2014 journal article

Controlled Living Polymerization of Carbodiimides Using Versatile, Air-Stable Nickel(II) Initiators: Facile Incorporation of Helical, Rod-like Materials

MACROMOLECULES, 47(14), 4587–4595.

By: J. Reuther n, M. Bhatt*, G. Tian n, B. Batchelor*, R. Campos* & B. Novak*

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2014 journal article

Identification of the specific, shutter-like conformational reorientation in a chiroptical switching polycarbodiimide by VCD spectroscopy

Physical Chemistry Chemical Physics, 16(23), 11456–11460.

By: C. Merten, J. Reuther, J. DeSousa & B. Novak

Source: NC State University Libraries
Added: August 6, 2018

2013 journal article

Evidence of Entropy-Driven Bistability through N-15 NMR Analysis of a Temperature- and Solvent-Induced, Chiroptical Switching Polycarbodiimide

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135(51), 19292–19303.

By: J. Reuther n & B. Novak*

TL;DR: The thermo- and solvo-driven chiroptical switching process observed in specific polycarbodiimides occurs in a concerted fashion with large deviations in specific optical rotation and CD Cotton effect as a consequence of varying populations of two distinct polymer conformations, and it is proposed that the increased entropy in the system is a direct consequence of increased disorder in the solvent as the switching occurs. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2012 journal article

Determining the Regioregularity in Alkyne Polycarbodiimides and Their Orthogonal Modification of Side Chains To Yield Perfectly Alternating Functional Polymers

MACROMOLECULES, 45(20), 8155–8165.

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2012 journal article

Direct Probing of Regioregularity for Polycarbodiimide Systems via N-15 NMR Analysis

MACROMOLECULES, 45(19), 7719–7728.

By: J. Reuther n, J. DeSousa* & B. Novak*

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

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