Synthesis of Oxorhenium(V) Complexes with Diamido Amine Ancillary Ligands and Their Role in Oxygen Atom Transfer Catalysis
Feng, Y., Aponte, J., Houseworth, P. J., Boyle, P. D., & Ison, E. A. (2009, November 4). Inorganic Chemistry, Vol. 48, pp. 11058–11066.
MeSH headings : Amines / chemistry; Catalysis; Crystallography, X-Ray; Ligands; Models, Molecular; Molecular Structure; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Oxygen / chemistry; Rhenium / chemistry; Stereoisomerism
topics (OpenAlex): CO2 Reduction Techniques and Catalysts; Metal-Catalyzed Oxygenation Mechanisms; Metal complexes synthesis and properties
TL;DR:
Although the Re(VII) intermediate could not be isolated, its activity in OAT reactions was probed by competition experiments with PPh(3) and four para-substituted triarylphosphines, suggesting that the OAT reaction in these five-coordinate complexes appears to be governed by isomerization of the starting complex.
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