2015 journal article

Oxyfunctionalization with Cp*Ir-III(NHC)(Me)(CI) with O-2: Identification of a Rare Bimetallic Ir-IV mu-Oxo Intermediate

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137(10), 3574–3584.

By: M. Lehman n, D. Pahls*, J. Meredith*, R. Sommer n, D. Heinekey*, T. Cundari*, E. Ison n

TL;DR: Isotope labeling studies confirmed the origin of the methyl group in the methanol product is the iridium-methyl bond in the [Cp*Ir(NHC)Me(CD2Cl2)][BAr(F)4] starting material, and DFT and MCSCF calculations reveal several important features of the electronic structure of 3. (via Semantic Scholar)
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Added: August 6, 2018

2014 journal article

Oxyfunctionalization with Cp*Ir-III(NHC)(Me)L Complexes

ORGANOMETALLICS, 33(19), 5081–5084.

By: M. Lehman n, P. Boyle n, R. Sommer n & E. Ison n

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2013 journal article

Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*Ir-III(L) Complexes

ACS CATALYSIS, 3(10), 2304–2310.

By: M. Lehman n, J. Gary*, P. Boyle n, M. Sanford* & E. Ison n

author keywords: H/D exchange; C-H activation; C-H functionalization; Cp*Ir-III catalysts; kinetics; isotope effects
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

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