@article{amunugama_asempa_jakubikova_verani_2023, title={Probing the effect of nitro-substituents in the modulation of LUMO energies for directional electron transport through 4d(6) ruthenium(ii)-based metallosurfactants}, volume={8}, ISSN={["1477-9234"]}, DOI={10.1039/d3dt01797d}, abstractNote={Nitro groups intended to modulate the energy of Frontier molecular orbitals were installed onto terpyridine- and phenanthroline-based RuIImetallosurfactants aiming to match the Fermi levels of electrodes for charge transport in Au|LB|Au junctions.}, journal={DALTON TRANSACTIONS}, author={Amunugama, Samudra and Asempa, Eyram and Jakubikova, Elena and Verani, Claudio N.}, year={2023}, month={Aug} } @article{amunugama_asempa_tripathi_wanniarachchi_baydoun_hoffmann_jakubikova_verani_2022, title={Electron transport through a (terpyridine) ruthenium metallo-surfactant containing a redox-active aminocatechol derivative}, volume={5}, ISSN={["1477-9234"]}, DOI={10.1039/d2dt00938b}, abstractNote={A ruthenium-containing metallosurfactant [Ru(terpy-X)(SQ)Cl]PF6 displays extensive orbital mixing, and allows a low-lying LUMO primarily associated with the SQ ligand to engage in directional electron transport in Au|LB 1|Au junctions.}, journal={DALTON TRANSACTIONS}, author={Amunugama, Samudra and Asempa, Eyram and Tripathi, Ramesh Chandra and Wanniarachchi, Dakshika and Baydoun, Habib and Hoffmann, Peter and Jakubikova, Elena and Verani, Claudio N.}, year={2022}, month={May} }