Works (298)

Updated: April 3rd, 2024 21:56

2023 journal article

A scalable microstructure photonic coating fabricated by roll-to-roll “defects” for daytime sub-ambient passive radiative cooling

Nano Letters, 23(17), 7767–7774.

By: S. Liu n, C. Sui*, M. Harbinson n, M. Pudlo n, H. Perera n, Z. Zhang, R. Liu*, Z. Ku* ...

Contributors: J. Ryu n, J. Ryu, J. Ryu, J. Ryu, J. Ryu, S. Liu n, C. Sui*, M. Harbinson n ...

Ed(s): J. Ryu n

author keywords: nanocomposite; subambient daytime cooling; passive radiative cooling; scalable photonic structure
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries, NC State University Libraries, ORCID
Added: August 14, 2023

2023 article

Continuous Ligand-Free Catalysis Using a Hybrid Polymer Network Support

Davis, B. A., Genzer, J., Efimenko, K., & Abolhasani, M. (2023, July 14). JACS AU, Vol. 7.

By: B. Davis n, J. Genzer n, K. Efimenko n & M. Abolhasani n

author keywords: flow chemistry; continuous manufacturing; heterogeneouscatalysis; cross-coupling; hydrogenation
Sources: Web Of Science, NC State University Libraries, ORCID
Added: July 31, 2023

2023 article

Enhanced Triboelectric Charge Stability by Air-Stable Radicals

Im, S., Frey, E., Lacks, D. J., Genzer, J., & Dickey, M. D. (2023, September 7). ADVANCED SCIENCE, Vol. 9.

By: S. Im n, E. Frey n, D. Lacks*, J. Genzer n & M. Dickey n

author keywords: air-stable radicals; charge retention; kelvin probe force microscopy (KPFM); self-assembled monolayer (SAM); triboelectric charge
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: September 18, 2023

2023 article

Patterning of a High Surface Area Liquid Metal-Carbon Composite Film Using Laser Processing

Frey, E. J., Im, S., Bachmann, A. L., Genzer, J., & Dickey, M. D. (2023, September 22). ADVANCED FUNCTIONAL MATERIALS, Vol. 9.

By: E. Frey n, S. Im n, A. Bachmann n, J. Genzer n & M. Dickey n

author keywords: eutectic gallium-indium; high surface area electrodes; laser sintering; laser-induced carbonization; liquid metal particles; poly(amic acid); strain-invariant resistance
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: October 16, 2023

2023 article

Tuning Interfacial Adhesion in Polyester/Polyamide Systems

Machikiti, Z., Pourdeyhimi, B., Genzer, J., & Efimenko, K. (2023, July 31). INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, Vol. 7.

By: Z. Machikiti n, B. Pourdeyhimi n, J. Genzer n & K. Efimenko n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 14, 2023

2023 journal article

UV- and thermally-active small bi-functional gelator for creating gradient polymer network coatings

BIOINTERPHASES, 18(1).

By: P. Kannan n & J. Genzer n

MeSH headings : Azides / chemistry; Polymers / chemistry; Silicon / chemistry; Temperature; Ultraviolet Rays
TL;DR: This work presents a versatile one-pot synthesis method for creating surface-anchored orthogonal gradient networks using a small bi-functional gelator, 4-azidosulfonylphenethyltrimethoxysilane (4-ASPTMS), and demonstrates the generation of orthogona gradient network coatings exhibiting cross-link density (or stiffness) gradients in orthogonic directions. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: February 13, 2023

2022 journal article

Controlling PA6/PET adhesion to facilitate interfacial fracture

EUROPEAN POLYMER JOURNAL, 171.

By: Z. Machikiti n, B. Pourdeyhimi n, J. Genzer n & K. Efimenko n

author keywords: Interfacial adhesion; Modification; Fracture toughness; Annealing
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: June 6, 2022

2022 article

Degradable Anti-Biofouling Polyester Coatings with Controllable Lifetimes

Mu, G., Genzer, J., & Gorman, C. B. (2022, January 20). LANGMUIR, Vol. 1.

By: G. Mu n, J. Genzer n & C. Gorman n

MeSH headings : Biofouling / prevention & control; Methacrylates / chemistry; Polyesters; Polymerization; Polymers / chemistry
TL;DR: Degradable, anti-biofouling coatings with longer lifetimes and better mechanical properties are synthesized using a radical ring-opening polymerization and show good bovine serum albumin resistance capability. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: January 21, 2022

2022 journal article

Direct measurement of rate-dependent mode I and mode II traction-separation laws for cohesive zone modeling of laminated glass

COMPOSITE STRUCTURES, 279.

By: F. Poblete n, K. Mondal n, Y. Ma*, M. Dickey n, J. Genzer n & Y. Zhu n

author keywords: Glass; PVB; Interfacial mechanics; Cohesive zone modeling; Adhesion; Shear strength
Sources: Web Of Science, NC State University Libraries
Added: October 26, 2021

2022 article

Intensified Hydrogenation in Flow Using a Poly(beta-cyclodextrin) Network-Supported Catalyst

Davis, B. A., Bennett, J. A., Genzer, J., Efimenko, K., & Abolhasani, M. (2022, November 21). ACS SUSTAINABLE CHEMISTRY & ENGINEERING, Vol. 11.

By: B. Davis n, J. Bennett n, J. Genzer n, K. Efimenko n & M. Abolhasani n

author keywords: heterogeneous catalysis; flow chemistry; network-supported catalysis; transfer hydrogenation; process intensification
Sources: Web Of Science, NC State University Libraries, ORCID
Added: November 22, 2022

2022 article

Nonwoven Membranes with Infrared Light-Controlled Permeability

Ramesh, S., Davis, J., Roros, A., Zhou, C., He, N., Gao, W., … Genzer, J. (2022, September 9). ACS APPLIED MATERIALS & INTERFACES, Vol. 9.

By: S. Ramesh n, J. Davis n, A. Roros n, C. Zhou n, N. He n, W. Gao n, S. Menegatti n, S. Khan n, J. Genzer n

author keywords: smart-gated membranes; photothermal effect; stimuli-responsive hydrogels; nonwovens; graphene oxide
MeSH headings : Gels; Graphite; Microgels; Permeability; Polypropylenes; Temperature
TL;DR: This study presents the development of the first composite nonwoven fiber mats (NWFs) with infrared light-controlled permeability and shows potential toward processing temperature-sensitive bioactive ingredients or remote-controlled bioreactors. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: November 7, 2022

2022 article

PDMS networks meet barnacles: a complex and often toxic relationship

Rittschof, D., Orihuela, B., Genzer, J., & Efimenko, K. (2022, November 18). BIOFOULING, Vol. 11.

By: D. Rittschof*, B. Orihuela*, J. Genzer n & K. Efimenko n

author keywords: Barnacles; silicone formulation; trypsin; toxicity
MeSH headings : Animals; Thoracica; Trypsin; Biofilms; Biofouling / prevention & control; Silicones / chemistry
Sources: Web Of Science, NC State University Libraries, ORCID
Added: December 13, 2022

2022 article

Potent Antibacterial Composite Nonwovens Functionalized with Bioactive Peptides and Polymers

Barbieri, E., Cutright, C. C., Ramesh, S., Khan, S. A., Efimenko, K., Genzer, J., & Menegatti, S. (2022, August 23). ADVANCED MATERIALS INTERFACES, Vol. 8.

By: E. Barbieri n, C. Cutright n, S. Ramesh n, S. Khan n, K. Efimenko n, J. Genzer n, S. Menegatti n

author keywords: antimicrobial coating; bacitracin; controlled release; E; coli; polymyxin B; S; aureus; surface functionalization
TL;DR: The proposed antibacterial fabric outperforms its commercial counterparts in terms of biocompatibility, showing virtually no adverse effect on human epidermal keratinocytes and demonstrate affordable and scalable routes for developing antimicrobial NWFs that efficiently eliminate resilient pathogenic bacteria. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 24, 2022

2022 review

Self-healing and repair of fabrics: A comprehensive review of the application toolkit

[Review of ]. MATERIALS TODAY, 54, 90–109.

By: S. Ramesh n, S. Khan n, Y. Park*, E. Ford n, S. Menegatti n & J. Genzer n

author keywords: Self-repair; Self-healing; Fabrics; Nonwovens; Property recovery; Repair
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 15, 2022

2021 review

Antipathogenic properties and applications of low-dimensional materials

[Review of ]. NATURE COMMUNICATIONS, 12(1).

By: Z. Shaw*, S. Kuriakose*, S. Cheeseman*, M. Dickey n, J. Genzer n, A. Christofferson*, R. Crawford*, C. McConville* ...

MeSH headings : Anti-Infective Agents / chemistry; Anti-Infective Agents / pharmacology; Bacteria / drug effects; Bacteria / growth & development; Bacterial Infections / drug therapy; Bacterial Infections / microbiology; Biofilms / drug effects; Biofilms / growth & development; Candida / drug effects; Candida / physiology; Drug Resistance, Microbial / drug effects; Humans; Mycoses / drug therapy; Mycoses / microbiology; Nanostructures / administration & dosage; Nanostructures / chemistry; Particle Size
TL;DR: This review provides a critical assessment of current LDMs that have exhibited antimicrobial behaviour and their mechanism of action and will guide future design parameters for LDM-based antimicrobial applications. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: June 24, 2021

2021 journal article

Continuous Ligand-Free Suzuki-Miyaura Cross-Coupling Reactions in a Cartridge Flow Reactor Using a Gel-Supported Catalyst

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 60(26), 9418–9428.

By: J. Bennett n, B. Davis n, M. Ramezani n, J. Genzer n, K. Efimenko n & M. Abolhasani n

Sources: Web Of Science, NC State University Libraries, ORCID
Added: June 29, 2021

2021 article

Counterpropagating Gradients of Antibacterial and Antifouling Polymer Brushes

Ko, Y., Truong, V. K., Woo, S. Y., Dickey, M. D., Hsiao, L., & Genzer, J. (2021, December 14). BIOMACROMOLECULES, Vol. 12.

By: Y. Ko n, V. Truong n, S. Woo n, M. Dickey n, L. Hsiao n & J. Genzer n

MeSH headings : Anti-Bacterial Agents / pharmacology; Biofouling / prevention & control; Polymerization; Polymers
TL;DR: The formation of counterpropagating density gradients in poly([2-dimethylaminoethyl] methacrylate) (PDMAEMA) brushes featuring spatially varying quaternized and betainized units are reported on. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: December 15, 2021

2021 journal article

DFT Analysis of Organotin Catalytic Mechanisms in Dehydration Esterification Reactions for Terephthalic Acid and 2,2,4,4-Tetramethyl-1,3-cyclobutanediol

JOURNAL OF PHYSICAL CHEMISTRY A, 125(23), 4943–4956.

By: J. Clark n, P. Thacker n, C. McGill n, J. Miles n, P. Westmoreland n, K. Efimenko n, J. Genzer n, E. Santiso n

TL;DR: Calculations are used to show that esterification of TMCD and TPA will reduce and subsequently dehydrate a dimethyl tin oxide catalyst, becoming ligands on the now four-coordinate complex, a key first step in understanding polyester synthesis and avoiding undesirable side reactions during production. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: June 9, 2021

2021 article

Deposition of silicate coatings on poly(ethylene terephthalate) for improved scratch and solvent resistance

Castillo, G. A., Dickey, M. D., Gorman, C. B., Genzer, J., & Efimenko, K. (2021, October 21). JOURNAL OF APPLIED POLYMER SCIENCE, Vol. 10.

By: G. Castillo n, M. Dickey n, C. Gorman n, J. Genzer n & K. Efimenko n

author keywords: coatings; crystallization; packaging
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: October 22, 2021

2021 journal article

Dual-Responsive Microgels for Structural Repair and Recovery of Nonwoven Membranes for Liquid Filtration

ACS APPLIED POLYMER MATERIALS, 3(3), 1508–1517.

By: S. Ramesh n, J. Davis n, A. Roros n, J. Eiben n, T. Fabiani n, R. Smith n, L. Reynolds n, B. Pourdeyhimi n ...

author keywords: stimuli-responsive; microgels; nonwovens; permeability; healing; fabric repair
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: February 13, 2021

2021 journal article

Dynamic Surfaces-Degradable Polyester Networks that Resist Protein Adsorption

LANGMUIR, 37(30), 8978–8988.

By: G. Mu n, C. Pandiyarajan n, X. Lu n, M. Weaver n, J. Genzer n & C. Gorman n

MeSH headings : Adsorption; Hydrophobic and Hydrophilic Interactions; Kinetics; Polyesters; Serum Albumin, Bovine
TL;DR: A series of novel degradable alternating copolyesters composed of diglycolic anhydride and two epoxides and a photoactive crosslinking agent are synthesized, finding the lower gel fraction networks possess a higher swelling ratio and resist bovine serum albumin adsorption better by entropic shielding and faster degradation. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: July 24, 2021

2021 journal article

Functional Gels Containing Hydroxamic Acid Degrade Organophosphates in Aqueous Solutions

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 60(24), 8799–8811.

By: S. Zboray n, K. Efimenko n, J. Jones n & J. Genzer n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: July 19, 2021

2021 journal article

Novel computational design of high refractive index nanocomposites and effective refractive index tuning based on nanoparticle morphology effect

COMPOSITES PART B-ENGINEERING, 223.

By: S. Liu n, M. Islam n, Z. Ku*, D. Boyd*, Y. Zhong*, A. Urbas*, E. Smith*, J. Derov* ...

author keywords: Polymer-matrix composites (PMCs); Optical properties; Finite element analysis (FEA); Physical methods of analysis
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: July 9, 2021

2021 article

Surface-Bound Microgels for Separation, Sensing, and Biomedical Applications

Cutright, C. C., Harris, J. L., Ramesh, S., Khan, S. A., Genzer, J., & Menegatti, S. (2021, August 16). ADVANCED FUNCTIONAL MATERIALS, Vol. 8.

By: C. Cutright n, J. Harris n, S. Ramesh n, S. Khan n, J. Genzer n & S. Menegatti n

author keywords: deposition techniques; hydrogel microparticles; stimuli-responsive polymers; surface coating; surface morphology
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 17, 2021

2021 journal article

Tuning the Properties of Surface-Anchored Polymer Networks by Varying the Concentration of a Thermally Activated Cross-Linker, Annealing Time, and Temperature in a One-Pot Reaction

ACS APPLIED POLYMER MATERIALS, 3(11), 5568–5577.

By: S. Woo n, C. Pandiyarajan n & J. Genzer n

author keywords: hydrogel; substrate-anchored network; gel fraction; one-pot reaction; poly(vinylpyrrolidone); sulfonylazide; 6-ASHTES
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: December 6, 2021

2021 article

UV- and Thermally-Active Bifunctional Gelators Create Surface-Anchored Polymer Networks

Pandiyarajan, C. K., & Genzer, J. (2021, June 26). MACROMOLECULAR RAPID COMMUNICATIONS, Vol. 6.

By: C. Pandiyarajan n & J. Genzer*

author keywords: 4-azidosulfonylphenethyltrimethoxysilane (4-ASPTMS); 6-azidosulfonyltriethoxysilane(6-ASHTES); gel fraction; photo- or UV-crosslinking; poly(2-hydroxyethylmeth-acrylate) (PHEMA); poly(vinylpyrrolidone) (PVP); polymer coatings; surface-attached networks; thermal-crosslinking; thin films
MeSH headings : Gels; Polymers; Silicon; Spectroscopy, Fourier Transform Infrared; Ultraviolet Rays
TL;DR: A versatile one-step synthesis of surface-attached polymer networks using small bifunctional gelators (SBG) and 6-azidosulfonylhexyltriethoxysilane (6-ASHTES) is reported, which enables the covalent attachment of the crosslinked polymer chains. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: July 12, 2021

2020 journal article

Charge Density Gradients of Polymer Thin Film by Gaseous Phase Quaternization

ACS MACRO LETTERS, 9(2), 158–162.

By: Y. Ko n, S. Christau*, R. Klitzing* & J. Genzer n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: March 16, 2020

2020 journal article

Controlled heating and alignment platform enhances versatility in colloidal probe fabrication

REVIEW OF SCIENTIFIC INSTRUMENTS, 91(1).

By: R. Schmitz n, C. Wohl*, P. Tiemsin* & J. Genzer n

TL;DR: The Controlled Heating and Alignment Platform (CHAP) is presented for fabricating colloidal probes without altering the original characteristics of the attached particle, which minimizes particle heating and enables control over the viscosity of the thermoplastic adhesive to prevent it from contaminating the particle surface. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: March 23, 2020

2020 journal article

Dependence of deposition method on the molecular structure and stability of organosilanes revealed from degrafting by tetrabutylammonium fluoride

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 22(2), 658–666.

By: J. Miles n, Y. Ko n & J. Genzer n

TL;DR: Fast degrafting for organosilane SAMs deposited from the vapor phase is observed, indicating that SAMs prepared in this manner form more loosely packed arrays, with less in-plane connectivity, compared to their solution-deposited counterparts. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: February 3, 2020

2020 journal article

Design of High Efficient Mid‐Wavelength Infrared Polarizer on ORMOCHALC Polymer

Macromolecular Materials and Engineering, 305(5), 2000033.

By: M. Islam n, J. Kim*, Y. Ko n, Z. Ku*, D. Boyd*, E. Smith*, V. Nguyen*, J. Myers* ...

Contributors: M. Islam n, J. Kim*, Y. Ko n, Z. Ku*, D. Boyd*, E. Smith*, V. Nguyen*, J. Myers* ...

author keywords: Fabry-Perot cavity; linear polarizers; mid-wavelength infrared; organically modified chalcogenides; sulfur polymers
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID, Crossref
Added: April 6, 2020

2020 journal article

Effect of Poly(vinyl butyral) Comonomer Sequence on Adhesion to Amorphous Silica: A Coarse-Grained Molecular Dynamics Study

ACS APPLIED MATERIALS & INTERFACES, 12(42), 47879–47890.

By: C. Walker n, J. Genzer n & E. Santiso n

author keywords: polymer adsorption; silica; copolymer sequences; coarse-graining; molecular dynamics
TL;DR: An unexpectedly complex relationship between blockiness parameter and adhesion energy is discovered for intermediate vinyl alcohol (VA) content; adhesion strength to the silica slab was found to be maximal not for diblockCopolymers, but rather random-blocky copolymers with a moderately high degree of blockiness. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: December 21, 2020

2020 journal article

Enhanced mid-wavelength infrared refractive index of organically modified chalcogenide (ORMOCHALC) polymer nanocomposites with thermomechanical stability

OPTICAL MATERIALS, 108.

By: M. Islam*, S. Liu, D. Boyd, Y. Zhong, M. Nahid*, R. Henry*, L. Taussig, Y. Ko* ...

author keywords: Organically modified chalcogenide; Sulfur polymer; Refractive index tuning; Infrared optics; Nanocomposite reinforcing; Thermomechanical stability
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: November 24, 2020

2020 journal article

Extending the fused-sphere SAFT-gamma Mie force field parameterization approach to poly(vinyl butyral) copolymers

JOURNAL OF CHEMICAL PHYSICS, 152(4).

By: C. Walker n, J. Genzer n & E. Santiso n

TL;DR: This study explores the application of the fused-sphere SAFT-γ Mie approach to copolymers and demonstrates its capabilities at modeling poly(vinyl alcohol-co-vinyl butyral) (PVB), an important commercial copolymer widely used as an interlayer in laminated safety glass applications. (via Semantic Scholar)
UN Sustainable Development Goal Categories
13. Climate Action (Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: April 6, 2020

2020 journal article

Nonwoven fiber mats with thermo-responsive permeability to inorganic and organic electrolytes

JOURNAL OF MEMBRANE SCIENCE, 616.

By: C. Cutright n, R. Finkelstein n, E. Orlowski n, E. McIntosh n, Z. Brotherton n, T. Fabiani n, S. Khan n, J. Genzer n, S. Menegatti n

author keywords: Stimuli-responsive hydrogels; "Smart gating" membranes; Stimuli-controlled permeability; Fiber coating; Controlled transport
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: October 12, 2020

2020 journal article

Packing density, homogeneity, and regularity: Quantitative correlations between topology and thermoresponsive morphology of PNIPAM-co-PAA microgel coatings

APPLIED SURFACE SCIENCE, 508.

By: C. Cutright n, Z. Brotherton n, L. Alexander n, J. Harris n, K. Shi n, S. Khan n, J. Genzer n, S. Menegatti n

author keywords: Stimuli-responsive microgels; Self-assembled monolayers; Spin coating; Particle interactions; Particle packing
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: April 14, 2020

2020 journal article

The Next 100 Years of Polymer Science

MACROMOLECULAR CHEMISTRY AND PHYSICS, 221(16).

author keywords: Macromolecular Chemistry and Physics; polymer properties and applications; polymer synthesis; Staudinger; sustainability
Sources: Web Of Science, NC State University Libraries
Added: August 17, 2020

2019 journal article

Computer Simulation of Surface-Initiated Controlled Radical Polymerization: Effect of Free-Monomer Model on Brush Properties

MACROMOLECULAR THEORY AND SIMULATIONS, 28(5).

By: S. Turgman-Cohen* & J. Geezer

author keywords: controlled radical polymerization; Monte Carlo; polymer brushes; simulation; tethered polymers
Sources: Web Of Science, NC State University Libraries
Added: August 26, 2019

2019 journal article

Determining Water Sorption and Desorption in Thin Hydrophilic Polymer Films by Thermal Treatment

ACS APPLIED POLYMER MATERIALS, 1(9), 2495–2502.

By: Y. Ko n, J. Miles n & J. Genzer n

author keywords: polymer film; ellipsometry; dry thickness; moisture; charge density; CTE; TOC
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: October 7, 2019

2019 journal article

Development of a fused-sphere SAFT-gamma Mie force field for poly(vinyl alcohol) and poly(ethylene)

JOURNAL OF CHEMICAL PHYSICS, 150(3).

By: C. Walker n, J. Genzer n & E. Santiso n

TL;DR: This work addresses two key issues in extending the SAFT-γ Mie coarse-graining methodology to polymers, including the treatment of polymer chain rigidity and the disparity between the structure of linear chains of tangent spheres and the structures of the real polymers. (via Semantic Scholar)
UN Sustainable Development Goal Categories
13. Climate Action (Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: February 11, 2019

2019 journal article

Generating Surface-Anchored Zwitterionic Networks and Studying Their Resistance to Bovine Serum Albumin Adsorption

ACS APPLIED POLYMER MATERIALS, 1(12), 3323–3333.

By: E. Walker n, C. Pandiyarajan n, K. Efimenko n & J. Genzer n

author keywords: zwitterion; antifouling coatings; BSA adsorption; surface-attached networks; gel swelling
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: January 6, 2020

2019 journal article

Hydrogel/Elastomer Laminates Bonded via Fabric Interphases for Stimuli-Responsive Actuators

MATTER, 1(3), 674–689.

By: A. Hubbard n, W. Cui*, Y. Huang*, R. Takahashi*, M. Dickey n, J. Genzer n, D. King*, J. Gong*

Sources: Web Of Science, NC State University Libraries
Added: April 6, 2020

2019 journal article

Influence of surface topography attributes on settlement and adhesion of natural and synthetic species

SOFT MATTER, 15(20), 4045–4067.

By: S. Erramilli n & J. Genzer n

TL;DR: This review decomposes the attributes of surface topographies into their constituents, namely feature dimensions, geometry, and stiffness, and examines how they contribute (individually or collectively) to settlement and adhesion of natural organisms and synthetic particles on the surface. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 5, 2019

2019 journal article

Light-Induced Structuring of Photosensitive Polymer Brushes

ACS APPLIED POLYMER MATERIALS, 1(11), 301–3026.

By: A. Kopyshev*, K. Kanevche*, N. Lomadze*, E. Pfitzner*, S. Loebner*, R. Patil n, J. Genzer n, J. Heberle*, S. Santer*

author keywords: photosensitive polymer brushes; reversible and irreversible structuring of polymer brushes; photosensitive azobenzene containing surfactant; strong polyelectrolyte brush; SRG formation in polymer brushes
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: December 2, 2019

2019 journal article

Liquid Metal Nanoparticles as Initiators for Radical Polymerization of Vinyl Monomers

ACS MACRO LETTERS, 8(11), 1522–1527.

By: J. Ma n, Y. Lin n, Y. Kim*, Y. Ko n, J. Kim*, K. Oh*, J. Sun*, C. Gorman n ...

Contributors: J. Ma n, Y. Lin n, Y. Kim*, Y. Ko n, J. Kim*, K. Oh*, J. Sun*, C. Gorman n ...

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: December 9, 2019

2019 journal article

Mechanochemical Degrafting of a Surface-Tethered Poly(acrylic acid) Brush Promoted Etching of Its Underlying Silicon Substrate

LANGMUIR, 35(42), 13693–13699.

By: Y. Li*, Y. Lin n, Y. Dai*, Y. Ko n & J. Genzer n

TL;DR: The findings suggest that both polymer brushes (especially polyelectrolyte brushes) and SAMs anchored to silicon substrates may undergo erosion/etching on the substrates in basic environments, which compromises their stability and therefore jeopardizes their applications in coating, biosensing, etc. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: November 11, 2019

2019 journal article

Spontaneous Degrafting of Weak and Strong Polycationic Brushes in Aqueous Buffer Solutions

MACROMOLECULES, 52(16), 6192–6200.

By: Y. Ko n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: September 16, 2019

2019 journal article

Thermally Activated One-Pot, Simultaneous Radical and Condensation Reactions Generate Surface-Anchored Network Layers from Common Polymers

MACROMOLECULES, 52(2), 700–707.

By: C. Pandiyarajan n & J. Genzer n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: February 11, 2019

2019 journal article

Thermally driven directional free-radical polymerization in confined channels

POLYMER CHEMISTRY, 10(8), 920–925.

By: P. Datta n, K. Efimenko n & J. Genzer n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: March 11, 2019

2019 journal article

Thermo-mechanical transformation of shape memory polymers from initially flat discs to bowls and saddles

SMART MATERIALS AND STRUCTURES, 28(4).

By: R. Mailen*, C. Wagner n, R. Bang n, M. Zikry n, M. Dickey n & J. Genzer n

Contributors: R. Mailen*, C. Wagner n, R. Bang n, M. Zikry n, M. Dickey n & J. Genzer n

author keywords: shape-memory polymers; modeling; viscoelasticity; thermo-mechanical; axial symmetry
Sources: Web Of Science, NC State University Libraries, ORCID
Added: April 2, 2019

2019 journal article

Toughening stretchable fibers via serial fracturing of a metallic core

SCIENCE ADVANCES, 5(2).

By: C. Cooper n, I. Joshipura n, D. Parekh n, J. Norkett n, R. Mailen n, V. Miller n, J. Genzer n, M. Dickey n

TL;DR: Tough, metamaterial-like core-shell fibers that maintain stress at the fracture strength of a metal throughout the strain of an elastomer. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: February 23, 2019

2018 journal article

Adsorption of size-polydisperse particles on sinusoidally corrugated surfaces

MOLECULAR SIMULATION, 44(6), 494–506.

By: P. Schoch n & J. Genzer n

author keywords: Particle adsorption; corrugated surface; fouling
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2018 journal article

Fabrication of Flexible Hydrogel Sheets Featuring Periodically Spaced Circular Holes with Continuously Adjustable Size in Real Time

ACS APPLIED MATERIALS & INTERFACES, 10(36), 30844–30851.

author keywords: photosensitive polymers; PNIPAm; hydrogels; UV cross-linking; stimuli-responsive structured polymer films; azobenzene-containing molecules
TL;DR: The formation of stimuli-responsive structured hydrogel thin films whose pattern geometry can be adjusted on demand and tuned reversibly by varying solvent quality or by changing temperature is reported on. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: October 16, 2018

2018 journal article

Kinetic Study of Degrafting Poly(methyl methacrylate) Brushes from Flat Substrates by Tetrabutylammonium Fluoride

MACROMOLECULES, 51(24), 10237–10245.

By: R. Patil n, J. Miles n, Y. Ko n, P. Datta n, B. Rao n, D. Kiserow*, J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: January 14, 2019

2018 journal article

Microfluidic synthesis of elastomeric microparticles: A case study in catalysis of palladium-mediated cross-coupling

AIChE Journal, 64(8), 3188–3197.

By: J. Bennett n, A. Kristof n, V. Vasudevan n, J. Genzer n, J. Srogl n & M. Abolhasani n

author keywords: microfluidics; reactor analysis; cross-coupling; interfacial processes; multiphase flow; polymerization
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Crossref, NC State University Libraries, ORCID
Added: March 21, 2019

2018 journal article

Shape memory polymers for self-folding via compression of thermoplastic sheets

JOURNAL OF APPLIED POLYMER SCIENCE, 135(47).

By: A. Hubbard n, D. Davis n, M. Dickey n & J. Genzer n

author keywords: Mooney-Rivlin; self-folding; shape-memory polymers; thermoplastics
Sources: Web Of Science, NC State University Libraries, ORCID
Added: November 26, 2018

2018 journal article

Sonication-enabled rapid production of stable liquid metal nanoparticles grafted with poly(1-octadecene-alt-maleic anhydride) in aqueous solutions

NANOSCALE, 10(42), 19871–19878.

By: Y. Lin n, J. Genzer n, W. Li*, R. Qiao*, M. Dickey n & S. Tang*

TL;DR: A facile route to rapidly produce an aqueous suspension of stable LM NPs within five minutes is introduced and the stabilization mechanisms are elucidated, which possess the potential to advance the use of LM in biomedical applications. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: December 3, 2018

2018 journal article

Visualization of Mechanochemically-Assisted Degrafting of Surface-Tethered Poly(Acrylic Acid) Brushes

ACS MACRO LETTERS, 7(6), 609–613.

By: Y. Li n, Y. Lin n, Y. Ko n, D. Kiserow* & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: November 19, 2018

2017 journal article

A fully coupled thermo-viscoelastic finite element model for self-folding shape memory polymer sheets

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 55(16), 1207–1219.

By: R. Mailen n, M. Dickey n, J. Genzer n & M. Zikry n

Contributors: R. Mailen n, M. Dickey n, J. Genzer n & M. Zikry n

author keywords: modeling; viscoelastic properties; stimuli-sensitive polymers; viscous heating; shape memory
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2017 journal article

Controllable curvature from planar polymer sheets in response to light

Soft Matter, 13(12), 2299–2308.

By: A. Hubbard n, R. Mailen n, M. Zikry n, M. Dickey n & J. Genzer n

Contributors: A. Hubbard n, R. Mailen n, M. Zikry n, M. Dickey n & J. Genzer n

TL;DR: Results from this study show that curvature can be controlled by the distribution and darkness of the ink pattern on the polymer sheet, and utilize the direct and indirect curvature mechanisms to demonstrate the formation and actuation of gripper devices, which represent the potential utility of this approach. (via Semantic Scholar)
Sources: Crossref, NC State University Libraries, ORCID
Added: December 6, 2018

2017 journal article

Design and Fabrication of Wettability Gradients with Tunable Profiles through Degrafting Organosilane Layers from Silica Surfaces by Tetrabutylammonium Fluoride

LANGMUIR, 33(51), 14556–14564.

By: J. Miles n, S. Schlenker n, Y. Ko n, R. Patil n, B. Rao n & J. Genzer n

TL;DR: The fabrication of surface wettability gradients on flat surfaces is described by a simple, two-step procedure that permits precise tuning of the gradient profile and observes a relatively homogeneous coverage of silane throughout the degrafting process, providing a much more uniform surface when compared to additive approaches of gradient formation. (via Semantic Scholar)
UN Sustainable Development Goal Categories
14. Life Below Water (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2017 journal article

Effect of Network Density in Surface-Anchored Poly(N-isopropylacrylamide) Hydrogels on Adsorption of Fibrinogen

LANGMUIR, 33(8), 1974–1983.

By: C. Pandiyarajan n & J. Genzer n

MeSH headings : Acrylamides / chemistry; Acrylic Resins / chemistry; Adsorption; Benzophenones / chemistry; Fibrinogen / chemistry; Hydrogels / chemistry
TL;DR: A systematic investigation of the network properties such as gel fraction, cross-link density, and swelling ratio reveals that gels with higher MABP content produce densely cross-linked hydrophobic networks with low or no swelling in an aqueous medium. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2017 journal article

Effects of thermo-mechanical behavior and hinge geometry on folding response of shape memory polymer sheets

JOURNAL OF APPLIED PHYSICS, 122(19).

By: R. Mailen*, M. Dickey n, J. Genzer n & M. Zikry n

Contributors: R. Mailen*, M. Dickey n, J. Genzer n & M. Zikry n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2017 journal article

Enhanced Stability of Surface-Tethered Diblock Copolymer Brushes with a Neutral Polymer Block and a Weak Polyelectrolyte Block: Effects of Molecular Weight and Hydrophobicity of the Neutral Block

MACROMOLECULES, 50(21), 8580–8587.

By: Y. Li n, Y. Ko n, Y. Lin n, D. Kiserow n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2017 journal article

Further insight into the mechanism of poly(styrene-co-methyl methacrylate) microsphere formation

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 55(13), 2249–2259.

By: S. Applin*, R. Schmitz n, P. Tiemsin*, J. Genzer n, J. Connell* & C. Wohl*

author keywords: emulsion polymerization; copolymerization; methylmethacrylate; microspheres; particle nucleation; polystyrene; particle size distribution
TL;DR: A particle formation mechanism for poly(styrene-co-methyl methacrylate) microspheres was proposed based on characterization results and known reaction kinetics and it was proposed that particle size and size distributions were influenced by co-monomer composition and addition time. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2017 journal article

Phase Behavior and Self-Assembly of Perfectly Sequence-Defined and Monodisperse Multiblock Copolypeptides

BIOMACROMOLECULES, 18(2), 599–609.

MeSH headings : Elastin / chemistry; Hydrophobic and Hydrophilic Interactions; Micelles; Peptides / chemistry; Phase Transition; Polymers / chemistry; Transition Temperature
TL;DR: This paper investigates how the properties of multiblock copolypeptides can be tuned by their block architecture, defined by the size and distribution of blocks along the polymer chain, and demonstrates that when sequence can be precisely controlled, nanoscale self-assembly of polypeptide micelles can be modulated by block architecture. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2017 journal article

Salt-Induced Aggregation of Negatively Charged Gold Nanoparticles Confined in a Polymer Brush Matrix

MACROMOLECULES, 50(18), 7333–7343.

By: S. Christau n, T. Moeller*, J. Genzer n, R. Koehler* & R. Klitzing*

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2017 journal article

Sensors: Stretchable Capacitive Sensors of Torsion, Strain, and Touch Using Double Helix Liquid Metal Fibers (Adv. Funct. Mater. 20/2017)

Advanced Functional Materials, 27(20).

By: C. Cooper n, K. Arutselvan n, Y. Liu n, D. Armstrong n, Y. Lin n, M. Khan n, J. Genzer n, M. Dickey n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Crossref, NC State University Libraries
Added: January 25, 2020

2017 journal article

Sequential self-folding of polymer sheets

SCIENCE ADVANCES, 3(3).

By: Y. Liu n, B. Shaw n, M. Dickey n & J. Genzer n

TL;DR: A markedly simple strategy for programmed self-folding of two-dimensional polymer sheets into 3D objects in a sequential manner using external light, designed to absorb only specific wavelengths of light and to absorb differently at the same wavelength using color hues. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2017 journal article

Shape-transformable liquid metal nanoparticles in aqueous solution

CHEMICAL SCIENCE, 8(5), 3832–3837.

By: Y. Lin n, Y. Liu n, J. Genzer n & M. Dickey n

TL;DR: This paper reports the formation of shape-changing and phase-transforming liquid metal particles that have potential applications in drug delivery, catalysis, colloidal jamming, and optics. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2017 journal article

Stretchable Capacitive Sensors of Torsion, Strain, and Touch Using Double Helix Liquid Metal Fibers

ADVANCED FUNCTIONAL MATERIALS, 27(20).

By: C. Cooper n, K. Arutselvan n, Y. Liu n, D. Armstrong n, Y. Lin n, M. Khan n, J. Genzer n, M. Dickey n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2017 journal article

Vacuum filling of complex microchannels with liquid metal

LAB ON A CHIP, 17(18), 3043–3050.

By: Y. Lin n, O. Gordon n, M. Khan n, N. Vasquez n, J. Genzer n & M. Dickey n

TL;DR: The ability to fill dense and complex geometries with liquid metal in this manner may enable broader application of liquid metals in electronic and microfluidic applications. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2016 review

"2D or not 2D": Shape-programming polymer sheets

[Review of ]. PROGRESS IN POLYMER SCIENCE, 52, 79–106.

By: Y. Liu n, J. Genzer n & M. Dickey n

author keywords: Shape programming; Active materials; Folding; Polymer sheets
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2016 journal article

"Grafting Through" Polymerization Involving Surface-Bound Monomers

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 54(2), 263–274.

By: P. Datta n & J. Genzer n

author keywords: gradient; grafting through; polymer grafting; surface polymerization; template polymerization
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2016 journal article

Affinity interactions of human immunoglobulin G with short peptides: role of ligand spacer on binding, kinetics, and mass transfer

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 408(7), 1829–1841.

By: F. Shen n, O. Rojas n, J. Genzer n, P. Gurgel n & R. Carbonell n

author keywords: Peptide ligands; Immunoglobulin G; Peptide HWRGWV; Spacer arms; Quartz crystal microbalance
MeSH headings : Adsorption; Amino Acid Sequence; Humans; Immunoglobulin G / metabolism; Kinetics; Ligands; Peptides / chemistry; Peptides / metabolism; Polyethylene Glycols / chemistry; Protein Binding; Quartz Crystal Microbalance Techniques / methods; Silicon Dioxide / chemistry
TL;DR: Light was shed on interfacial effects important for detection and bioseparation by following the shifts in frequency and energy dissipation in a quartz crystal microbalance, as well as thermodynamic and kinetics parameters. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2016 journal article

Amidation of Polyesters Is Slow in Nonaqueous Solvents: Efficient Amidation of Poly(ethylene terephthalate) with 3-Aminopropyltriethoxysilane in Water for Generating Multifunctional Surfaces

ACS Applied Materials & Interfaces, 8(51), 35641–35649.

By: G. Castillo n, L. Wilson n, K. Efimenko n, M. Dickey n, C. Gorman n & J. Genzer n

author keywords: poly(ethylene terephthalate); PET; polyester; 3-aminopropyltriethoxysilane; APTES; amidation; aqueous; surface modification; surface activation
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID, Crossref
Added: August 6, 2018

2016 journal article

Drawing liquid metal wires at room temperature

Extreme Mechanics Letters, 7, 55–63.

By: Y. Lin n, C. Ladd n, S. Wang n, A. Martin n, J. Genzer n, S. Khan n, M. Dickey n

author keywords: Liquid metal; Room temperature fabrication; Metallic wires
Sources: Crossref, NC State University Libraries, ORCID
Added: December 6, 2018

2016 journal article

Effect of gold nanoparticle hydrophobicity on thermally induced color change of PNIPAM brush/gold nanoparticle hybrids

POLYMER, 98, 454–463.

By: S. Christau n, T. Moeller, F. Brose*, J. Genzer n, O. Soltwedel* & R. Klitzing*

author keywords: Polymer brushes; Gold nanoparticles; Nanomaterials; Hybrid materials; Colorimetric sensors; Neutron reflectivity; Thin films
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2016 journal article

Light-Induced Reversible Change of Roughness and Thickness of Photosensitive Polymer Brushes

ACS APPLIED MATERIALS & INTERFACES, 8(29), 19175–19184.

By: A. Kopyshev*, C. Galvin n, R. Patil n, J. Genzer n, N. Lomadze*, D. Feldmann*, J. Zakrevski*, S. Santer*

author keywords: photosensitive brushes; azobenzene containing surfactants; light driven reversible change of surface topography and thickness; domain memory in polymer brushes; orientation of azobenzenes in polymer brushes
TL;DR: The photomechanical function of the dry polymer brush was found to be reversible with repeated irradiation cycles and requires only a few seconds for switching, and the roughness of the brush also changes reversibly between a few Angstroms and several nanometers. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2016 journal article

Multipurpose Polymeric Coating for Functionalizing Inert Polymer Surfaces

ACS APPLIED MATERIALS & INTERFACES, 8(8), 5694–5705.

By: A. Oezcam, K. Efimenko*, R. Spontak*, D. Fischer* & J. Genzer*

author keywords: silicones; ultraviolet/ozone treatment; surface modification; trichlorosilane; PVMS; NEXAFS; semifluorinated; PET
TL;DR: PVMS-TCS is found to serve as a convenient precursor for the deposition of organosilanes and the subsequent growth of polymer brushes, even on hydrophobic surfaces, such as poly(ethylene terephthalate) and polypropylene. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2016 journal article

Polymer brushes modified by photosensitive azobenzene containing polyamines

POLYMER, 98, 421–428.

By: A. Kopyshev*, C. Galvin n, J. Genzer n, N. Lomadze* & S. Santer*

author keywords: Photosensitive brushes; Photosensitive azobenzene containing polyamines
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2016 journal article

Self-Folding of Thick Polymer Sheets Using Gradients of Heat

JOURNAL OF MECHANISMS AND ROBOTICS-TRANSACTIONS OF THE ASME, 8(3).

By: D. Davis n, B. Chen n, M. Dickey n & J. Genzer n

Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2016 journal article

Surface-Anchored Poly(N-isopropylacrylamide) Orthogonal Gradient Networks

MACROMOLECULES, 49(14), 5076–5083.

By: C. Pandiyarajan n, M. Rubinstein* & J. Genzer n

TL;DR: A versatile synthetic route leading toward generating surface-attached polyacrylamide gels is presented, in which the cross-link density varies continuously and gradually across the substrate in two orthogonal directions. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2016 journal article

Swelling of Hydrophilic Polymer Brushes by Water and Alcohol Vapors

MACROMOLECULES, 49(11), 4316–4329.

By: C. Galvin n & J. Genzer n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2016 journal article

Targeted Mutagenesis and Combinatorial Library Screening Enables Control of Protein Orientation on Surfaces and Increased Activity of Adsorbed Proteins

LANGMUIR, 32(34), 8660–8667.

By: C. Cruz-Teran n, K. Carlin n, K. Efimenko n, J. Genzer n & B. Rao n

TL;DR: Results strongly suggest that mutations introduced in Sso7d-2B5 alter its orientation relative to the parent protein, when adsorbed on silica surfaces, and has direct relevance to development of protein-based biosensors and biocatalysts. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Beyond Microstructures: Using the Kerr Effect to Characterize the Macrostructures of Synthetic Polymers

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 53(3), 155–166.

By: R. Gurarslan n, S. Hardrict n, D. Roy*, C. Galvin n, M. Hill*, H. Gracz n, B. Sumerlin*, J. Genzer n, A. Tonelli n

author keywords: Kerr Effect; microstructure; NMR; structural characterization; structure-property relations
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Creating surface patterns of polymer brushes by degrafting via tetrabutyl ammonium fluoride

RSC ADVANCES, 5(105), 86120–86125.

By: R. Patil n, D. Kiserow n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Direct Measurement of Molecular Weight and Grafting Density by Controlled and Quantitative Degrafting of Surface-Anchored Poly(methyl methacrylate)

ACS MACRO LETTERS, 4(2), 251–254.

By: R. Patil n, S. Turgman-Cohen*, J. Srogl n, D. Kiserow n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Expanding the Polymer Mechanochemistry Toolbox through Surface-Initiated Polymerization

ACS MACRO LETTERS, 4(6), 636–639.

By: H. Klok* & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Film-Stabilizing Attributes of Polymeric Core-Shell Nanoparticles

ACS NANO, 9(8), 7940–7949.

By: X. Cai n, H. Yuan n, A. Blencowe*, G. Qiao*, J. Genzer n & R. Spontak n

author keywords: microgel particles; polymer thin film; nanolaminate; film stabilization; polymer coating; dewetting
TL;DR: Observations indicate that the present CSMG NP films are stabilized primarily by multidirectional penetration of relatively short, unentangled NP arms caused by NP layering, rather than by chain entanglement as in linear homopolymer thin films. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Handwritten, Soft Circuit Boards and Antennas Using Liquid Metal Nanoparticles

SMALL, 11(48), 6397–6403.

By: Y. Lin n, C. Cooper n, M. Wang n, J. Adams n, J. Genzer n & M. Dickey n

TL;DR: Soft circuit boards can be handwritten by a stylus, which sinters the particles into conductive traces by applying localized mechanical pressure to the elastomeric sheets. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2015 journal article

Instability of Surface-Grafted Weak Polyacid Brushes on Flat Substrates

Macromolecules, 48(16), 5677–5687.

By: C. Galvin n, E. Bain n, A. Henke* & J. Genzer n

Sources: Crossref, NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2015 journal article

Making polymer brush photosensitive with azobenzene containing surfactants

POLYMER, 79, 65–72.

By: A. Kopyshev*, N. Lomadze*, D. Feldmann*, J. Genzer n & S. Santer*

author keywords: Azobenzene containing cationic surfactants; Photosensitive polymer brushes; Opto-mechanically induced scission of; polymer chains
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Modelling of shape memory polymer sheets that self-fold in response to localized heating

SOFT MATTER, 11(39), 7827–7834.

By: R. Mailen n, Y. Liu n, M. Dickey n, M. Zikry n & J. Genzer n

Contributors: R. Mailen n, Y. Liu n, M. Dickey n, M. Zikry n & J. Genzer n

TL;DR: A nonlinear finite element analysis (FEA) of the thermo-mechanical shrinking and self-folding behavior of pre-strained polystyrene polymer sheets provides a fundamental understanding of shrinking, self- folding dynamics, and bending angles, and provides design guidelines for origami shapes and structures. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2015 journal article

Modification of Silicone Elastomer Surfaces with Zwitterionic Polymers: Short-Term Fouling Resistance and Triggered Biofouling Release

ACS APPLIED MATERIALS & INTERFACES, 7(46), 25586–25591.

By: P. Shivapooja, Q. Yu*, B. Orihuela*, R. Mays n, D. Rittschof*, J. Genzer n, G. Lopez

author keywords: silicones; elastomers; zwitterionic polymers; fouling-resistance; biofouling
MeSH headings : Bacteria / drug effects; Bacterial Adhesion; Biofilms / drug effects; Biofouling; Ions; Photoelectron Spectroscopy; Polymerization; Polymers / chemistry; Polyvinyls / pharmacology; Silicone Elastomers / chemistry; Siloxanes / pharmacology; Spectroscopy, Fourier Transform Infrared; Surface Properties
TL;DR: This work presents a method for dual-mode-management of biofouling by modifying surface of silicone elastomers with zwitterionic polymeric grafts, which exhibited both fouling resistance and triggered fouling-release functionality. (via Semantic Scholar)
UN Sustainable Development Goal Categories
14. Life Below Water (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

On-Demand Degrafting and the Study of Molecular Weight and Grafting Density of Poly(methyl methacrylate) Brushes on Flat Silica Substrates

LANGMUIR, 31(8), 2372–2381.

By: R. Patil n, S. Turgman-Cohen*, J. Srogl n, D. Kiserow n & J. Genzer n

TL;DR: The dry PMMA brush thickness and the number-average molecular weight suggest that the grafting density of the PMMA grafts is independent of polymerization time, indicating well-controlled/living growth of MMA and small but noticeable dependence of the polymer brush graftingdensity on the inhibitor/catalyst ratio. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Polymer Brush/Metal Nanoparticle Hybrids for Optical Sensor Applications: from Self-Assembly to Tailored Functions and Nanoengineering

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 229(7-8), 1089–1117.

By: S. Christau*, J. Genzer n & R. Klitzing*

author keywords: Polymer Brushes; Metallic Nanoparticles; Gold Nanoparticles; Hybrid; Nanocomposite; Sensing; Sensoring; Surface Plasmon Resonance
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Proteinlike Copolymers as Encapsulating Agents for Small-Molecule Solutes

LANGMUIR, 31(11), 3518–3526.

By: R. Malik n, J. Genzer n & C. Hall n

MeSH headings : Hydrophobic and Hydrophilic Interactions; Molecular Dynamics Simulation; Polymers / chemistry; Solutions / chemistry; Solvents / chemistry
TL;DR: The utilization of proteinlike copolymers (PLCs) as encapsulating agents for small-molecule solutes is described and a single-chain PLC encapsulates solute successfully by collapsing the macromolecule to a well-defined globular conformation. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2015 journal article

Self-folding of polymer sheets using microwaves and graphene ink

RSC Advances, 5(108), 89254–89261.

By: D. Davis n, R. Mailen n, J. Genzer n & M. Dickey n

Sources: Crossref, NC State University Libraries, ORCID
Added: December 6, 2018

2015 journal article

Thermoresponsive PDMAEMA Brushes: Effect of Gold Nanoparticle Deposition

JOURNAL OF PHYSICAL CHEMISTRY B, 119(32), 10348–10358.

By: Z. Yenice, S. Schoen, H. Bildirir, J. Genzer n & R. Klitzing

MeSH headings : Gold / chemistry; Metal Nanoparticles / chemistry; Methacrylates / chemistry; Microscopy, Atomic Force; Microscopy, Electron, Scanning; Nylons / chemistry; Phase Transition; Surface Properties; Temperature; Water / chemistry
TL;DR: The paper addresses the effect of gold nanoparticle (Au-NP) deposition on the thermoresponsive volume phase transition of the weak polyelectrolyte poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) brushes and shows that the AFM full-indentation method can be successfully applied to determine the polymer brush thicknesses. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2014 journal article

Adsorption of "soft" spherical particles onto sinusoidally-corrugated substrates

Soft Matter, 10(38), 7452–7458.

By: P. Schoch n & J. Genzer n

TL;DR: A Monte Carlo simulation scheme based on the bond fluctuation model is utilized to simulate settlement of "soft" adhesive particles onto sinusoidally-corrugated substrates and shows that the wavelength of substrate features plays a significant role in the settlement of single particle systems. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2014 journal article

Adsorption of Multiple Spherical Particles onto Sinusoidally Corrugated Substrates

LANGMUIR, 30(31), 9407–9417.

By: P. Schoch n & J. Genzer n

MeSH headings : Adsorption; Hair / chemistry; Monte Carlo Method; Particle Size; Surface Properties
TL;DR: The adhesion of particles with an effective interaction shell to the substrates is reduced dramatically when the particle size is smaller than the feature width of the periodic substrate. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2014 journal article

Brush/Gold Nanoparticle Hybrids: Effect of Grafting Density on the Particle Uptake and Distribution within Weak Polyelectrolyte Brushes

LANGMUIR, 30(43), 13033–13041.

By: S. Christau*, T. Moeller, Z. Yenice*, J. Genzer n & R. Klitzing*

TL;DR: X-ray reflectivity is a suitable tool for investigating the spatial structure of the hybrid, and it is combined with scanning electron microscopy and UV/vis spectroscopy to study the particle loading and interpenetration of the particles within the polymer brush matrix. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2014 journal article

Effect of ultraviolet/ozone treatment on the surface and bulk properties of poly(dimethyl siloxane) and poly(vinylmethyl siloxane) networks

Polymer, 55(14), 3107–3119.

By: A. Özçam n, K. Efimenko n & J. Genzer n

author keywords: Silicone elastomers; Surface modification; PDMS
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Crossref, NC State University Libraries
Added: February 21, 2020

2014 journal article

Evolution of Homopolymer Thin-Film Instability on Surface-Anchored Diblock Copolymers Varying in Composition

LANGMUIR, 30(39), 11689–11695.

By: X. Cai n, J. Genzer n & R. Spontak n

TL;DR: This study investigates the destabilization rate and mechanism of homopolystyrene films differing in thickness on top of poly(styrene-b-methyl methacrylate) diblock copolymer monolayers varying in chemical composition anchored to flat silica-like substrates to examine the effect of surface constitution on PS stability. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2014 journal article

In-plane deformation of shape memory polymer sheets programmed using only scissors

POLYMER, 55(23), 5948–5952.

By: J. Allensworth, Y. Liu*, H. Braun, J. Genzer* & M. Dickey*

author keywords: Shape morphing; Shape programming; Shape memory polymers
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2014 journal article

Self-Folding Origami Microstrip Antennas

IEEE TRANSACTIONS ON ANTENNAS AND PROPAGATION, 62(10), 5416–5419.

By: G. Hayes n, Y. Liu n, J. Genzer n, G. Lazzi* & M. Dickey n

author keywords: Light-activated; light-sensitive; microstrip antennas; origami; pre-stressed polymers; reconfigurable; self-folding; shape memory polymers
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2014 journal article

Simple geometric model to describe self-folding of polymer sheets

PHYSICAL REVIEW E, 89(4).

By: Y. Liu n, R. Mailen n, Y. Zhu n, M. Dickey n & J. Genzer n

TL;DR: Measurements of the macroscopic, thermally driven shrinkage behavior of the sheets help predict the kinetics of folding by determining how fast the top of the hinge shrinks as a function of temperature and time. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2014 journal article

Swelling of Polyelectrolyte and Polyzwitterion Brushes by Humid Vapors

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 136(36), 12737–12745.

By: C. Galvin n, M. Dimitriou*, S. Satija* & J. Genzer n

TL;DR: Evidence is provided that swelling behavior of polyelectrolyte and polyzwitterion brushes derived from poly(dimethylamino)ethyl methacrylate in water vapor stems from the formation of inter- and intramolecular zwitterionic complexes. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2014 journal article

Three-dimensional folding of pre-strained polymer sheets via absorption of laser light

Journal of Applied Physics, 115(20), 204911.

By: Y. Liu n, M. Miskiewicz n, M. Escuti n, J. Genzer n & M. Dickey n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID, Crossref
Added: August 6, 2018

2014 journal article

Toward the Development of a Versatile Functionalized Silicone Coating

ACS APPLIED MATERIALS & INTERFACES, 6(24), 22544–22552.

By: A. Oezcam, R. Spontak n & J. Genzer n

author keywords: silicone elastomer; trichlorosilane; poly(vinylmethylsiloxane); poly(dimethylsiloxane); thiol-ene; functional silicone
TL;DR: umerous experimental probes, including optical microscopy, Fourier-transform infrared spectroscopy, surface contact angle, ellipsometry, and nanoindentation are utilized to interrogate the physical and chemical characteristics of these PVMS-TCS coatings. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

Characterizing polymer macrostructures by identifying and locating microstructures along their chains with the kerr effect

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 51(9), 735–741.

By: S. Hardrict n, R. Gurarslan n, C. Galvin n, H. Gracz n, D. Roy*, B. Sumerlin*, J. Genzer n, A. Tonelli n

author keywords: microstructure; solution properties; structure-property relations; thin films
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

Computer Simulation of Template Polymerization Using a Controlled Reaction Scheme

MACROMOLECULES, 46(6), 2474–2484.

By: P. Datta n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

Effect of Protein-like Copolymers Composition on the Phase Separation Dynamics of a Polymer Blend: A Monte Carlo Simulation

MACROMOLECULES, 46(10), 4207–4214.

By: R. Malik n, C. Hall n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

Generation and Properties of Antibacterial Coatings Based on Electrostatic Attachment of Silver Nanoparticles to Protein-Coated Polypropylene Fibers

ACS APPLIED MATERIALS & INTERFACES, 5(11), 5298–5306.

By: K. Goli n, N. Gera n, X. Liu n, B. Rao n, O. Rojas n & J. Genzer n

author keywords: antibacterial; polypropylene; protein adsorption; nanoparticle; functional coating
MeSH headings : Anti-Bacterial Agents / chemistry; Coated Materials, Biocompatible / chemistry; Escherichia coli / drug effects; Escherichia coli Infections / prevention & control; Hydrophobic and Hydrophilic Interactions; Light; Metal Nanoparticles / chemistry; Microscopy, Electron, Scanning; Microscopy, Electron, Transmission; Polypropylenes / chemistry; Proteins / chemistry; Silver / chemistry; Static Electricity; Ultraviolet Rays
TL;DR: The results show that PP surfaces coated with AgNPs exhibit excellent antibacterial activity with 100% removal efficiency and are tested against gram negative bacteria Escherichia coli. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

Macromol. Theory Simul. 1/2013

Macromolecular Theory and Simulations, 22(1), 1–1.

By: E. Bain n, S. Turgman-Cohen n & J. Genzer n

Sources: Crossref, NC State University Libraries
Added: September 6, 2020

2013 journal article

Microfluidic channels fabricated from poly(vinylmethylsiloxane) networks that resist swelling by organic solvents

LAB ON A CHIP, 13(22), 4317–4320.

By: R. Mays n, M. Dickey n & J. Genzer n

TL;DR: In contrast to PDMS microchannels, the UV-treated PVMS structures exhibit high resistance to swelling by toluene, thus providing a versatile alternative to poly(dimethylsiloxane) (PDMS). (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2013 journal article

On the Surface Interactions of Proteins with Lignin

ACS Applied Materials & Interfaces, 5(1), 199–206.

By: C. Salas*, O. Rojas*, L. Lucia*, M. Hubbe* & J. Genzer*

author keywords: adsorption; lignin; proteins; soy glycinin; beta-conglycinin; quartz crystal microbalance
MeSH headings : Adsorption; Antigens, Plant / chemistry; Antigens, Plant / metabolism; Diffusion; Globulins / chemistry; Globulins / metabolism; Hydrophobic and Hydrophilic Interactions; Lignin / chemistry; Lignin / metabolism; Mercaptoethanol / chemistry; Protein Denaturation; Seed Storage Proteins / chemistry; Seed Storage Proteins / metabolism; Soybean Proteins / chemistry; Soybean Proteins / metabolism; Surface Plasmon Resonance; Urea / chemistry; Water / chemistry
TL;DR: This work investigates the interactions at the solid-liquid interface of lignin with the two main proteins in soy, glycinin and β-conglycinin, and quantifies the extent of adsorption and the degree of hydration of the interfacial layers. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Crossref, NC State University Libraries, Web Of Science
Added: August 6, 2018

2013 journal article

Opto-Mechanical Scission of Polymer Chains in Photosensitive Diblock-Copolymer Brushes

LANGMUIR, 29(45), 13967–13974.

By: A. Kopyshev*, C. Galvin n, J. Genzer n, N. Lomadze* & S. Santer*

TL;DR: The results indicate that this process may be explained by employing classical continuum fracture mechanics, which might be important for tailoring the phenomenon for applying it to poststructuring of polymer brushes. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 review

Progress in Computer Simulation of Bulk, Confined, and Surface-initiated Polymerizations

[Review of ]. MACROMOLECULAR THEORY AND SIMULATIONS, 22(1), 8–30.

By: E. Bain n, S. Turgman-Cohen n & J. Genzer n

author keywords: computer simulation; Gillespie; grafting from; polymerization; stochastic
TL;DR: An outlook of these two classes of computer simulation approaches as they are applied to ‘‘grafting from’’ polymerizations is concluded. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

Self-assembly fronts in collision: impinging ordering organosilane layers

SOFT MATTER, 9(8), 2493–2505.

By: K. Efimenko n, A. Oezcam, J. Genzer n, D. Fischer*, F. Phelan* & J. Douglas*

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

Surface wrinkling by chemical modification of poly(dimethylsiloxane)-based networks during sputtering

Soft Matter, 9(32), 7797.

By: M. Casper n, A. Gözen n, M. Dickey n, J. Genzer n & J. Maria n

UN Sustainable Development Goal Categories
Sources: Crossref, NC State University Libraries, Web Of Science, ORCID
Added: August 6, 2018

2013 journal article

Thiol-containing polymeric embedding materials for nanoskiving

JOURNAL OF MATERIALS CHEMISTRY C, 1(1), 121–130.

By: R. Mays n, P. Pourhossein*, D. Savithri n, J. Genzer n, R. Chiechi* & M. Dickey n

Contributors: R. Mays n, P. Pourhossein*, D. Savithri n, J. Genzer n, R. Chiechi* & M. Dickey n

Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2013 journal article

Water-Wettable Polypropylene Fibers by Facile Surface Treatment Based on Soy Proteins

ACS APPLIED MATERIALS & INTERFACES, 5(14), 6541–6548.

By: C. Salas*, J. Genzer*, L. Lucia*, M. Hubbe* & O. Rojas*

author keywords: soy proteins; surface modification; polypropylene nonwovens; protein adsorption; wettability; wicking
MeSH headings : Adsorption; Antigens, Plant / chemistry; Antigens, Plant / metabolism; Fluorescein-5-isothiocyanate / chemistry; Globulins / chemistry; Globulins / metabolism; Polypropylenes / chemistry; Quartz Crystal Microbalance Techniques; Quaternary Ammonium Compounds / chemistry; Seed Storage Proteins / chemistry; Seed Storage Proteins / metabolism; Soybean Proteins / chemistry; Soybean Proteins / metabolism; Spectrometry, Fluorescence; Surface Plasmon Resonance; Surface Properties; Water / chemistry; Wettability
TL;DR: The results from wicking tests indicate that hydrophobic PP nonwovens absorb a significant amount of water after protein treatment, i.e., the PP-modified surfaces become completely hydrophilic. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Adsorption of Glycinin and beta-Conglycinin on Silica and Cellulose: Surface Interactions as a Function of Denaturation, pH, and Electrolytes

BIOMACROMOLECULES, 13(2), 387–396.

By: C. Salas n, O. Rojas n, L. Lucia n, M. Hubbe n & J. Genzer n

MeSH headings : Adsorption; Antigens, Plant / chemistry; Cellulose / chemistry; Circular Dichroism; Electrolytes / chemistry; Globulins / chemistry; Hydrogen-Ion Concentration; Hydrophobic and Hydrophilic Interactions; Kinetics; Mercaptoethanol / chemistry; Osmolar Concentration; Protein Denaturation; Quartz Crystal Microbalance Techniques; Seed Storage Proteins / chemistry; Silicon Dioxide / chemistry; Solutions; Soybean Proteins / chemistry; Static Electricity; Surface Properties; Thermodynamics
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 review

Applications of surface-grafted macromolecules derived from post-polymerization modification reactions

[Review of ]. PROGRESS IN POLYMER SCIENCE, 37(7), 871–906.

By: C. Galvin n & J. Genzer n

author keywords: Surface-anchored polymers; Post-polymerization modification; Polymer analogous reactions; Functional polymer layer; Polymer nanocomposites; Biomaterials
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Computer Simulation of Concurrent Bulk- and Surface-Initiated Living Polymerization

MACROMOLECULES, 45(4), 2128–2137.

By: S. Turgman-Cohen n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Determining the Polydispersity in Chemical Composition and Monomer Sequence Distribution in Random Copolymers Prepared by Postpolymerization Modification of Homopolymers

ACS MACRO LETTERS, 1(9), 1128–1133.

By: W. Powers*, C. Ryu*, Y. Jhon n, L. Strickland n, C. Hall n & J. Genzer n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Experimental and Computational Study of the Effect of Alcohols on the Solution and Adsorption Properties of a Nonionic Symmetric Triblock Copolymer

The Journal of Physical Chemistry B, 116(4), 1289–1298.

By: X. Liu n, F. He n, C. Salas n, M. Pasquinelli n, J. Genzer n & O. Rojas n

Contributors: X. Liu n, F. He n, C. Salas n, M. Pasquinelli n, J. Genzer n & O. Rojas n

MeSH headings : Adsorption; Alcohols / chemistry; Cellulose / chemistry; Computer Simulation; Hydrophobic and Hydrophilic Interactions; Micelles; Models, Molecular; Molecular Conformation; Polyethylene Glycols / chemistry; Propylene Glycols / chemistry; Rotation; Solutions; Static Electricity; Surface Tension
TL;DR: Overall, the solution and adsorption properties of nonionic symmetric triblock copolymers in the presence of alcohols are rationalized by changes in solvency and the hydrophobic effect. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (Web of Science; OpenAlex)
Sources: Crossref, NC State University Libraries, ORCID
Added: December 6, 2018

2012 journal article

Formation and Antifouling Properties of Amphiphilic Coatings on Polypropylene Fibers

Biomacromolecules, 13(11), 3769–3779.

By: K. Goli, O. Rojas* & J. Genzer*

MeSH headings : Adsorption; Borohydrides / chemistry; Glutaral / chemistry; Hydrophobic and Hydrophilic Interactions; Methacrylates / chemistry; Polymerization; Polymers / chemical synthesis; Polypropylenes / chemistry; Protein Denaturation; Silanes / chemistry; Surface Properties; Surface-Active Agents / chemical synthesis
TL;DR: The results suggest that amphiphilic coatings suppress significantly adsorption of proteins as compared with PP fibers or PP surfaces coated with PHEMA brushes. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Crossref, NC State University Libraries
Added: September 6, 2020

2012 journal article

Formation of Polyampholyte Brushes via Controlled Radical Polymerization and Their Assembly in Solution

Langmuir, 28(1), 872–882.

By: Y. Jhon n, S. Arifuzzaman n, A. Özçam n, D. Kiserow n & J. Genzer n

TL;DR: It is demonstrated that ARGET-ATRP of NaMA provides a convenient route to preparation of PMAA, which is an alternative method to the more traditional approach based on preparing PMAA by polymerizing tert-butyl methacrylate (tBMA) followed by cleavage of the tert- butyl group. (via Semantic Scholar)
Sources: Crossref, NC State University Libraries
Added: December 27, 2020

2012 journal article

Generation of Functional Coatings on Hydrophobic Surfaces through Deposition of Denatured Proteins Followed by Grafting from Polymerization

BIOMACROMOLECULES, 13(5), 1371–1382.

By: K. Goli n, O. Rojas n, A. Oezcam & J. Genzer n

MeSH headings : Adsorption; Antigens, Plant / chemistry; Globulins / chemistry; Hydrophobic and Hydrophilic Interactions; Polymerization; Polypropylenes / chemistry; Protein Denaturation / drug effects; Protein Stability; Seed Storage Proteins / chemistry; Silanes / chemistry; Soybean Proteins / chemistry; Surface Properties; Temperature; Urea / pharmacology
TL;DR: Hydrophilic coatings were produced on flat hydrophobic substrates featuring n-octadecyltrichlorosilane (ODTS) and synthetic polypropylene (PP) nonwoven surfaces through the adsorption of denatured proteins, yielding enhanced wettability. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Generation of functional PET microfibers through surface-initiated polymerization

JOURNAL OF MATERIALS CHEMISTRY, 22(12), 5855–5864.

By: A. Oezcam, K. Roskov n, R. Spontak n & J. Genzer n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Influence of gradient strength and composition profile on the onset of the cloud point transition in hydroxyethyl methacrylate/dimethylaminoethyl methacrylate gradient copolymers

POLYMER, 53(5), 1131–1137.

By: K. Gallow*, Y. Jhon n, J. Genzer n & Y. Loo*

author keywords: Gradient Copolymers; Composition Profile; Cloud Point
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Interfacial stabilization of bilayered nanolaminates by asymmetric block copolymers

APPLIED PHYSICS LETTERS, 100(10).

By: A. Gozen n, J. Genzer n & R. Spontak n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Oligomer Orientation in Vapor-Molecular-Layer-Deposited Alkyl-Aromatic Polyamide Films

LANGMUIR, 28(28), 10464–10470.

By: Q. Peng n, K. Efimenko n, J. Genzer n & G. Parsons n

Contributors: Q. Peng n, K. Efimenko n, J. Genzer n & G. Parsons n

MeSH headings : Alkylation; Molecular Structure; Nylons / chemical synthesis; Nylons / chemistry; Surface Properties; Volatilization
TL;DR: Near-edge X-ray absorption fine structure (NEXAFS) spectroscopy is used to offer insight into molecular orientation in films deposited via molecular-layer deposition (MLD) and shows that the oligomer units are lying nearly parallel to the surface, which differs from the linear vertical growth mode often used to illustrate film growth. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2012 journal article

Phase behavior of gradient copolymer solutions: a Monte Carlo simulation study

SOFT MATTER, 8(24), 6471–6482.

By: G. Pandav*, V. Pryamitsyn*, K. Gallow*, Y. Loo*, J. Genzer n & V. Ganesan*

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Responsive PET Nano/Microfibers via Surface-Initiated Polymerization

ACS APPLIED MATERIALS & INTERFACES, 4(1), 59–64.

By: A. Ozcam n, K. Roskov n, J. Genzer n & R. Spontak n

author keywords: electrospinning; polymer brush; poly(ethylene terephthalate); responsive polymer; surface functionalization
MeSH headings : Acrylamides / chemistry; Acrylic Resins; Nanofibers / chemistry; Polyethylene Glycols / chemistry; Polyethylene Terephthalates; Polymerization; Polymers / chemical synthesis; Polymers / chemistry
TL;DR: Water contact-angle measurements conducted at temperatures below and above the lower critical solution temperature of PNIPAAm, coupled with adsorption of Au nanoparticles from aqueous suspension, demonstrate that the brushes retain their reversible thermoresponsive nature, thereby making PNipAAm-functionalized PET microfibers suitable for filtration media, tissue scaffolds, delivery vehicles, and sensors requiring robust microf fibers. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Self-folding of polymer sheets using local light absorption

SOFT MATTER, 8(6), 1764–1769.

By: Y. Liu n, J. Boyles n, J. Genzer n & M. Dickey n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2012 book

Soft matter gradient surfaces: methods and applications

By: J. Genzer

Sources: NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2012 article

Surface-Bound Gradients for Studies of Soft Materials Behavior

ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 42, Vol. 42, pp. 435–468.

By: J. Genzer n

author keywords: self-assembly; grafted polymer; polymer brush; screening; directed motion; combinatorial materials science; high throughput; soft materials
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Surface-Initiated Polymerization by Means of Novel, Stable, Non-Ester-Based Radical Initiator

MACROMOLECULES, 45(9), 3802–3815.

By: E. Bain n, K. Dawes n, A. Oezcam, X. Hu n, C. Gorman n, J. Srogl*, J. Genzer n

Contributors: E. Bain n, K. Dawes n, A. Oezcam, X. Hu n, C. Gorman n, J. Srogl*, J. Genzer n

Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2012 journal article

The effect of confinement on thermal frontal polymerization

POLYMER CHEMISTRY, 3(12), 3243–3246.

By: P. Datta n, K. Efimenko n & J. Genzer n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Time Dependence of Lysozyme Adsorption on End-Grafted Polymer Layers of Variable Grafting Density and Length

LANGMUIR, 28(4), 2122–2130.

By: J. Genzer n, S. Arifuzzaman n, R. Bhat n, K. Efimenko n, C. Ren* & I. Szleifer*

MeSH headings : Adsorption; Biofouling; Models, Molecular; Muramidase / chemistry; Polyhydroxyethyl Methacrylate / chemistry; Silicon Dioxide / chemistry; Surface Properties; Time Factors
TL;DR: This work monitors the time dependence of adsorption of lysozyme on surfaces comprising polymer assemblies made of poly(2-hydroxyethyl methacrylate) brushes grafted onto flat silica surfaces such that they produce patterns featuring orthogonal and gradual variation of the chain length and grafting density. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Adsorption of PEO-PPO-PEO Triblock Copolymers with End-Capped Cationic Chains of Poly(2-dimethylaminoethyl methacrylate)

LANGMUIR, 27(16), 9769–9780.

By: X. Liu*, A. Vesterinen*, J. Genzer*, J. Seppala* & O. Rojas*

MeSH headings : Adsorption; Ethylamines / chemistry; Methacrylates / chemistry; Polyethylene Glycols / chemistry; Polymers / chemistry; Propylene Glycols / chemistry; Surface Properties
TL;DR: The results obtained are much lower, as expected, when compared with results obtained at the air/liquid interface, where a tighter packing is observed, and the percentage of water coupled to the adsorbed cationic polymer decreases with solution ionic strength. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Block copolymer self-organization vs. interfacial modification in bilayered thin-film laminates

SOFT MATTER, 7(7), 3268–3272.

By: A. Gozen n, J. Zhou*, K. Roskov n, A. Shi*, J. Genzer n & R. Spontak n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Charge- and temperature-dependent interactions between anionic poly (N-isopropylacrylamide) polymers in solution and a cationic surfactant at the water/air interface

SOFT MATTER, 7(18), 8498–8507.

By: S. Volden*, J. Genzer n, K. Zhu*, M. Ese*, B. Nystrom* & W. Glomm*

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Cloud Point Suppression in Dilute Solutions of Model Gradient Copolymers with Prespecified Composition Profiles

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 49(9), 629–637.

By: K. Gallow*, Y. Jhon n, W. Tang*, J. Genzer n & Y. Loo*

author keywords: atom transfer radical polymerization; cloud point; composition profile; dimethylaminoethyl methacrylate; dilute aqueous solutions; gradient copolymers; gradient strength; hydroxyethyl methacrylate; monomer sequence distribution
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Effect of copolymer compatibilizer sequence on the dynamics of phase separation of immiscible binary homopolymer blends

SOFT MATTER, 7(22), 10620–10630.

By: R. Malik n, C. Hall n & J. Genzer n

UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Metallothionein-inspired prototype of molecular pincer

CHEMICAL COMMUNICATIONS, 47(28), 8067–8069.

By: S. Voltrova*, D. Hidasova*, J. Genzer n & J. Srogl*

MeSH headings : Amides / chemistry; Cysteine / chemistry; Imides / chemistry; Lead / chemistry; Metallothionein / chemistry; Oxidation-Reduction; Zinc / chemistry
TL;DR: Study of Zn and Pb release from complexes with natural and synthetic amidothiol motifs inspired the design of a "molecular pincer" that scavenges quantitatively metals from liquid environment and releases them, on-demand, under very mild oxidative conditions. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Multilayers of Weak Polyelectrolytes of Low and High Molecular Mass Assembled on Polypropylene and Self-Assembled Hydrophobic Surfaces

LANGMUIR, 27(8), 4541–4550.

By: X. Liu n, K. Goli*, J. Genzer* & O. Rojas*

MeSH headings : Electrolytes / chemistry; Hydrophobic and Hydrophilic Interactions; Molecular Weight; Polyelectrolytes; Polymers / chemistry; Polypropylenes / chemistry; Surface Properties
TL;DR: The assembly of highly dissipative polyelectrolyte multilayers (PEMs) is demonstrated by quartz crystal microgravimetry and shows that, despite the expected interdiffusion for the different polymer chains, there is a net macromolecular segregation to the free surface. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Phase Separation Dynamics for a Polymer Blend Compatibilized by Protein-like Copolymers: A Monte Carlo Simulation

MACROMOLECULES, 44(20), 8284–8293.

By: R. Malik n, C. Hall n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Photochromic materials with tunable color and mechanical flexibility

SOFT MATTER, 7(8), 3766–3774.

By: H. Yang n, A. Ozcam n, K. Efimenko n & J. Genzer n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Poly(2-hydroxyethyl methacrylate) for Enzyme Immobilization: Impact on Activity and Stability of Horseradish Peroxidase

BIOMACROMOLECULES, 12(5), 1822–1830.

By: S. Lane*, Z. Kuang*, J. Yom*, S. Arifuzzaman n, J. Genzer n, B. Farmer*, R. Naik*, R. Vaia*

MeSH headings : Enzyme Stability; Enzymes, Immobilized / chemistry; Enzymes, Immobilized / metabolism; Horseradish Peroxidase / metabolism; Kinetics; Molecular Dynamics Simulation; Polyhydroxyethyl Methacrylate / chemistry
TL;DR: A general enzyme-brush coupling motif must optimize reactive group density to balance binding with neutrality of surroundings to prevent loss of activity. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2011 journal article

Poly(vinylmethylsiloxane) Elastomer Networks as Functional Materials for Cell Adhesion and Migration Studies

BIOMACROMOLECULES, 12(4), 1265–1271.

By: S. Ahmed n, H. Yang n, A. Ozcam n, K. Efimenko n, M. Weiger n, J. Genzer n, J. Haugh n

MeSH headings : Amino Acid Sequence; Animals; Cell Adhesion; Cell Movement; Mice; Microscopy, Fluorescence; Molecular Sequence Data; NIH 3T3 Cells; Oligopeptides / chemistry; Polyvinyls / chemistry; Siloxanes / chemistry
TL;DR: These experiments show that a peptide containing the synergy sequence of fibronectin (PHSRN) in addition to RGD promotes more productive cell migration without markedly enhancing cell adhesion strength. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2011 journal article

Simultaneous Bulk- and Surface-Initiated Controlled Radical Polymerization from Planar Substrates

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(44), 17567–17569.

By: S. Turgman-Cohen n & J. Genzer n

MeSH headings : Computer Simulation; Free Radicals / chemical synthesis; Free Radicals / chemistry; Monte Carlo Method; Polymerization; Polymers / chemical synthesis; Polymers / chemistry; Surface Properties
TL;DR: This work uses Monte Carlo computer simulations to investigate the simultaneous controlled radical polymerization in solution and from a flat surface, providing evidence that the assumption that the molecular weight of surface-initiated polymers is equal to that of polymers grown in bulk is generally invalid. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

ATRP of 2-Vinylpyridine and tert-Butyl Acrylate Mixtures Giving Precursors of Polyampholytes

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 48(3), 735–741.

By: E. Cadova*, J. Konecny*, J. Kriz*, R. Svitakova*, P. Holler*, J. Genzer n, P. Vlcek*

author keywords: atom transfer radical polymerization (ATRP); copolymerization; polyelectrolytes
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Adsorption of a Nonionic Symmetric Triblock Copolymer on Surfaces with Different Hydrophobicity

LANGMUIR, 26(12), 9565–9574.

MeSH headings : Adsorption; Hydrophobic and Hydrophilic Interactions; Microscopy, Atomic Force; Polymers / chemistry; Surface Plasmon Resonance; Surface Properties
TL;DR: In insights are provided into the structure and stability of both hydrated and nonhydrated adsorbed triblock copolymer, which produce modest increases in hydrophilicity of all the substrates investigated. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (Web of Science; OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Computer Simulation of Controlled Radical Polymerization Effect of Chain Confinement Due to Initiator Grafting Density and Solvent Quality in "Grafting From" Method

MACROMOLECULES, 43(22), 9567–9577.

By: S. Turgman-Cohen n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Controlling comonomer distribution in random copolymers by chemical coloring of surface-tethered homopolymers: An insight from discontinuous molecular dynamics simulation

Langmuir, 26(11), 8810–8820.

By: L. Strickland n, C. Hall n & J. Genzer n

TL;DR: It is demonstrated that the comonomer distribution in the A(1-x)B(x) RCPs depends on the interplay among (1) the length and the grafting density of the A-based homopolymer anchors, (2) the solubility of the parent homopolymers, and (3) thesolubilityof the B coloring units. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2010 review

Emerging applications of stimuli-responsive polymer materials

[Review of ]. NATURE MATERIALS, 9(2), 101–113.

MeSH headings : Biosensing Techniques; Drug Carriers / chemistry; Drug Carriers / metabolism; Models, Molecular; Nanoparticles / chemistry; Polymers / chemistry; Polymers / metabolism; Surface Properties
TL;DR: This work reviews recent advances and challenges in the developments towards applications of stimuli-responsive polymeric materials that are self-assembled from nanostructured building blocks and provides a critical outline of emerging developments. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Formation of silicone elastomer networks films with gradients in modulus

POLYMER, 51(3), 763–773.

By: J. Crowe-Willoughby n, K. Weiger n, A. Ozcam n & J. Genzer n

author keywords: Silicone elastomer; Gradient; Modulus
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Glass Transition Temperatures of Styrene/4-BrStyrene Copolymers with Variable Co-Monomer Compositions and Sequence Distributions

MACROMOLECULES, 43(16), 6912–6914.

By: A. Tonelli n, Y. Jhon n & J. Genzer n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Investigating the Molecular Origins of Responsiveness in Functional Silicone Elastomer Networks

MACROMOLECULES, 43(11), 5043–5051.

By: J. Crowe-Willoughby n, D. Stevens n, J. Genzer n & L. Clarke n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Neutron reflectometry of supported hybrid bilayers with inserted peptide

SOFT MATTER, 6(5), 862–865.

By: M. Smith n, D. McGillivray*, J. Genzer n, M. Losche* & P. Kilpatrick n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Polymer Nanotubules Obtained by Layer-by-Layer Deposition within AAO-Membrane Templates with Sub-100-nm Pore Diameters

SMALL, 6(23), 2683–2689.

By: Y. Cho*, W. Lee*, Y. Jhon n, J. Genzer n & K. Char*

MeSH headings : Microscopy, Atomic Force; Nanotechnology / methods; Nanotubes / chemistry; Nanotubes / ultrastructure; Polymers / chemistry; Porosity
TL;DR: The layer-by-layer (LbL) deposition technique on templates has been one of the most popular methods for the formation of nanotubes. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Protein-Like Copolymers (PLCs) as Compatibilizers for Homopolymer Blends

Macromolecules, 43(11), 5149–5157.

By: R. Malik n, C. Hall n & J. Genzer n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, Crossref
Added: August 6, 2018

2010 journal article

Simulation of Mechanically-Assembled Monolayers In Poor Solvent Using Discontinuous Molecular Dynamics

MACROMOLECULES, 43(6), 3072–3080.

By: L. Strickland, C. Hall* & J. Genzer*

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Surface and Friction Behavior of a Silicone Surfactant Adsorbed on Model Textiles Substrates

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 49(18), 8550–8557.

By: X. Liu n, J. Song n, D. Wu n, J. Genzer n, T. Theyson n & O. Rojas n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2010 journal article

Temperature-Dependent Optical Properties of Gold Nanoparticles Coated with a Charged Diblock Copolymer and an Uncharged Triblock Copolymer

ACS NANO, 4(2), 1187–1201.

By: S. Volden*, A. Kjoniksen*, K. Zhu*, J. Genzer n, B. Nystrom* & W. Glomm*

author keywords: Mie-Drude; localized surface plasmon resonance; thermoresponsive NIPAAM polymers; ultraviolet spectroscopy; adsorption; dynamic light scattering; lower critical solution temperature
MeSH headings : Adsorption; Europium / chemistry; Gold / chemistry; Metal Nanoparticles / chemistry; Nanotechnology; Optical Phenomena; Polymers / chemistry; Spectrometry, Fluorescence; Surface Properties; Temperature
TL;DR: It is demonstrated that the optical properties of gold nanoparticles can be used to detect and follow stimuli-induced changes in adsorbed macromolecules, and flocculation behavior of the neutral copolymer on planar gold surfaces results in multilayer formation. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 journal article

Asphaltene Adsorption onto Self-Assembled Monolayers of Alkyltrichlorosilanes of Varying Chain Length

ACS APPLIED MATERIALS & INTERFACES, 1(6), 1347–1357.

author keywords: asphaltenes; self-assembled monolayers; alklyltrichlorosilanes; NEXAFS; ellipsometry; wettability
TL;DR: The adsorption of asphaltenes onto flat silica surfaces modified with self-assembled monolayers of alkyltrichlorosilanes of varying thickness due to a variable number of carbon atoms has been studied by means of contact angle measurements, spectroscopic ellipsometry, and near-edge X-ray absorption fine structure spectroscopy. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 journal article

Asphaltene Adsorption onto Self-Assembled Monolayers of Mixed Aromatic and Aliphatic Trichlorosilanes

LANGMUIR, 25(11), 6260–6269.

TL;DR: The adsorption of asphaltenes onto flat solid surfaces modified with mixed self-assembled monolayers of aliphatic and aromatic trichlorosilanes with varying wettabilities, aromaticities, and thicknesses is tested and suggests that the leading interaction governing the adsor adaptation of asphtenes is their interaction with the polar silica substrate and that the chemical composition of the SAM is of secondary importance. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 journal article

Design of copolymers with tunable randomness using discontinuous molecular dynamics simulation

Macromolecules, 42(22), 9063–9071.

By: L. Strickland n, C. Hall n & J. Genzer n

UN Sustainable Development Goal Categories
Sources: NC State University Libraries, NC State University Libraries
Added: August 6, 2018

2009 journal article

Determination of the Electron Escape Depth for NEXAFS Spectroscopy

LANGMUIR, 25(11), 6341–6348.

By: K. Sohn*, M. Dimitriou*, J. Genzer n, D. Fischer*, C. Hawker* & E. Kramer*

MeSH headings : Electrons; Ethers / chemistry; Models, Biological; Polymers / chemistry; Spectrometry, X-Ray Emission / methods; Surface Properties
TL;DR: It is shown that the common assumption in the analysis of NEXAFS data from polymer films, namely, that the carbon atom density is constant as a function of depth, is not valid. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 journal article

Development and Testing of Hierarchically Wrinkled Coatings for Marine Antifouling

ACS APPLIED MATERIALS & INTERFACES, 1(5), 1031–1040.

By: K. Efimenko n, J. Finlay n, M. Callow n, J. Callow n & J. Genzer n

author keywords: marine fouling; buckling; wrinkling; topographically corrugated substrate; Ulva settlement; barnacle settlement
MeSH headings : Animals; Biocompatible Materials / chemistry; Crystallization / methods; Dimethylpolysiloxanes / chemistry; Materials Testing; Seawater / chemistry; Surface Properties; Thoracica / growth & development
TL;DR: Observations suggest that surface topography plays a dominant role in governing the coating defense against barnacle fouling even without fine-tuning the chemical composition of the overcoat. (via Semantic Scholar)
UN Sustainable Development Goal Categories
14. Life Below Water (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 journal article

Discriminating Among Co-monomer Sequence Distributions in Random Copolymers Using Interaction Chromatography

MACROMOLECULAR RAPID COMMUNICATIONS, 30(18), 1543–1548.

By: J. Han*, B. Jeon*, C. Ryu n, J. Semler n, Y. Jhon n & J. Genzer n

author keywords: co-monomer sequence distribution; interaction chromatography; monomers; polystyrene; poly(styrene-co-4-bromostyrene); PBrxS; random copolymer adsorption
TL;DR: Interaction chromatography has been employed to validate that adsorption of poly[styrene-co-(4-bromostyrene)] (PBr(x) S) random copolymers, where x denotes the mole fraction, depends on the average number of adsorptive segments, the type of Adsorbing substrate, and on the co-monomer sequence distribution in PBr( x) S. (via Semantic Scholar)
UN Sustainable Development Goal Categories
10. Reduced Inequalities (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 journal article

Dispersion of Cellulose Crystallites by Nonionic Surfactants in a Hydrophobic Polymer Matrix

POLYMER ENGINEERING AND SCIENCE, 49(10), 2054–2061.

By: J. Kim n, G. Montero n, Y. Habibi n, J. Hinestroza*, J. Genzer n, D. Argyropoulos n, O. Rojas n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 journal article

Effect of Comonomer Sequence Distribution on the Adsorption of Random Copolymers onto Impenetrable Flat Surfaces

MACROMOLECULES, 42(7), 2843–2853.

By: Y. Jhon n, J. Semler n, J. Genzer n, M. Beevers n, O. Gus'kova n, P. Khalatur n, A. Khokhlov n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2009 journal article