Matthew Correll Lehman

Works (3)

Updated: July 5th, 2023 15:43

2015 article

Oxyfunctionalization with Cp*IrIII(NHC)(Me)(Cl) with O2: Identification of a Rare Bimetallic IrIV μ-Oxo Intermediate

Lehman, M. C., Pahls, D. R., Meredith, J. M., Sommer, R. D., Heinekey, D. M., Cundari, T. R., & Ison, E. A. (2015, February 21). Journal of the American Chemical Society, Vol. 137, pp. 3574–3584.

By: M. Lehman n, D. Pahls *, J. Meredith*, R. Sommer n , D. Heinekey *, T. Cundari *, E. Ison n 

topics (OpenAlex): N-Heterocyclic Carbenes in Organic and Inorganic Chemistry; Magnetism in coordination complexes; Organometallic Complex Synthesis and Catalysis
TL;DR: Isotope labeling studies confirmed the origin of the methyl group in the methanol product is the iridium-methyl bond in the [Cp*Ir(NHC)Me(CD2Cl2)][BAr(F)4] starting material, and DFT and MCSCF calculations reveal several important features of the electronic structure of 3. (via Semantic Scholar)
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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2014 article

Oxyfunctionalization with Cp*IrIII(NHC)(Me)L Complexes

Lehman, M. C., Boyle, P. D., Sommer, R. D., & Ison, E. A. (2014, September 16). Organometallics, Vol. 33, pp. 5081–5084.

By: M. Lehman n, P. Boyle n, R. Sommer n  & E. Ison n 

topics (OpenAlex): Organometallic Complex Synthesis and Catalysis; Asymmetric Hydrogenation and Catalysis; Metal-Catalyzed Oxygenation Mechanisms
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Sources: Web Of Science, ORCID, NC State University Libraries
Added: August 6, 2018

2013 article

Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*IrIII(L) Complexes

Lehman, M. C., Gary, J. B., Boyle, P. D., Sanford, M. S., & Ison, E. A. (2013, August 27). ACS Catalysis, Vol. 3, pp. 2304–2310.

By: M. Lehman n, J. Gary *, P. Boyle n, M. Sanford * & E. Ison n 

author keywords: H/D exchange; C-H activation; C-H functionalization; Cp*Ir-III catalysts; kinetics; isotope effects
topics (OpenAlex): Catalytic Cross-Coupling Reactions; Asymmetric Hydrogenation and Catalysis
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UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

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