driven Bisphenol A Epoxy Resin Adhesion to Metal Oxide Surfaces

Jani, P. K., Farias, B. V., Jain, R. K., Houston, K. R., Velev, O. D., Santiso, E. E., … Khan, S. A. (2024, January 31). MACROMOLECULES, Vol. 1.

By: P. Jani n, B. Farias n, R. Jain n, K. Houston*, O. Velev n, E. Santiso n, L. Hsiao n, S. Khan n

Sources: ORCID, Web Of Science, NC State University Libraries
Added: February 1, 2024

2023 article

Compositional Design of Surface Oxides in Gallium-Indium Alloys

Farrell, Z. J., Jacob, A. R., Truong, V. K., Elbourne, A., Kong, W., Hsiao, L., … Tabor, C. (2023, January 11). CHEMISTRY OF MATERIALS, Vol. 1.

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: January 12, 2023

2023 journal article

Interacting collagen and tannic acid Particles: Uncovering pH-dependent rheological and thermodynamic behaviors

Journal of Colloid and Interface Science, 650, 541–552.

By: P. Sarker n, P. Jani n, L. Hsiao n, O. Rojas n & S. Khan n

author keywords: Particle-polyelectrolyte interactions; Collagen; Tannic Acid; Biomaterials; Rheology; Isothermal titration calorimetry; Quartz Crystal Microbalance
TL;DR: The effect of pH on the interactions between collagen and TA particles is explored by adding TA particles at physiological pH to collagen at both acidic and neutral pH, and results show significant increase in elastic modulus with an increase in collagen concentration. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Crossref, NC State University Libraries, Web Of Science, ORCID
Added: July 5, 2023

2023 journal article

Molecular structure effects on the mechanisms of corrosion protection of model epoxy coatings on metals

Materials Chemistry Frontiers, 7(2), 274–286.

By: Y. Kotb n, C. Serfass n, A. Cagnard*, K. Houston*, S. Khan n, L. Hsiao n, O. Velev n

Sources: Crossref, ORCID, Web Of Science, NC State University Libraries
Added: December 14, 2022

2023 journal article

Network physics of attractive colloidal gels: resilience, rigidity, and phase diagram

[ArXiv Preprint]. 1.

By: M. Nabizadeh, F. Nasirian, X. Li, Y. Saraswat, R. Waheibi, L. Hsiao*, D. Bi, B. Ravandi, S. Jamali

Sources: NC State University Libraries, NC State University Libraries
Added: August 1, 2023

2022 journal article

Hydrodynamic origin for the suspension viscoelasticity of rough colloids

JOURNAL OF RHEOLOGY, 66(5), 895–906.

By: S. Pradeep n, A. Wessel n & L. Hsiao n

author keywords: Linear viscoelasticity; Rough colloids; Dense suspensions; Hydrodynamics; Mode-coupling
Sources: Web Of Science, NC State University Libraries, ORCID
Added: September 6, 2022

2022 journal article

Microstructural Defects of Epoxy–Phenolic Polymers on Metal Substrates during Acidic Corrosion

ACS Applied Polymer Materials, 4(5), 3196–3204.

By: C. Serfass n, Y. Kotb n, K. Smith n, K. Houston*, S. Khan n, O. Velev n, L. Hsiao n

Sources: NC State University Libraries, NC State University Libraries, ORCID
Added: August 1, 2023

2022 journal article

What makes epoxy-phenolic coatings on metals ubiquitous: Surface energetics and molecular adhesion characteristics

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 608, 634–643.

By: Y. Kotb n, A. Cagnard*, K. Houston*, S. Khan n, L. Hsiao n & O. Velev n

author keywords: Adhesion; Polymer; metal interactions; Epoxy coatings; Contact angle; Surface energy; Pull-off test; XPS
MeSH headings : Epoxy Compounds; Epoxy Resins; Physical Phenomena; Steel; Wettability
TL;DR: Theoretical adhesion results reveal a superior adhesion of epoxy compared to phenolic resins, and epoxy resins having a higher content of epoxide-to-hydroxyl groups show improved theoretical and practical adhesion. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: November 15, 2021

2021 journal article

Bending of Soft Micropatterns in Elastohydrodynamic Lubrication Tribology

EXPERIMENTAL MECHANICS, 61(6), 969–979.

By: Y. Peng n, C. Serfass n, C. Hill n & L. Hsiao n

author keywords: Soft materials; Tribology; Textures
Sources: Web Of Science, NC State University Libraries, ORCID
Added: May 17, 2021

2021 article

Counterpropagating Gradients of Antibacterial and Antifouling Polymer Brushes

Ko, Y., Truong, V. K., Woo, S. Y., Dickey, M. D., Hsiao, L., & Genzer, J. (2021, December 14). BIOMACROMOLECULES, Vol. 12.

By: Y. Ko n, V. Truong n, S. Woo n, M. Dickey n, L. Hsiao n & J. Genzer n

MeSH headings : Anti-Bacterial Agents / pharmacology; Biofouling / prevention & control; Polymerization; Polymers
TL;DR: The formation of counterpropagating density gradients in poly([2-dimethylaminoethyl] methacrylate) (PDMAEMA) brushes featuring spatially varying quaternized and betainized units are reported on. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: ORCID, Web Of Science, NC State University Libraries
Added: December 15, 2021

2021 article

Elasticity of colloidal gels: structural heterogeneity, floppy modes, and rigidity

Rocklin, D. Z., Hsiao, L., Szakasits, M., Solomon, M. J., & Mao, X. (2021, June 15). SOFT MATTER, Vol. 6.

TL;DR: Structural heterogeneity of the gels, which leads to floppy modes and a nonaffine-affine crossover as frequency increases, evolves as a function of the volume fraction and is key to understanding the frequency-dependent elasticity. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: July 12, 2021

2021 journal article

Elastohydrodynamic friction of robotic and human fingers on soft micropatterned substrates

Nature Materials, 20(12), 1707–1711.

By: Y. Peng n, C. Serfass n, A. Kawazoe*, Y. Shao*, K. Gutierrez*, C. Hill n, V. Santos*, Y. Visell*, L. Hsiao n

MeSH headings : Elasticity; Friction; Humans; Lubrication; Robotics
TL;DR: A scaling law is reported that governs the peak friction values of elastohydrodynamic lubrication on patterned surfaces, which are absent in smooth tribopairs and arise due to a separation of length scales in the lubricant flow. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, Crossref, ORCID
Added: May 17, 2021

2021 journal article

Interfacial Contributions in Nanodiamond-Reinforced Polymeric Fibers

JOURNAL OF PHYSICAL CHEMISTRY B, 125(36), 10312–10323.

By: P. Adhikari n, P. Jani n, L. Hsiao n, O. Rojas n & S. Khan n

MeSH headings : Glass; Nanodiamonds; Polymers; Polyvinyl Alcohol; Tensile Strength
TL;DR: The interfacial energy parameters that explain the reinforcement of polymers with nanodiamond (ND) and the development of mechanical strength of electrospun ND-reinforced composites open the possibility for tailoring the interfacial interactions in polymer-ND fiber composites to achieve maximum mechanical reinforcement. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: September 7, 2021

2021 journal article

Jamming Distance Dictates Colloidal Shear Thickening

PHYSICAL REVIEW LETTERS, 127(15).

By: S. Pradeep n, M. Nabizadeh*, A. Jacob n, S. Jamali* & L. Hsiao n

TL;DR: The results suggest that the force per contact is different for particles with different morphologies, and the available free volume for colloids of different roughness is related to the deficiency from the maximum number of nearest neighbors at jamming under shear. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: October 26, 2021

2021 journal article

Local velocity of thermoresponsive colloidal gels in rate-driven flow

PHYSICS OF FLUIDS, 33(3).

By: K. Smith n, A. San-Miguel n & L. Hsiao n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: April 19, 2021

2021 journal article

Mechanical and Electrical Properties of DNA Hydrogel-Based Composites Containing Self-Assembled Three-Dimensional Nanocircuits

APPLIED SCIENCES-BASEL, 11(5).

By: M. Gao n, A. Krissanaprasit n, A. Miles*, L. Hsiao n & T. LaBean n

author keywords: DNA hydrogel; DNA hydrogel-based composites; self-assembly; biomaterials; DNA nanotechnology; carbon nanotubes; gold nanoparticles
Sources: Web Of Science, NC State University Libraries, ORCID
Added: March 22, 2021

2021 journal article

Migration and Morphology of Colloidal Gel Clusters in Cylindrical Channel Flow

LANGMUIR, 37(34), 10308–10318.

By: K. Smith n & L. Hsiao n

TL;DR: A compounding effect where larger gel clusters, formed under strong attractions and low shear stresses, are susceptible to shear-induced migration that intensifies r-dependent heterogeneity and deviations in the flow behavior from predictive models is found. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: September 20, 2021

2021 journal article

Printable homocomposite hydrogels with synergistically reinforced molecular-colloidal networks

Nature Communications, 12(1), 2834.

By: A. Williams n, S. Roh n, A. Jacob n, S. Stoyanov n, L. Hsiao n & O. Velev n

TL;DR: A class of self-reinforced homocomposite hydrogels (HHGs) comprised of interpenetrating networks of multiscale hierarchy with synergistically enforced colloidal-molecular HHGs open up numerous opportunities for formulation of biocompatible gels with robust structure-property relationships. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, Crossref, ORCID
Added: July 6, 2021

2020 journal article

Contact criterion for suspensions of smooth and rough colloids

SOFT MATTER, 16(21), 4980–4989.

By: S. Pradeep n & L. Hsiao n

TL;DR: Sensitivity analyses show that a deviation of the search distance by 1% of the particle diameter results in z changing by up to 10%, with the error in contact number distribution being magnified in dense suspensions (φ > 0.50) due to an increased number of nearest neighbors in the first coordination shell. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: June 22, 2020

2020 article

Printable homocomposite hydrogels with synergistically reinforced molecular-colloidal networks

Williams, A., Roh, S., Jacob, A., Stoyanov, S., Hsiao, L., & Velev, O. (2020, December 2).

Source: ORCID
Added: January 28, 2024

2020 journal article

Rheological and Tribological Behavior of Gels and Emulsions Containing Polymer and Phospholipid

ACS Applied Polymer Materials, 2(4), 1623–1633.

By: B. Farias n, L. Hsiao n & S. Khan n

UN Sustainable Development Goal Categories
Sources: Crossref, NC State University Libraries, ORCID
Added: March 12, 2020

2020 journal article

Shear-Induced Microstructural Variations in Nanoemulsion-Laden Organohydrogel Fibers

ACS Applied Polymer Materials, 2(2), 594–603.

By: E. Cardenas-Vasquez n, K. Smith n, T. Doolan n & L. Hsiao n

author keywords: composite hydrogel fibers; colloidal materials; fiber extrusion; microstructural variations; mass transport; drug delivery
Sources: Web Of Science, NC State University Libraries, Crossref, ORCID
Added: March 16, 2020

2020 journal article

The Formulator's Toolbox for Consumer Products

Chemical Engineering Progress, 2020(July), 26–31.

By: K. Smith & L. Hsiao

Source: NC State University Libraries
Added: August 1, 2023

2019 journal article

Colloidal gel elasticity arises from the packing of locally glassy clusters

NATURE COMMUNICATIONS, 10.

By: K. Whitaker*, Z. Varga*, L. Hsiao n, M. Solomon*, J. Swan* & E. Furst*

TL;DR: The quantitative agreement between integrated experimental, computational, and graph theoretic approaches are used to understand the arrested state and the origins of the gel elastic response. (via Semantic Scholar)
UN Sustainable Development Goal Categories
2. Zero Hunger (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: June 4, 2019

2019 journal article

Composite double network hydrogels with thermoresponsive colloidal nanoemulsions

AIChE Journal, 65(12), e16817.

By: L. Kass n, E. Cardenas‐Vasquez n & L. Hsiao n

author keywords: composite hydrogels; double network hydrogels; nanoemulsions; thermoresponsive
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, Crossref, ORCID
Added: December 16, 2019

2019 review

Experimental synthesis and characterization of rough particles for colloidal and granular rheology

[Review of ]. CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 43, 94–112.

By: L. Hsiao n & S. Pradeep n

author keywords: Rough particles; Colloidal suspensions; Granular suspensions; Hydrodynamics; Friction; Rheology
Sources: Web Of Science, NC State University Libraries
Added: December 16, 2019

2019 journal article

Interfacial Rheology of Gallium-Based Liquid Metals

Langmuir, 35(36), 11774–11783.

By: A. Jacob n, D. Parekh n, M. Dickey n & L. Hsiao n

TL;DR: A direct comparison of the viscoelastic properties for gallium-based liquid metals is provided and a microstructural evolution of the interface occurs when aluminum preferentially migrates from the bulk to the surface as well as simple methods to optimize their rheological behavior for future applications are provided. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Crossref, NC State University Libraries, ORCID
Added: August 28, 2019

2017 journal article

3D printing of self-assembling thermoresponsive nanoemulsions into hierarchical mesostructured hydrogels

SOFT MATTER, 13(5), 921–929.

By: L. Hsiao*, A. Badruddoza*, L. Cheng* & P. Doyle*

TL;DR: This work demonstrates that nanoemulsions, which belong to a class of solution-based materials with flexible functionalities, can be printed into prototypes with complex shapes using a commercially available 3D printer with a few modifications. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2017 journal article

Multiple particle tracking study of thermally-gelling nanoemulsions

SOFT MATTER, 13(37), 6606–6619.

By: L. Cheng*, L. Hsiao n & P. Doyle*

TL;DR: The approach demonstrates that probes with different surface chemistries are useful in probing the local regions of a colloidal gel and allows the measurement of local properties within structurally heterogeneous hydrogels. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2017 journal article

Rheological State Diagrams for Rough Colloids in Shear Flow

PHYSICAL REVIEW LETTERS, 119(15).

TL;DR: Model colloids with varying surface roughness length scales up to 10% of the particle radius are developed, demonstrating that a reduction in the onset stress of thickening and a sign change in the first normal stresses occur when friction competes with lubrication. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2017 journal article

Translational and rotational dynamics in dense suspensions of smooth and rough colloids

Soft Matter, 13(48), 9229–9236.

By: L. Hsiao n, I. Saha-Dalal*, R. Larson* & M. Solomon*

TL;DR: These experiments show that the meansquare displacement is unaffected by particle roughness, while the mean square angular displacement decreases for rough colloids at high volume fractions, which is evidently due to steric frustration caused by the surface topography of the particles. (via Semantic Scholar)
UN Sustainable Development Goal Categories
13. Climate Action (Web of Science)
Sources: Crossref, NC State University Libraries, ORCID
Added: July 27, 2019

2015 journal article

Celebrating Soft Matter's 10th Anniversary: Sequential phase transitions in thermoresponsive nanoemulsions

Soft Matter, 11(43), 8426–8431.

By: L. Hsiao* & P. Doyle*

TL;DR: The coexistence of stress-bearing percolation with arrested phase separation in a colloidal system of thermoresponsive nanoemulsions spanning a broad range of volume fractions and temperatures is reported and it is suggested that the formation of metastable gelled states not only depends on the attraction strength and volume fraction of the system, but is also sensitive to the rate at which the attractionstrength is increased. (via Semantic Scholar)
Sources: Crossref, NC State University Libraries
Added: July 27, 2019

2015 journal article

Metastable orientational order of colloidal discoids

Nature Communications, 6(1).

TL;DR: It is reported that colloidal oblate discoids initially self-assemble into short, metastable strands with orientational order—regardless of the final structure, which may guide self-assembly for anisotropic systems in which orientational Order is desired. (via Semantic Scholar)
Sources: Crossref, NC State University Libraries
Added: July 27, 2019

2014 journal article

A model colloidal gel for coordinated measurements of force, structure, and rheology

Journal of Rheology, 58(5), 1485–1504.

By: L. Hsiao*, M. Solomon*, K. Whitaker* & E. Furst*

Sources: Crossref, NC State University Libraries
Added: July 27, 2019

2014 journal article

Role of shear-induced dynamical heterogeneity in the nonlinear rheology of colloidal gels

Soft Matter, 10(46), 9254–9259.

By: L. Hsiao*, H. Kang*, K. Ahn* & M. Solomon*

TL;DR: The effect of flow-induced dynamical heterogeneity on the nonlinear elastic modulus of weakly aggregated colloidal gels that have undergone yielding by an imposed step strain deformation is reported. (via Semantic Scholar)
Sources: Crossref, NC State University Libraries
Added: July 27, 2019

2012 journal article

Role of isostaticity and load-bearing microstructure in the elasticity of yielded colloidal gels

Proceedings of the National Academy of Sciences, 109(40), 16029–16034.

By: L. Hsiao*, R. Newman, S. Glotzer* & M. Solomon

author keywords: colloids; confocal microscopy; suspensions; shear flow
MeSH headings : Elasticity; Gels / chemistry; Microscopy, Confocal; Molecular Dynamics Simulation; Polymethyl Methacrylate / chemistry; Rheology; Structure-Activity Relationship
TL;DR: These studies show that bond breakage occurs mainly due to the erosion of rigid clusters that persist far beyond the yield strain, and find a power-law scaling of the elastic modulus with the stress-bearing volume fraction that is valid over a range of volume fractions and gelation conditions. (via Semantic Scholar)
Sources: Crossref, NC State University Libraries
Added: July 27, 2019

2005 journal article

Evolution of periodicity in periodical cicadas.

Ecology, 86(12), 3200–3211.

By: N. Lehmann-Ziebarth*, P. Heideman*, R. Shapiro*, S. Stoddart*, C. Hsiao*, G. Stephenson*, P. Milewski*, A. Ives*

author keywords: Allee effects; evolution of periodicity; Magicicada; rock-paper-scissors competition; spatial dynamics
TL;DR: Although not enough information is known about periodical cicadas to draw firm conclusions, the theoretical arguments favor a combination of predator satiation and nymph competition as being key to the evolution of strictly fixed periods and occurrence of only one brood at most geographical locations. (via Semantic Scholar)
UN Sustainable Development Goal Categories
15. Life on Land (OpenAlex)
Sources: Crossref, NC State University Libraries
Added: December 16, 2019

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