Works (18)

Updated: August 28th, 2023 21:15

2017 journal article

Catalytic "MOF-Cloth" Formed via Directed Supramolecular Assembly of UiO-66-NH2 Crystals on Atomic Layer Deposition-Coated Textiles for Rapid Degradation of Chemical Warfare Agent Simulants

CHEMISTRY OF MATERIALS, 29(11), 4894–4903.

By: D. Lee n, J. Zhao n, G. Peterson & G. Parsons n

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2016 journal article

Atomically Thin MoS2 Narrowband and Broadband Light Superabsorbers

ACS NANO, 10(8), 7493–7499.

By: L. Huang n, G. Li n, A. Gurarslan n, Y. Yu n, R. Kirste n, W. Guo n, J. Zhao n, R. Collazo n ...

Contributors: L. Huang n, G. Li n, A. Gurarslan n, Y. Yu n, R. Kirste n, W. Guo n, J. Zhao n, R. Collazo n ...

author keywords: MoS2; two-dimensional materials; light absorption; leaky mode; resonant photonics
TL;DR: A combined theoretical and experimental effort to enable strong light absorption in atomically thin MoS2 films by integrating the films with resonant photonic structures that are deterministically designed using a unique reverse design approach based on leaky mode coupling. (via Semantic Scholar)
UN Sustainable Development Goal Categories
7. Affordable and Clean Energy (OpenAlex)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2016 journal article

Copper Benzenetricarboxylate Metal-Organic Framework Nucleation Mechanisms on Metal Oxide Powders and Thin Films formed by Atomic Layer Deposition

ACS APPLIED MATERIALS & INTERFACES, 8(14), 9514–9522.

By: P. Lemaire n, J. Zhao n, P. Williams n, H. Walls*, S. Shepherd*, M. Losego n, G. Peterson, G. Parsons n

Contributors: P. Lemaire n, J. Zhao n, P. Williams n, H. Walls*, S. Shepherd*, M. Losego n, G. Peterson, G. Parsons n

author keywords: metal-organic framework; atomic layer deposition; Cu-BTC; HKUST-1; hydroxy double salt; metal oxide; nucleation
TL;DR: It is found that thin inorganic nucleation layers formed by atomic layer deposition (ALD) can promote solvothermal growth of copper benzenetricarboxylate MOF (Cu-BTC) on various substrate surfaces. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2016 journal article

Diffusion of CO2 in Large Crystals of Cu-BTC MOF

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(36), 11449–11452.

Contributors: T. Tovar*, J. Zhao n, W. Nunn n, H. Barton n, G. Peterson*, G. Parsons n, M. LeVan*

TL;DR: A new reproducible procedure to synthesize millimeter-scale Cu- BTC single crystals using concentrated reactants and an acetic acid modulator is described, confirming the high quality of these Cu-BTC single crystals. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2016 journal article

Ultra-Fast Degradation of Chemical Warfare Agents Using MOF-Nanofiber Kebabs

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(42), 13224–13228.

By: J. Zhao n, D. Lee n, R. Yaga*, M. Hall, H. Barton n, I. Woodward n, C. Oldham n, H. Walls*, G. Peterson, G. Parsons n

Contributors: J. Zhao n, D. Lee n, R. Yaga*, M. Hall, H. Barton n, I. Woodward n, C. Oldham n, H. Walls*, G. Peterson, G. Parsons n

author keywords: atomic layer deposition; chemical warfare agents; metal-organic frameworks; nanofibers; thin films
TL;DR: The results therefore provide the earliest report of MOF-nanofiber textile composites capable of ultra-fast degradation of CWAs and exhibit excellent reactivity for detoxifying CWAs. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2016 journal article

Ultralight Interconnected Metal Oxide Nanotube Networks

SMALL, 12(18), 2432–2438.

By: K. Stano n, S. Faraji n, R. Hodges n, O. Yildiz n, B. Wells n, H. Akyildiz n, J. Zhao n, J. Jur n, P. Bradford n

TL;DR: Record-breaking ultralow density aluminum oxide structures are prepared using a novel templating technique and the application of the low density networks as humidity sensing materials as well as thermal insulation is demonstrated. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2016 journal article

Wicking Enhancement in Three-Dimensional Hierarchical Nanostructures

LANGMUIR, 32(32), 8029–8033.

By: Z. Wang n, J. Zhao n, A. Bagal n, E. Dandley n, C. Oldham n, T. Fang n, G. Parsons n, C. Chang n

Contributors: Z. Wang n, J. Zhao n, A. Bagal n, E. Dandley n, C. Oldham n, T. Fang n, G. Parsons n, C. Chang n

TL;DR: Enhanced wicking dynamics is demonstrated by using nanostructures with three-dimensional (3D) hierarchical features to increase the surface area while mitigating the obstruction of liquid flow. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2015 journal article

Facile Conversion of Hydroxy Double Salts to Metal-Organic Frameworks Using Metal Oxide Particles and Atomic Layer Deposition Thin-Film Templates

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(43), 13756–13759.

By: J. Zhao n, W. Nunn n, P. Lemaire n, Y. Lin n, M. Dickey n, C. Oldham n, H. Walls*, G. Peterson ...

Contributors: J. Zhao n, W. Nunn n, P. Lemaire n, Y. Lin n, M. Dickey n, C. Oldham n, H. Walls*, G. Peterson, M. Losego*, G. Parsons n

TL;DR: (Zn,Cu) hydroxy double salt intermediate formed in situ from ZnO particles or thin films enables rapid growth of HKUST-1 (Cu3(BTC)2) at room temperature, and the space-time-yield reaches >3 × 10(4) kg·m(-3)·d(-1), at least 1 order of magnitude greater than any prior report. (via Semantic Scholar)
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2015 journal article

Multifunctional nano-accordion structures for stretchable transparent conductors

MATERIALS HORIZONS, 2(5), 486–494.

By: A. Bagal n, E. Dandley n, J. Zhao n, X. Zhang n, C. Oldham n, G. Parsons n, C. Chang n

Contributors: A. Bagal n, E. Dandley n, J. Zhao n, X. Zhang n, C. Oldham n, G. Parsons n, C. Chang n

UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2015 journal article

Ordered 3D Thin-Shell Nanolattice Materials with Near-Unity Refractive Indices

ADVANCED FUNCTIONAL MATERIALS, 25(42), 6644–6649.

By: X. Zhang n, A. Bagal n, E. Dandley n, J. Zhao n, C. Oldham n, B. Wu*, G. Parsons n, C. Chang n

Contributors: X. Zhang n, A. Bagal n, E. Dandley n, J. Zhao n, C. Oldham n, B. Wu*, G. Parsons n, C. Chang n

Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2014 journal article

A Model for the Flexibility of the Distal Histidine in Dehaloperoxidase-Hemoglobin A Based on X-ray Crystal Structures of the Carbon Monoxide Adduct

BIOCHEMISTRY, 53(15), 2474–2482.

By: J. Zhao n, V. Serrano n & S. Franzen n

MeSH headings : Amino Acid Sequence; Carbon Monoxide / chemistry; Crystallography, X-Ray; Electrophoresis, Polyacrylamide Gel; Hemoglobin A / chemistry; Hemoglobins / chemistry; Histidine / chemistry; Molecular Sequence Data; Peroxidases / chemistry; Protein Conformation
TL;DR: The X-ray crystallographic structure of the carbonmonoxy complex (DHPCO) is reported, supporting the modified hypothesis suggesting a competition between the strength of interactions with heme ligand and the heme propionates as the factors that determine the conformation of the distal histidine. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2014 journal article

Conformal and highly adsorptive metal-organic framework thin films via layer-by-layer growth on ALD-coated fiber mats

JOURNAL OF MATERIALS CHEMISTRY A, 3(4), 1458–1464.

By: J. Zhao n, B. Gong n, W. Nunn n, P. Lemaire n, E. Stevens n, F. Sidi n, P. Williams n, C. Oldham n ...

Contributors: J. Zhao n, B. Gong n, W. Nunn n, P. Lemaire n, E. Stevens n, F. Sidi n, P. Williams n, C. Oldham n ...

Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2014 journal article

Highly adsorptive, MOF-functionalized nonwoven fiber mats for hazardous gas capture enabled by atomic layer deposition

Advanced Materials Interfaces, 1(4).

By: J. Zhao, M. Losego, P. Lemaire, P. Williams, B. Gong, S. Atanasov, T. Blevins, C. Oldham ...

Source: NC State University Libraries
Added: August 6, 2018

2013 journal article

Functional Consequences of the Open Distal Pocket of Dehaloperoxidase-Hemoglobin Observed by Time-Resolved X-ray Crystallography

BIOCHEMISTRY, 52(45), 7943–7950.

By: J. Zhao n, V. Srajer* & S. Franzen n

MeSH headings : Binding Sites; Carbon Monoxide / chemistry; Carbon Monoxide / metabolism; Crystallography, X-Ray / methods; Hemoglobins / chemistry; Hemoglobins / metabolism; Peroxidases / chemistry; Peroxidases / metabolism
TL;DR: Using time-resolved X-ray crystallography, a bifunctional dehaloperoxidase-hemoglobin (DHP) is contrasted with previously studied examples of myoglobin and hemoglobin to understand the functional role of the distal pocket of globins. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

Structural and Kinetic Study of an Internal Substrate Binding Site in Dehaloperoxidase-Hemoglobin A from Amphitrite ornata

BIOCHEMISTRY, 52(14), 2427–2439.

By: J. Zhao n, V. Serrano n, J. Zhao n, P. Le n & S. Franzen n

MeSH headings : 2-Propanol / chemistry; Animals; Crystallography, X-Ray; Dimethyl Sulfoxide / chemistry; Hemoglobins / chemistry; Hemoglobins / metabolism; Kinetics; Methanol / chemistry; Models, Molecular; Peroxidases / chemistry; Peroxidases / metabolism; Phenols / chemistry; Polychaeta / chemistry; Polychaeta / enzymology; Polychaeta / metabolism; Protein Conformation
TL;DR: The X-ray crystal structure is consistent with the presence of an internal active site above the heme α-edge, in which the substrate would be oxidized in two consecutive steps inside the enzyme, followed by attack by H2O via a water channel in the protein. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2013 journal article

The Regulatory Implications of Hydroquinone for the Multifunctional Enzyme Dehaloperoxidase-Hemoglobin from Amphitrite ornata

JOURNAL OF PHYSICAL CHEMISTRY B, 117(47), 14615–14624.

By: J. Zhao n, J. Zhao n & S. Franzen n

MeSH headings : Animals; Chlorophenols / metabolism; Hemoglobins / chemistry; Hemoglobins / metabolism; Hydrogen Peroxide / metabolism; Hydroquinones / metabolism; Models, Molecular; Multifunctional Enzymes / chemistry; Multifunctional Enzymes / metabolism; Oxidation-Reduction; Peroxidases / chemistry; Peroxidases / metabolism; Phenols / metabolism; Polychaeta / chemistry; Polychaeta / enzymology; Polychaeta / metabolism
TL;DR: Light is shed on understanding the difference between substrate and inhibitor binding sites and regulatory implication for the peroxidase and oxygen-transporter functions in DHP, and the reversible reactions between ferric/oxyferrous DHP A and H2Q/1,4-BQ are shown to involve a proton-coupled electron transfer (PCET) mechanism. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

Catalytic efficiency of dehaloperoxidase A is controlled by electrostatics - application of the vibrational Stark effect to understand enzyme kinetics

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 430(3), 1011–1015.

author keywords: Vibrational Stark effect; Hemoglobin; 4-mercaptobenzonitrile; Enzyme kinetics; Electric field
MeSH headings : Animals; Catalysis; Kinetics; Mutation; Peroxidase / chemistry; Peroxidase / genetics; Peroxidases / chemistry; Peroxidases / genetics; Polychaeta / enzymology; Protein Conformation; Spectroscopy, Fourier Transform Infrared; Static Electricity; Vibration
TL;DR: By labeling the protein with 4-mercaptobenzonitrile (MBN), a Stark probe molecule, this work provides further evidence that the diffusion control of the catalytic process arises from the electrostatic repulsion between the enzyme and the negatively charged substrate. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2012 journal article

The Role of the Distal Histidine in H2O2 Activation and Heme Protection in both Peroxidase and Globin Functions

The Journal of Physical Chemistry B, 116(40), 12065–12077.

By: J. Zhao n, V. de Serrano n, R. Dumarieh n, M. Thompson n, R. Ghiladi n & S. Franzen n

Contributors: J. Zhao n, V. De Serrano n, R. Dumarieh n, M. Thompson n, R. Ghiladi n & S. Franzen n

MeSH headings : Biocatalysis; Chlorophenols / chemistry; Chlorophenols / metabolism; Heme / chemistry; Heme / metabolism; Hemoglobin A / chemistry; Hemoglobin A / metabolism; Histidine / chemistry; Histidine / genetics; Histidine / metabolism; Hydrogen Peroxide / chemistry; Hydrogen Peroxide / metabolism; Models, Molecular; Molecular Structure; Mutation; Oxidation-Reduction; Peroxidases / chemistry; Peroxidases / metabolism; Quinones / chemistry; Quinones / metabolism
TL;DR: The distal histidine mutations of dehaloperoxidase-hemoglobin A to aspartate (H55D) and asparagine and H55N have been prepared to study the role played by the distal Histidine in both activation and protection against oxidation by radicals in heme proteins. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID, Crossref
Added: August 6, 2018

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