An unsupported metal hydroxide for the design of molecular μ-oxo bridged heterobimetallic complexes
Falzone, A. J., Nguyen, J., Weare, W. W., Sommer, R. D., & Boyle, P. D. (2013, December 24). Chemical Communications, Vol. 50, pp. 2139–2141.
MeSH headings : Chromium / chemistry; Coordination Complexes / chemical synthesis; Coordination Complexes / chemistry; Crystallography, X-Ray; Electrochemical Techniques; Hydroxides / chemistry; Molecular Conformation; Oxidation-Reduction; Oxygen / chemistry; Solar Energy; Titanium / chemistry
topics (OpenAlex): Metal-Catalyzed Oxygenation Mechanisms; Organometallic Complex Synthesis and Catalysis; Magnetism in coordination complexes
TL;DR:
The terminal hydroxide is used to synthesize the first example of a heterobimetallic Ti-O-Cr compound containing an unsupported μ-oxo bridge and exhibits a new absorbance at 288 nm (4.32 eV), which is assigned to a metal-to-metal charge transfer (MMCT) transition.
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