Works (2)
Updated: July 5th, 2023 15:49
2009 journal article
Synthesis of Oxorhenium(V) Complexes with Diamido Amine Ancillary Ligands and Their Role in Oxygen Atom Transfer Catalysis
INORGANIC CHEMISTRY, 48(23), 11058–11066.
MeSH headings : Amines / chemistry; Catalysis; Crystallography, X-Ray; Ligands; Models, Molecular; Molecular Structure; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Oxygen / chemistry; Rhenium / chemistry; Stereoisomerism
TL;DR:
Although the Re(VII) intermediate could not be isolated, its activity in OAT reactions was probed by competition experiments with PPh(3) and four para-substituted triarylphosphines, suggesting that the OAT reaction in these five-coordinate complexes appears to be governed by isomerization of the starting complex.
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UN Sustainable Development Goal Categories
7. Affordable and Clean Energy
(Web of Science)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018
2007 journal article
Instabilities in droplets spreading on gels
Physical Review Letters, 99, 123501.
Source: NC State University Libraries
Added: August 6, 2018
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