Daniel Earl Stasiw

Works (5)

Updated: July 5th, 2023 15:43

2021 article

Chromophore-radical excited state antiferromagnetic exchange controls the sign of photoinduced ground state spin polarization

Kirk, M. L., Shultz, D. A., Hewitt, P., Stasiw, D. E., Chen, J., & Est, A. (2021, September 9). CHEMICAL SCIENCE, Vol. 9.

By: M. Kirk *, D. Shultz n , P. Hewitt n, D. Stasiw n, J. Chen * & A. Est *

TL;DR: It is proposed that the emissive polarization in 6-Me-mPh-Pt results from zero-field splitting induced transitions between the chromophoric 2T1 and 4T1 states, whereas predominant spin–orbit induced transitions around low-energy NN-based states give rise to the absorptive polarization observed for mPh- Pt. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (Web of Science; OpenAlex)
Sources: Web Of Science, ORCID
Added: October 18, 2021

2016 journal article

Toward Controlling the Solid State Valence Tautomeric Interconversion Character by Solvation

CRYSTAL GROWTH & DESIGN, 16(4), 2385–2393.

By: M. Ribeiro *, D. Stasiw n, P. Pattison, P. Raithby *, D. Shultz n  & C. Pinheiro *

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2015 journal article

Determining the Conformational Landscape of a and pi Coupling Using para-Phenylene and "Aviram-Ratner" Bridges

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(29), 9222–9225.

By: D. Stasiw n, J. Zhang n, G. Wang  n, R. Dangi*, B. Stein *, D. Shultz n , M. Kirk *, L. Wojtas*, R. Sommer n 

TL;DR: The torsional dependence of donor-bridge-acceptor (D-B-A) electronic coupling matrix elements and the pairwise exchange interactions are further illuminated in three-dimensional, "Ramachandran-type" plots that relate D-B and B-A torsions to both electronic and exchange couplings. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2013 journal article

Electronic and Exchange Coupling in a Cross-Conjugated D–B–A Biradical: Mechanistic Implications for Quantum Interference Effects

Journal of the American Chemical Society, 135(39), 14713–14725.

By: M. Kirk *, D. Shultz n , D. Stasiw n, D. Habel-Rodriguez*, B. Stein * & P. Boyle n

TL;DR: The results reveal important excited-state contributions to the ground-state singlet-triplet splitting in this cross-conjugated D-B-A biradical that contribute to the understanding of electronic coupling in cross- Conjugated molecules and specifically to quantum interference effects. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, Crossref, ORCID
Added: August 6, 2018

2013 journal article

Superexchange Contributions to Distance Dependence of Electron Transfer/Transport: Exchange and Electronic Coupling in Oligo(para-Phenylene)- and Oligo(2,5-Thiophene)-Bridged Donor–Bridge–Acceptor Biradical Complexes

Journal of the American Chemical Society, 135(45), 17144–17154.

By: M. Kirk *, D. Shultz n , D. Stasiw n, G. Lewis n, G. Wang  n, C. Brannen n, R. Sommer n , P. Boyle n

TL;DR: The work provides a direct measurement of superexchange contributions to β, with no contribution from incoherent hopping, and offers unique insight into the intrinsic molecular factors that govern H(DA) and β, which are important for understanding the electronic origin of electron transfer and electron transport mediated by molecular bridges. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, Crossref
Added: August 6, 2018

Citation Index includes data from a number of different sources. If you have questions about the sources of data in the Citation Index or need a set of data which is free to re-distribute, please contact us.

Certain data included herein are derived from the Web of Science© and InCites© (2024) of Clarivate Analytics. All rights reserved. You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.