@article{sohail_cheadle_khan_mane_salem_ernst_miguel_opperman_pirzada_crook_et al._2025, title={Pickering Emulsion for Enhanced Viability of Plant Growth Promoting Bacteria and Combined Delivery of Agrochemicals and Biologics}, ISSN={["1616-3028"]}, url={https://doi.org/10.1002/adfm.202418272}, DOI={10.1002/adfm.202418272}, abstractNote={Abstract Non‐sporulating plant growth‐promoting bacteria (PGPB) are widely underutilized in the bio‐based agroindustry due to difficulties in maintaining viability without spores. A unique approach is presented to prepare PGPB‐based green formulations by integrating Gram‐negative, nonsporulating PGPBs: Pseudomonas simiae (Psi) and Azospirillum brasilense ( Abr ) into cellulose acetate stabilized Pickering emulsions. The bacteria show enhanced survivability within the emulsions without any nutrient supply after 4 weeks of storage with Psi and Abr showing 200% and 500% increases respectively relative to non‐nutritive saline (1X PBS) control. Transcriptomics suggest that lysed bacteria from the emulsification process act as crucial nutrient sources, thereby boosting bacterial survival rates. Moreover, these PGPBs maintain survival even in the presence of the model pesticide fluopyram, with Pseudomonas simiae concentration showing a twofold increase after 1 month of storage while still preserving the efficacy of fluopyram against target pests. This robust survival trait among nonsporulating PGPB marks a notable advancement in developing formulations tailored specifically for these organisms. It underscores their untapped potential for practical applications in agricultural and environmental contexts. Furthermore, the emulsions enable simultaneous loading of biologicals (PGPBs) and agrochemical pesticides without compromising performance, thus offering the promise of a single loading platform to deliver multiple actives.}, journal={ADVANCED FUNCTIONAL MATERIALS}, author={Sohail, Mariam and Cheadle, John and Khan, Rishum and Mane, Hrishikesh and Salem, Khandoker Samaher and Ernst, Katie and Miguel, Adriana San and Opperman, Charles H. and Pirzada, Tahira and Crook, Nathan and et al.}, year={2025}, month={Feb} } @article{perera_ernst_tafreshi_khan_2024, title={Viscoelastic Fluid Stresses in the Formation and Shaping of Melt-Spun Hollow Fibers}, volume={12}, ISSN={["2771-9545"]}, url={https://doi.org/10.1021/acsaenm.4c00551}, DOI={10.1021/acsaenm.4c00551}, abstractNote={Hollow fibers are considered for a wide range of applications as their inherent internal void geometry enhances functionality and reduces material need. This study examines how stresses in polymer melts affect fiber void space and cross-sectional shapes during 4-C segmented arc melt spinning, a process where polymer extruded through four C-shaped arcs coalesce after extrusion to form a single hollow fiber. We conducted spinning trials under various conditions and analyzed hollow fiber cross sections by measuring circularity and hollowness, defined as the volume fraction of the fiber's hollow core relative to the total fiber volume. Rheological properties of different polypropylene melts at the temperature and conditions of spinning are related to the final fiber properties to show that the processing parameters of spinning temperature and flow rate are of significance. Experiments maintaining constant denier, or linear density, reveal that hollowness and circularity are related to the flow behavior through the Weissenberg number (Wi). At low Wi, hollowness increases with Wi; however, as Wi exceeds unity, the polymer takes on more elastic characteristics and the fiber transitions to constant hollowness, followed by instability at higher Wi values. Computational fluid dynamics (CFD) simulations using the Giesekus model allow for the analysis of stresses present during extrusion, revealing that uneven stress distributions at high Wi lead to a decrease in the circularity of the inside of the fiber. At low Wi, the extruded polymer melt has more viscous character and more time to resolve stresses in the melt before solidification, creating a fiber that retains less hollowness but more shape uniformity. A generalized inverse relationship between fiber circularity and hollowness is also observed across various polymer samples, flow rates, and temperatures. These findings provide valuable insights on hollow fiber spinning and predictions of hollow fiber geometry based on the viscoelastic properties of the polymer melt.}, journal={ACS APPLIED ENGINEERING MATERIALS}, author={Perera, Himendra S. and Ernst, Katherine J. and Tafreshi, Hooman V. and Khan, Saad A.}, year={2024}, month={Dec} }