@article{na_ayres_chandra_gorman_parsons_2008, title={Nanoencapsulation and Stabilization of Single-Molecule/Particle Electronic Nanoassemblies Using Low-Temperature Atomic Layer Deposition}, volume={112}, ISSN={["1932-7447"]}, url={http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000261835000061&KeyUID=WOS:000261835000061}, DOI={10.1021/jp8066298}, abstractNote={This work addresses a significant challenge in engineered molecular systems regarding both understanding and controlling the stability of molecule/nanoparticle nanostructures under ambient exposure. Results deal specifically with molecular electronic junctions, where electronic contacts and transport are known to be sensitive to sample history and ambient exposure. We demonstrate that low-temperature atomic layer deposition can gently encapsulate and stabilize molecular electronic junctions, making it feasible to handle and transport junctions in air for many days with minimal change in electronic conduction. These findings indicate the potential for long-term stability of advanced synthetic nanoparticle/molecule nanoconstructs. For this study, conductivity through nanoparticle/molecule/nanoparticle junctions is analyzed and found to be consistent with nonresonant charge tunneling through a single or a small number of oligomeric phenylene ethynylene molecules in the electrical junction. The conductivity w...}, number={51}, journal={JOURNAL OF PHYSICAL CHEMISTRY C}, author={Na, Jeong-Seok and Ayres, Jennifer A. and Chandra, Kusum L. and Gorman, Christopher B. and Parsons, Gregory N.}, year={2008}, month={Dec}, pages={20510–20517} } @article{ayres_simendinger_balik_2007, title={Characterization of titanium alkoxide sol-gel systems designed for anti-icing coatings: I. Chemistry}, volume={4}, ISSN={["1935-3804"]}, DOI={10.1007/s11998-007-9054-8}, number={4}, journal={JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH}, author={Ayres, Jennifer and Simendinger, W. H. and Balik, C. M.}, year={2007}, month={Dec}, pages={463–471} } @article{ayres_simendinger_balik_2007, title={Characterization of titanium alkoxide sol-gel systems designed for anti-icing coatings: II. Mass loss kinetics}, volume={4}, ISSN={["1547-0091"]}, DOI={10.1007/s11998-007-9055-7}, number={4}, journal={JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH}, author={Ayres, Jennifer and Simendinger, W. H. and Balik, C. M.}, year={2007}, month={Dec}, pages={473–481} } @article{na_ayres_chandra_chu_gorman_parsons_2007, title={Conduction mechanisms and stability of single molecule nanoparticle/molecule/nanoparticle junctions}, volume={18}, number={3}, journal={Nanotechnology}, author={Na, J. S. and Ayres, J. and Chandra, K. L. and Chu, C. and Gorman, C. B. and Parsons, G. N.}, year={2007} } @article{chu_ayres_stefanescu_walker_gorman_parsons_2007, title={Enhanced conduction through isocyanide terminal groups in alkane and biphenylene molecules measured in molecule/nanoparticle/molecule junctions}, volume={111}, ISSN={["1932-7447"]}, url={http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000246842400037&KeyUID=WOS:000246842400037}, DOI={10.1021/jp065377r}, abstractNote={Electrical conductance through conjugated biphenyl and saturated alkane molecules on gold electrodes is characterized using a molecule/nanoparticle/molecule electrical test-bed assembly, and comparisons are made between molecules containing isocyanide (−NC) and thiol (−S) terminal groups bound to the gold. Current versus voltage analysis is consistent with charge tunneling through all systems studied. For molecules containing biphenyl, diphenyl acetylene, and alkane bridges, those containing an isocyanide terminal group show an order of magnitude increase in conductance as compared to those containing a thiol terminal group. Various theoretical predictions of the effect of isocyanide terminal groups on charge transfer through conjugated molecular systems are discussed and related to the results observed for charge transfer through conjugated and saturated molecules. The similar trends in charge transport observed for the different metal/linker interfaces suggest that the metal/linker contact plays an impo...}, number={22}, journal={JOURNAL OF PHYSICAL CHEMISTRY C}, author={Chu, Changwoong and Ayres, J. A. and Stefanescu, D. M. and Walker, B. R. and Gorman, Christopher B. and Parsons, Gregory N.}, year={2007}, month={Jun}, pages={8080–8085} } @article{na_ayres_chandra_gorman_parsons_2007, title={Real-time conductivity analysis through single-molecule electrical junctions}, volume={18}, number={42}, journal={Nanotechnology}, author={Na, J. S. and Ayres, J. and Chandra, K. L. and Gorman, C. B. and Parsons, G. N.}, year={2007} }