@article{barton_jamir_davis_peterson_parsons_2021, title={Doubly Protective MOF-Photo-Fabrics: Facile Template-Free Synthesis of PCN-222-Textiles Enables Rapid Hydrolysis, Photo-Hydrolysis and Selective Oxidation of Multiple Chemical Warfare Agents and Simulants}, volume={27}, ISSN={["1521-3765"]}, url={https://doi.org/10.1002/chem.202003716}, DOI={10.1002/chem.202003716}, abstractNote={Abstract}, number={4}, journal={CHEMISTRY-A EUROPEAN JOURNAL}, publisher={Wiley}, author={Barton, Heather F. and Jamir, Jovenal D. and Davis, Alexandra K. and Peterson, Gregory W. and Parsons, Gregory N.}, year={2021}, month={Jan}, pages={1465–1472} } @article{volk_kim_jamir_dickey_parsons_2021, title={Oxidative molecular layer deposition of PEDOT using volatile antimony(V) chloride oxidant}, volume={39}, ISSN={["1520-8559"]}, url={https://doi.org/10.1116/6.0000791}, DOI={10.1116/6.0000791}, abstractNote={Molecular layer deposition and chemical vapor deposition are emerging and promising techniques for the incorporation of high-performance conductive polymers into high surface area devices, such as sintered tantalum anodes for electrolytic capacitors. Until recently, vapor-phase synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) has relied on solid reactants which require relatively high temperatures and complex dosing schemes for sequential layer-by-layer processes. This work introduces a facile and high-performing layer-by-layer oxidative molecular layer deposition (oMLD) scheme using the volatile liquid oxidant antimony(V) chloride (SbCl5) to deposit PEDOT thin films. Effects of reactor parameters on PEDOT film characteristics are described, and the necessary foundation for future studies aiming to understand the nucleation and growth of layer-by-layer oMLD PEDOT is detailed.}, number={3}, journal={JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A}, publisher={American Vacuum Society}, author={Volk, Amanda A. and Kim, Jung-Sik and Jamir, Jovenal and Dickey, Elizabeth C. and Parsons, Gregory N.}, year={2021}, month={May} } @article{lee_jamir_peterson_parsons_2020, title={Protective Fabrics: Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification}, volume={2}, ISSN={["2590-2385"]}, DOI={10.1016/j.matt.2019.11.005}, abstractNote={Metal-organic frameworks (MOFs) can catalyze toxic chemical decontamination, but new MOF materials and synthesis strategies are needed to improve performance, particularly in field-usable MOF-textile formats. This article reports for the first time the exceptional photocatalytic reactivity of Al-PMOF (Al-porphyrin-based MOF), composed of an earth-abundant metal-containing Al(OH)O4 cluster bridged by H2TCPP (5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin) chromophores, against the toxic sulfur mustard simulant 2-chloroethyl ethyl sulfide (CEES) under visible-light irradiation. Furthermore, Al-PMOF is strongly immobilized into polymeric fibers via well-controlled Al2O3 solid film conversion using dimethylformamide/water cosolvent. The approach enables a secure integration of conformal Al-PMOF films onto polymer fibers at a relatively low synthesis temperature (120°C). In addition, on a per-unit mass of MOF basis, the surface-bound Al-PMOF films enable extremely rapid CEES detoxification turnover frequency, up to 170 molCEESmolchromophore−1min−1, more than 10-fold faster than the best MOF powders and 2-fold better than MOF films reported to date.}, number={2}, journal={MATTER}, author={Lee, Dennis T. and Jamir, Jovenal D. and Peterson, Gregory W. and Parsons, Gregory N.}, year={2020}, month={Feb}, pages={404–415} } @article{lee_jamir_peterson_parsons_2019, title={Water-Stable Chemical-Protective Textiles via Euhedral Surface-Oriented 2D Cu-TCPP Metal-Organic Frameworks}, volume={15}, ISSN={["1613-6829"]}, url={https://doi.org/10.1002/smll.201805133}, DOI={10.1002/smll.201805133}, abstractNote={Abstract}, number={10}, journal={SMALL}, publisher={Wiley}, author={Lee, Dennis T. and Jamir, Jovenal D. and Peterson, Gregory W. and Parsons, Gregory N.}, year={2019}, month={Mar} }