Raymond Unocic

Boebinger, M. G., Yilmaz, D. E., Ghosh, A., Misra, S., Mathis, T. S., Kalinin, S. V., … Unocic, R. R. (2024). Direct Fabrication of Atomically Defined Pores in MXenes Using Feedback‐Driven STEM. Small Methods, 5. https://doi.org/10.1002/smtd.202400203

Yang, Y., Yuwono, J. A., Whittaker, T., Ibáñez, M. M., Wang, B., Kim, C., … Bedford, N. M. (2024). Double Hydroxide Nanocatalysts for Urea Electrooxidation Engineered toward Environmentally Benign Products. Advanced Materials, 7. https://doi.org/10.1002/adma.202403187

Wittman, R. M., Sacci, R. L., Unocic, R. R., & Zawodzinski, T. A. (2024). In Situ Liquid Electron Microscope Cells Strongly Attenuate Electrochemical Behavior. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 171(12). https://doi.org/10.1149/1945-7111/ad963a

Liang, K., Wu, T., Misra, S., Dun, C., Husmann, S., Prenger, K., … Naguib, M. (2024). Nitrogen‐Doped Graphene‐Like Carbon Intercalated MXene Heterostructure Electrodes for Enhanced Sodium‐ and Lithium‐Ion Storage. Advanced Science, 6. https://doi.org/10.1002/advs.202402708

Lasseter, J., Gellerup, S., Ghosh, S., Yun, S. J., Vasudevan, R., Unocic, R. R., … Rack, P. D. (2024). Selected Area Manipulation of MoS<sub>2</sub> via Focused Electron Beam-Induced Etching for Nanoscale Device Editing. ACS Applied Materials & Interfaces, 16(7), 9144–9154. https://doi.org/10.1021/acsami.3c17182

Smeaton, M. A., Abellan, P., Spurgeon, S. R., Unocic, R. R., & Jungjohann, K. L. (2024). Tutorial on In Situ and Operando (Scanning) Transmission Electron Microscopy for Analysis of Nanoscale Structure–Property Relationships. ACS Nano. https://doi.org/10.1021/acsnano.4c09256

Harutyunyan, A., Li, X., Wyss, S., Yanev, E., Li, Q.-J., Wu, S., … Schuck, P. J. (2024, May 23). Width-Dependent Growth of Atomically Thin Quantum Nanoribbons. https://doi.org/10.21203/rs.3.rs-4419911/v1

Li, X., Wyss, S., Yanev, E., Li, Q.-J., Wu, S., Sun, Y., … Harutyunyan, A. R. (2024). Width-dependent continuous growth of atomically thin quantum nanoribbons from nanoalloy seeds in chalcogen vapor. NATURE COMMUNICATIONS, 15(1). https://doi.org/10.1038/s41467-024-54413-9

Vlassiouk, I., Smirnov, S., Puretzky, A., Olunloyo, O., Geohegan, D. B., Dyck, O., … Ivanov, I. (2023). Armor for Steel: Facile Synthesis of Hexagonal Boron Nitride Films on Various Substrates. Advanced Materials Interfaces, 11(1). https://doi.org/10.1002/admi.202300704

Weber, J., Starchenko, V., Yuan, K., Anovitz, L. M., Ievlev, A. V., Unocic, R. R., … Stack, A. G. (2023). Armoring of MgO by a Passivation Layer Impedes Direct Air Capture of CO<sub>2. Environmental Science & Technology, 57(40), 14929–14937. https://doi.org/10.1021/acs.est.3c04690

Thompson, C. B., Liu, L., Leshchev, D. S., Hoffman, A. S., Hong, J., Bare, S. R., … Karim, A. M. (2023). CO Oxidation on Ir<sub>1</sub>/TiO<sub>2</sub>: Resolving Ligand Dynamics and Elementary Reaction Steps. ACS Catalysis, 13(12), 7802–7811. https://doi.org/10.1021/acscatal.3c01433

Yang, Y., Lie, W. H., Unocic, R. R., Yuwono, J. A., Klingenhof, M., Merzdorf, T., … Bedford, N. M. (2023). Defect‐Promoted Ni‐Based Layer Double Hydroxides with Enhanced Deprotonation Capability for Efficient Biomass Electrooxidation. Advanced Materials, 35(48). https://doi.org/10.1002/adma.202305573

Unocic, R. R., & Stach, E. A. (2023). Gas-phase electron microscopy for materials research. MRS Bulletin, 48(8), 828–832. https://doi.org/10.1557/s43577-023-00588-3

Ghimire, G., Ulaganathan, R. K., Tempez, A., Ilchenko, O., Unocic, R. R., Heske, J., … Canulescu, S. (2023). Molybdenum Disulfide Nanoribbons with Enhanced Edge Nonlinear Response and Photoresponsivity. Advanced Materials, 35(31). https://doi.org/10.1002/adma.202302469

Sutter, E., Kisslinger, K., Unocic, R. R., Burns, K., Hachtel, J., & Sutter, P. (2024). Photonics in Multimaterial Lateral Heterostructures Combining Group IV Chalcogenide van der Waals Semiconductors. Small, 20(20), 2307372. https://doi.org/10.1002/smll.202307372

Calì, E., Thomas, M. P., Vasudevan, R., Wu, J., Gavalda-Diaz, O., Marquardt, K., … Payne, D. J. (2023). Real-time insight into the multistage mechanism of nanoparticle exsolution from a perovskite host surface. Nature Communications, 14(1). https://doi.org/10.1038/s41467-023-37212-6

Subhash, B., Unocic, R. R., Lie, W. H., Gallington, L. C., Wright, J., Cheong, S., … Bedford, N. M. (2023). Resolving Atomic-Scale Structure and Chemical Coordination in High-Entropy Alloy Electrocatalysts for Structure–Function Relationship Elucidation. ACS Nano, 17(22), 22299–22312. https://doi.org/10.1021/acsnano.3c03884

Albrahim, M. A., Shrotri, A., Unocic, R. R., Hoffman, A. S., Bare, S. R., & Karim, A. M. (2023). Size‐Dependent Dispersion of Rhodium Clusters into Isolated Single Atoms at Low Temperature and the Consequences for CO Oxidation Activity. Angewandte Chemie International Edition, 62(44). https://doi.org/10.1002/anie.202308002

Boebinger, M. G., Brea, C., Ding, L. P., Misra, S., Olunloyo, O., Yu, Y., … Unocic, R. R. (2023). The Atomic Drill Bit: Precision Controlled Atomic Fabrication of 2D Materials. Advanced Materials, 35(14). https://doi.org/10.1002/adma.202210116

Sutter, P., Unocic, R. R., & Sutter, E. (2023). Tuning of Single Mixed (Helical) Dislocations in Core–Shell van der Waals Nanowires. Journal of the American Chemical Society, 145(37), 20503–20510. https://doi.org/10.1021/jacs.3c06469

Jaiswal, S., Fathi-Hafshejani, P., Yakupoglu, B., Boebinger, M. G., Azam, N., Unocic, R. R., … Mahjouri-Samani, M. (2023). Wafer-Scale Synthesis of 2D Materials by an Amorphous Phase-Mediated Crystallization Approach. ACS Applied Materials & Interfaces, 15(33), 39697–39706. https://doi.org/10.1021/acsami.3c06009

Miakota, D. I., Unocic, R. R., Bertoldo, F., Ghimire, G., Engberg, S., Geohegan, D., … Canulescu, S. (2022). A facile strategy for the growth of high-quality tungsten disulfide crystals mediated by oxygen-deficient oxide precursors. Nanoscale, 14(26), 9485–9497. https://doi.org/10.1039/D2NR01863B

Fadaeerayeni, S., Yu, X., Sarnello, E., Bao, Z., Jiang, X., Unocic, R. R., … Xiang, Y. (2022). Ammonia-Assisted Light Alkane Anti-coke Reforming on Isolated ReO<sub><i>x</i></sub> Sites in Zeolite. ACS Catalysis, 12(5), 3165–3172. https://doi.org/10.1021/acscatal.2c00230

Hattar, K., & Unocic, R. R. (2022). Applications of Liquid Cell-TEM in Corrosion Research. https://doi.org/10.1007/978-3-030-89101-5_6

Zhou, D., Fuentes-Cabrera, M., Singh, A., Unocic, R. R., Carrillo, J. M. Y., Xiao, K., … Li, B. (2022). Atomic Edge-Guided Polyethylene Crystallization on Monolayer Two-Dimensional Materials. Macromolecules, 55(2), 559–567. https://doi.org/10.1021/acs.macromol.1c01978

Ahmadi, Z., Lee, S., Patel, A., Unocic, R. R., Shamsaei, N., & Mahjouri‐Samani, M. (2022). Dry Printing and Additive Nanomanufacturing of Flexible Hybrid Electronics and Sensors. Advanced Materials Interfaces, 9(12). https://doi.org/10.1002/admi.202102569

Thapaliya, B. P., Misra, S., Yang, S., Jafta, C. J., Meyer, H. M., III, Bagri, P., … Dai, S. (2022). Enhancing Cycling Stability and Capacity Retention of NMC811 Cathodes by Reengineering Interfaces via Electrochemical Fluorination. Advanced Materials Interfaces, 9(18). https://doi.org/10.1002/admi.202200035

Jorgensen, C. S., Santodonato, L. J., Littrell, K. C., Kuo, C. H., Lee, C., Unocic, R. R., … DeBeer-Schmitt, L. M. (2022). In-Situ Study of Microstructure Evolution of Spinodal Decomposition in an Al-Rich High-Entropy Alloy. Frontiers in Materials, 9. https://doi.org/10.3389/fmats.2022.827333

Azam, N., Boebinger, M. G., Jaiswal, S., Unocic, R. R., Fathi-Hafshejani, P., & Mahjouri-Samani, M. (2022). Laser-Assisted Synthesis of Monolayer 2D MoSe<sub>2</sub> Crystals with Tunable Vacancy Concentrations: Implications for Gas and Biosensing. ACS Applied Nano Materials, 5(7), 9129–9139. https://doi.org/10.1021/acsanm.2c01458

Whitcomb, C. A., Sviripa, A., Schapowal, M. I., Mamedov, K., Unocic, R. R., Paolucci, C., & Davis, R. J. (2022). Mechanistic Insights on the Low-Temperature Oxidation of CO Catalyzed by Isolated Co Ions in N-Doped Carbon. ACS Catalysis, 12(24), 15529–15540. https://doi.org/10.1021/acscatal.2c04380

Roccapriore, K. M., Boebinger, M. G., Dyck, O., Ghosh, A., Unocic, R. R., Kalinin, S. V., & Ziatdinov, M. (2022). Probing Electron Beam Induced Transformations on a Single-Defect Level via Automated Scanning Transmission Electron Microscopy. ACS Nano, 16(10), 17116–17127. https://doi.org/10.1021/acsnano.2c07451

Subhash, B., Unocic, R., Gallington, L., Wright, J., Cheong, S., Tilley, R., & Bedford, N. (2022, November 1). Resolving Atomic-Scale Structure and Chemical Coordination in High Entropy Alloy Electrocatalysts for Structure-Function Relationship Elucidation. https://doi.org/10.21203/rs.3.rs-2155469/v1

Sutter, E., Komsa, H.-P., Puretzky, A. A., Unocic, R. R., & Sutter, P. (2022). Stacking Fault Induced Symmetry Breaking in van der Waals Nanowires. ACS Nano, 16(12), 21199–21207. https://doi.org/10.1021/acsnano.2c09172

Sharma, N. K., Kannan, R., Li, L., Anderson, N., Rashid, M., Collins, L., … Unocic, R. (2021). A Mechanism for Carbon Depletion at Bondline of High-Frequency Electric-Resistance-Welded X70 Pipeline Steel. Metallurgical and Materials Transactions A, 52(9), 3788–3798. https://doi.org/10.1007/s11661-021-06339-w

Ahmadi, Z., Lee, S., Unocic, R. R., Shamsaei, N., & Mahjouri‐Samani, M. (2021). Additive Nanomanufacturing of Multifunctional Materials and Patterned Structures: A Novel Laser‐Based Dry Printing Process. Advanced Materials Technologies, 6(5). https://doi.org/10.1002/admt.202001260

Vogt, C., Meirer, F., Monai, M., Groeneveld, E., Ferri, D., van Santen, R. A., … Weckhuysen, B. M. (2021). Dynamic restructuring of supported metal nanoparticles and its implications for structure insensitive catalysis. Nature Communications, 12(1). https://doi.org/10.1038/s41467-021-27474-3

Rimal, G., Schmidt, C., Hijazi, H., Feldman, L. C., Liu, Y., Skoropata, E., … Oh, S. (2021). Effective reduction of 
<mml:msub><mml:mi>PdCoO
 thin films via hydrogenation and sign tunable anomalous Hall effect. Physical Review Materials, 5(5). https://doi.org/10.1103/physrevmaterials.5.l052001

Liang, K., Matsumoto, R. A., Zhao, W., Osti, N. C., Popov, I., Thapaliya, B. P., … Naguib, M. (2021). Engineering the Interlayer Spacing by Pre‐Intercalation for High Performance Supercapacitor MXene Electrodes in Room Temperature Ionic Liquid. Advanced Functional Materials, 31(33). https://doi.org/10.1002/adfm.202104007

Liu, X., Li, B., Soto, F. A., Li, X., Unocic, R. R., Balbuena, P. B., … Esposito, D. V. (2021). Enhancing Hydrogen Evolution Activity of Monolayer Molybdenum Disulfide via a Molecular Proton Mediator. ACS Catalysis, 11(19), 12159–12169. https://doi.org/10.1021/acscatal.1c03016

Bertoldo, F., Unocic, R. R., Lin, Y.-C., Sang, X., Puretzky, A. A., Yu, Y., … Canulescu, S. (2021). Intrinsic Defects in MoS<sub>2</sub> Grown by Pulsed Laser Deposition: From Monolayers to Bilayers. ACS Nano, 15(2), 2858–2868. https://doi.org/10.1021/acsnano.0c08835

Sutter, E., Unocic, R. R., Idrobo, J. C., & Sutter, P. (2021). Multilayer Lateral Heterostructures of Van Der Waals Crystals with Sharp, Carrier–Transparent Interfaces. Advanced Science, 9(3). https://doi.org/10.1002/advs.202103830

Cochell, T. J., Unocic, R. R., Graña-Otero, J., & Martin, A. (2021). Nanoscale oxidation behavior of carbon fibers revealed with in situ gas cell STEM. Scripta Materialia, 199, 113820. https://doi.org/10.1016/j.scriptamat.2021.113820

Li, X., Li, B., Lei, J., Bets, K. V., Sang, X., Okogbue, E., … Harutyunyan, A. R. (2021). Nickel particle–enabled width-controlled growth of bilayer molybdenum disulfide nanoribbons. Science Advances, 7(50). https://doi.org/10.1126/sciadv.abk1892

Unocic, K. A., Hensley, D. K., Walden, F. S., Bigelow, W. C., Griffin, M. B., Habas, S. E., … Allard, L. F. (2021). Performing <em>In Situ</em> Closed-Cell Gas Reactions in the Transmission Electron Microscope. Journal of Visualized Experiments, 7(173). https://doi.org/10.3791/62174-v

Albrahim, M., Thompson, C., Leshchev, D., Shrotri, A., Unocic, R. R., Hong, J., … Karim, A. M. (2021). Reduction and Agglomeration of Supported Metal Clusters Induced by High-Flux X-ray Absorption Spectroscopy Measurements. The Journal of Physical Chemistry C, 125(20), 11048–11057. https://doi.org/10.1021/acs.jpcc.1c01823

Wang, K., Zhang, L., Nguyen, G. D., Sang, X., Liu, C., Yu, Y., … Xiao, K. (2021). Selective Antisite Defect Formation in WS<sub>2</sub> Monolayers via Reactive Growth on Dilute W‐Au Alloy Substrates. Advanced Materials, 34(3). https://doi.org/10.1002/adma.202106674

Chen, L., Unocic, R. R., Hoffman, A. S., Hong, J., Braga, A. H., Bao, Z., … Szanyi, J. (2021). Unlocking the Catalytic Potential of TiO<sub>2</sub>-Supported Pt Single Atoms for the Reverse Water–Gas Shift Reaction by Altering Their Chemical Environment. JACS Au, 1(7), 977–986. https://doi.org/10.1021/jacsau.1c00111

Cui, W., Hu, Z.-Y., Unocic, R. R., Van Tendeloo, G., & Sang, X. (2021). Atomic defects, functional groups and properties in MXenes. Chinese Chemical Letters, 32(1), 339–344. https://doi.org/10.1016/j.cclet.2020.04.024

Dyck, O., Ziatdinov, M., Lingerfelt, D. B., Unocic, R. R., Hudak, B. M., Lupini, A. R., … Kalinin, S. V. (2020). Author Correction: Atom-by-atom fabrication with electron beams. Nature Reviews Materials. https://doi.org/10.1038/s41578-020-0188-y

Guo, W., Mahurin, S. M., Unocic, R. R., Luo, H., & Dai, S. (2020). Broadening the Gas Separation Utility of Monolayer Nanoporous Graphene Membranes by an Ionic Liquid Gating. Nano Letters, 20(11), 7995–8000. https://doi.org/10.1021/acs.nanolett.0c02860

Misra, S., Aguiar, J. A., Gardner, S., Sang, X., Unocic, R. R., Munshi, A., … Scarpulla, M. A. (2020). Cadmium Selective Etching in CdTe Solar Cells Produces Detrimental Narrow-Gap Te in Grain Boundaries. ACS Applied Energy Materials, 3(2), 1749–1758. https://doi.org/10.1021/acsaem.9b02224

Gamler, J. T. L., Leonardi, A., Sang, X., Koczkur, K. M., Unocic, R. R., Engel, M., & Skrabalak, S. E. (2020). Effect of lattice mismatch and shell thickness on strain in core@shell nanocrystals. Nanoscale Advances, 2(3), 1105–1114. https://doi.org/10.1039/D0NA00061B

Zhou, D., Lang, J., Yoo, N., Unocic, R. R., Wu, Q., & Li, B. (2020). Fluid-Guided CVD Growth for Large-Scale Monolayer Two-Dimensional Materials. ACS Applied Materials & Interfaces, 12(23), 26342–26349. https://doi.org/10.1021/acsami.0c04125

Hernández-Escobar, D., Unocic, R. R., Kawasaki, M., & Boehlert, C. J. (2020). High-pressure torsion processing of Zn–3Mg alloy and its hybrid counterpart: A comparative study. Journal of Alloys and Compounds, 831, 154891. https://doi.org/10.1016/j.jallcom.2020.154891

Unocic, R. R., Jungjohann, K. L., Mehdi, B. L., Browning, N. D., & Wang, C. (2020). In situ</i> electrochemical scanning/transmission electron microscopy of electrode–electrolyte interfaces. MRS Bulletin, 45(9), 738–745. https://doi.org/10.1557/mrs.2020.226

Mukherjee, D., Gamler, J. T. L., Skrabalak, S. E., & Unocic, R. R. (2020). Lattice Strain Measurement of Core@Shell Electrocatalysts with 4D Scanning Transmission Electron Microscopy Nanobeam Electron Diffraction. ACS Catalysis, 10(10), 5529–5541. https://doi.org/10.1021/acscatal.0c00224

Zhu, Y., Poplawsky, J. D., Li, S., Unocic, R. R., Bland, L. G., Taylor, C. D., … Frankel, G. S. (2020). Localized corrosion at nm-scale hardening precipitates in Al-Cu-Li alloys. Acta Materialia, 189, 204–213. https://doi.org/10.1016/j.actamat.2020.03.006

Hu, G., Fung, V., Sang, X., Unocic, R. R., & Ganesh, P. (2020). Predicting synthesizable multi-functional edge reconstructions in two-dimensional transition metal dichalcogenides. Npj Computational Materials, 6(1). https://doi.org/10.1038/s41524-020-0327-4

Jiang, B., Bridges, C. A., Unocic, R. R., Pitike, K. C., Cooper, V. R., Zhang, Y., … Page, K. (2020). Probing the Local Site Disorder and Distortion in Pyrochlore High-Entropy Oxides. Journal of the American Chemical Society, 143(11), 4193–4204. https://doi.org/10.1021/jacs.0c10739

Zhou, X., Chen, L., Sterbinsky, G. E., Mukherjee, D., Unocic, R. R., & Tait, S. L. (2020). Pt-Ligand single-atom catalysts: tuning activity by oxide support defect density. Catalysis Science & Technology, 10(10), 3353–3365. https://doi.org/10.1039/C9CY02594D

Boebinger, M. G., Yarema, O., Yarema, M., Unocic, K. A., Unocic, R. R., Wood, V., & McDowell, M. T. (2020). Spontaneous and reversible hollowing of alloy anode nanocrystals for stable battery cycling. Nature Nanotechnology, 15(6), 475–481. https://doi.org/10.1038/s41565-020-0690-9

Li, X., Dyck, O., Unocic, R. R., Ievlev, A. V., Jesse, S., & Kalinin, S. V. (2020). Statistical learning of governing equations of dynamics from in-situ electron microscopy imaging data. Materials & Design, 195, 108973. https://doi.org/10.1016/j.matdes.2020.108973

Li, X., Kahn, E., Chen, G., Sang, X., Lei, J., Passarello, D., … Harutyunyan, A. R. (2020). Surfactant-Mediated Growth and Patterning of Atomically Thin Transition Metal Dichalcogenides. ACS Nano, 14(6), 6570–6581. https://doi.org/10.1021/acsnano.0c00132

Gamler, J. T. L., Leonardi, A., Ashberry, H. M., Daanen, N. N., Losovyj, Y., Unocic, R. R., … Skrabalak, S. E. (2019). Achieving Highly Durable Random Alloy Nanocatalysts through Intermetallic Cores. ACS Nano, 13(4), 4008–4017. https://doi.org/10.1021/acsnano.8b08007

Dyck, O., Ziatdinov, M., Lingerfelt, D. B., Unocic, R. R., Hudak, B. M., Lupini, A. R., … Kalinin, S. V. (2019). Atom-by-atom fabrication with electron beams. Nature Reviews Materials, 4(7), 497–507. https://doi.org/10.1038/s41578-019-0118-z

Sang, X., Li, X., Puretzky, A. A., Geohegan, D. B., Xiao, K., & Unocic, R. R. (2019). Atomic Insight into Thermolysis‐Driven Growth of 2D MoS<sub>2. Advanced Functional Materials, 29(52). https://doi.org/10.1002/adfm.201902149

Gamler, J. T. L., Ashberry, H. M., Sang, X., Unocic, R. R., & Skrabalak, S. E. (2019). Building Random Alloy Surfaces from Intermetallic Seeds: A General Route to Strain-Engineered Electrocatalysts with High Durability. ACS Applied Nano Materials, 2(7), 4538–4546. https://doi.org/10.1021/acsanm.9b00901

Stricker, E. A., Ke, X., Wainright, J. S., Unocic, R. R., & Savinell, R. F. (2019). Current Density Distribution in Electrochemical Cells with Small Cell Heights and Coplanar Thin Electrodes as Used in ec-S/TEM Cell Geometries. Journal of The Electrochemical Society, 166(4), H126–H134. https://doi.org/10.1149/2.0211904jes

Aguiar, J. A., Gong, M. L., Unocic, R. R., Tasdizen, T., & Miller, B. D. (2019). Decoding crystallography from high-resolution electron imaging and diffraction datasets with deep learning. Science Advances, 5(10). https://doi.org/10.1126/sciadv.aaw1949

Oyedele, A. D., Yang, S., Feng, T., Haglund, A. V., Gu, Y., Puretzky, A. A., … Xiao, K. (2019). Defect-Mediated Phase Transformation in Anisotropic Two-Dimensional PdSe<sub>2</sub> Crystals for Seamless Electrical Contacts. Journal of the American Chemical Society, 141(22), 8928–8936. https://doi.org/10.1021/jacs.9b02593

Ashberry, H. M., Gamler, J. T. L., Unocic, R. R., & Skrabalak, S. E. (2019). Disorder-to-Order Transition Mediated by Size Refocusing: A Route toward Monodisperse Intermetallic Nanoparticles. Nano Letters, 19(9), 6418–6423. https://doi.org/10.1021/acs.nanolett.9b02610

Sang, X., Naguib, M., Alhabeb, M., & Unocic, R. R. (2019). Effect of Synthesis Methods on the Structure and Defects of Two-Dimensional MXenes. In 2D Metal Carbides and Nitrides (MXenes) (pp. 111–123). https://doi.org/10.1007/978-3-030-19026-2_7

Hernández-Escobar, D., Marcus, J., Han, J.-K., Unocic, R. R., Kawasaki, M., & Boehlert, C. J. (2020). Effect of post-deformation annealing on the microstructure and micro-mechanical behavior of Zn–Mg hybrids processed by High-Pressure Torsion. Materials Science and Engineering: A, 771, 138578. https://doi.org/10.1016/j.msea.2019.138578

Brahlek, M., Rimal, G., Ok, J. M., Mukherjee, D., Mazza, A. R., Lu, Q., … Oh, S. (2019). Growth of metallic delafossite 
<mml:mrow><mml:mi>PdCo
 by molecular beam epitaxy. Physical Review Materials, 3(9). https://doi.org/10.1103/physrevmaterials.3.093401

Gutiérrez-Kolar, J. S., Baggetto, L., Sang, X., Shin, D., Yurkiv, V., Mashayek, F., … Unocic, R. R. (2019). Interpreting Electrochemical and Chemical Sodiation Mechanisms and Kinetics in Tin Antimony Battery Anodes Using <i>in Situ</i> Transmission Electron Microscopy and Computational Methods. ACS Applied Energy Materials, 2(5), 3578–3586. https://doi.org/10.1021/acsaem.9b00310

Key, J. W., Zhu, S., Rouleau, C. M., Unocic, R. R., Xie, Y., & Kacher, J. (2020). Investigating local oxidation processes in Fe thin films in a water vapor environment by in situ liquid cell TEM. Ultramicroscopy, 209, 112842. https://doi.org/10.1016/j.ultramic.2019.112842

Li, X., Zhang, J., Puretzky, A. A., Yoshimura, A., Sang, X., Cui, Q., … Xiao, K. (2019). Isotope-Engineering the Thermal Conductivity of Two-Dimensional MoS<sub>2. ACS Nano, 1. https://doi.org/10.1021/acsnano.8b09448

Chen, H., Lin, W., Zhang, Z., Jie, K., Mullins, D. R., Sang, X., … Dai, S. (2019). Mechanochemical Synthesis of High Entropy Oxide Materials under Ambient Conditions: Dispersion of Catalysts via Entropy Maximization. ACS Materials Letters, 1(1), 83–88. https://doi.org/10.1021/acsmaterialslett.9b00064

Zeng, M., Chen, Y., Zhang, E., Li, J., Mendes, R. G., Sang, X., … Fu, L. (2019). Molecular Scaffold Growth of Two-Dimensional, Strong Interlayer-Bonding-Layered Materials. CCS Chemistry, 1(1), 117–127. https://doi.org/10.31635/ccschem.019.20180003

Nandi, P., Sang, X., Hoglund, E. R., Unocic, R. R., Molodov, D. A., & Howe, J. M. (2019). Nanoscale mapping of the electron density at Al grain boundaries and correlation with grain-boundary energy. Physical Review Materials, 3(5). https://doi.org/10.1103/physrevmaterials.3.053805

Hu, G., Fung, V., Sang, X., Unocic, R. R., & Ganesh, P. (2019). Superior electrocatalytic hydrogen evolution at engineered non-stoichiometric two-dimensional transition metal dichalcogenide edges. Journal of Materials Chemistry A, 7(31), 18357–18364. https://doi.org/10.1039/C9TA05546K

Phillip, N. D., Ruther, R. E., Sang, X., Wang, Y., Unocic, R. R., Westover, A. S., … Veith, G. M. (2019). Synthesis of Ni-Rich Thin-Film Cathode as Model System for Lithium Ion Batteries. ACS Applied Energy Materials, 2(2), 1405–1412. https://doi.org/10.1021/acsaem.8b01982

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Sang, X., Xie, Y., Yilmaz, D. E., Lotfi, R., Alhabeb, M., Ostadhossein, A., … Unocic, R. R. (2018). In situ atomistic insight into the growth mechanisms of single layer 2D transition metal carbides. Nature Communications, 9(1). https://doi.org/10.1038/s41467-018-04610-0

Sang, X., Li, X., Zhao, W., Dong, J., Rouleau, C. M., Geohegan, D. B., … Unocic, R. R. (2018). In situ edge engineering in two-dimensional transition metal dichalcogenides. Nature Communications, 9(1). https://doi.org/10.1038/s41467-018-04435-x

Ding, J., Balachandran, J., Sang, X., Guo, W., Veith, G. M., Bridges, C. A., … Unocic, R. R. (2018). Influence of Nonstoichiometry on Proton Conductivity in Thin-Film Yttrium-Doped Barium Zirconate. ACS Applied Materials & Interfaces, 10(5), 4816–4823. https://doi.org/10.1021/acsami.7b16900

Jin, T., Sang, X., Unocic, R. R., Kinch, R. T., Liu, X., Hu, J., … Dai, S. (2018). Mechanochemical‐Assisted Synthesis of High‐Entropy Metal Nitride via a Soft Urea Strategy. Advanced Materials, 30(23). https://doi.org/10.1002/adma.201707512

Kim, S., Ievlev, A. V., Jakowski, J., Vlassiouk, I. V., Sang, X., Brown, C., … Ovchinnikova, O. S. (2018). Multi-purposed Ar gas cluster ion beam processing for graphene engineering. Carbon, 131, 142–148. https://doi.org/10.1016/j.carbon.2018.01.098

Santodonato, L. J., Liaw, P. K., Unocic, R. R., Bei, H., & Morris, J. R. (2018). Predictive multiphase evolution in Al-containing high-entropy alloys. Nature Communications, 9(1). https://doi.org/10.1038/s41467-018-06757-2

Kammert, J. D., Xie, J., Godfrey, I. J., Unocic, R. R., Stavitski, E., Attenkofer, K., … Davis, R. J. (2018). Reduction of Propionic Acid over a Pd-Promoted ReO<sub><i>x</i></sub>/SiO<sub>2</sub> Catalyst Probed by X-ray Absorption Spectroscopy and Transient Kinetic Analysis. ACS Sustainable Chemistry & Engineering, 6(9), 12353–12366. https://doi.org/10.1021/acssuschemeng.8b02820

Idrobo, J. C., Lupini, A. R., Feng, T., Unocic, R. R., Walden, F. S., Gardiner, D. S., … Krivanek, O. L. (2018). Temperature Measurement by a Nanoscale Electron Probe Using Energy Gain and Loss Spectroscopy. Physical Review Letters, 120(9). https://doi.org/10.1103/physrevlett.120.095901

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Lewis, B. B., Winkler, R., Sang, X., Pudasaini, P. R., Stanford, M. G., Plank, H., … Rack, P. D. (2017). 3D Nanoprinting via laser-assisted electron beam induced deposition: growth kinetics, enhanced purity, and electrical resistivity. Beilstein Journal of Nanotechnology, 8, 801–812. https://doi.org/10.3762/bjnano.8.83

Han, C. W., Choksi, T., Milligan, C., Majumdar, P., Manto, M., Cui, Y., … Ortalan, V. (2017). A Discovery of Strong Metal–Support Bonding in Nanoengineered Au–Fe<sub>3</sub>O<sub>4</sub> Dumbbell-like Nanoparticles by in Situ Transmission Electron Microscopy. Nano Letters, 17(8), 4576–4582. https://doi.org/10.1021/acs.nanolett.7b00827

Thompson, M., Dyatkin, B., Wang, H.-W., Turner, C., Sang, X., Unocic, R., … Cummings, P. (2017). An Atomistic Carbide-Derived Carbon Model Generated Using ReaxFF-Based Quenched Molecular Dynamics. C, 3(4), 32. https://doi.org/10.3390/c3040032

Stehle, Y. Y., Sang, X., Unocic, R. R., Voylov, D., Jackson, R. K., Smirnov, S., & Vlassiouk, I. (2017). Anisotropic Etching of Hexagonal Boron Nitride and Graphene: Question of Edge Terminations. Nano Letters, 17(12), 7306–7314. https://doi.org/10.1021/acs.nanolett.7b02841

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Yurkiv, V., Gutiérrez-Kolar, J. S., Unocic, R. R., Ramsubramanian, A., Shahbazian-Yassar, R., & Mashayek, F. (2017). Competitive Ion Diffusion within Grain Boundary and Grain Interiors in Polycrystalline Electrodes with the Inclusion of Stress Field. Journal of The Electrochemical Society, 164(12), A2830–A2839. https://doi.org/10.1149/2.0121713jes

Xu, D., Chen, W., Zeng, M., Xue, H., Chen, Y., Sang, X., … Fu, L. (2017). Crystal‐Field Tuning of Photoluminescence in Two‐Dimensional Materials with Embedded Lanthanide Ions. Angewandte Chemie, 130(3), 763–767. https://doi.org/10.1002/ange.201711071

Ziatdinov, M., Dyck, O., Maksov, A., Li, X., Sang, X., Xiao, K., … Kalinin, S. V. (2017). Deep Learning of Atomically Resolved Scanning Transmission Electron Microscopy Images: Chemical Identification and Tracking Local Transformations. ACS Nano, 11(12), 12742–12752. https://doi.org/10.1021/acsnano.7b07504

Zhao, Y., Liu, D., Chen, J., Zhu, L., Belianinov, A., Ovchinnikova, O. S., … Thong, J. T. L. (2017). Engineering the thermal conductivity along an individual silicon nanowire by selective helium ion irradiation. Nature Communications, 8(1). https://doi.org/10.1038/ncomms15919

Yang, B., Brown, C. C., Huang, J., Collins, L., Sang, X., Unocic, R. R., … Ovchinnikova, O. S. (2017). Enhancing Ion Migration in Grain Boundaries of Hybrid Organic–Inorganic Perovskites by Chlorine. Advanced Functional Materials, 27(26). https://doi.org/10.1002/adfm.201700749

Wang, C., Sang, X., Gamler, J. T. L., Chen, D. P., Unocic, R. R., & Skrabalak, S. E. (2017). Facet-Dependent Deposition of Highly Strained Alloyed Shells on Intermetallic Nanoparticles for Enhanced Electrocatalysis. Nano Letters, 17(9), 5526–5532. https://doi.org/10.1021/acs.nanolett.7b02239

Canepa, S. A., Sneed, B. T., Sun, H., Unocic, R. R., & Mølhave, K. (2018). Influence of Cetyltrimethylammonium Bromide on Gold Nanocrystal Formation Studied by In Situ Liquid Cell Scanning Transmission Electron Microscopy. The Journal of Physical Chemistry C, 122(4), 2350–2357. https://doi.org/10.1021/acs.jpcc.7b06383

Muckley, E. S., Naguib, M., Wang, H.-W., Vlcek, L., Osti, N. C., Sacci, R. L., … Ivanov, I. N. (2017). Multimodality of Structural, Electrical, and Gravimetric Responses of Intercalated MXenes to Water. ACS Nano, 11(11), 11118–11126. https://doi.org/10.1021/acsnano.7b05264

Unocic, K. A., Shin, D., Unocic, R. R., & Allard, L. F. (2017). NiAl Oxidation Reaction Processes Studied In Situ Using MEMS-Based Closed-Cell Gas Reaction Transmission Electron Microscopy. Oxidation of Metals, 88(3-4), 495–508. https://doi.org/10.1007/s11085-016-9676-2

Sang, X., Lupini, A. R., Ding, J., Kalinin, S. V., Jesse, S., & Unocic, R. R. (2017). Precision controlled atomic resolution scanning transmission electron microscopy using spiral scan pathways. Scientific Reports, 7(1). https://doi.org/10.1038/srep43585

Jarvis, K., Wang, C.-C., Varela, M., Unocic, R. R., Manthiram, A., & Ferreira, P. J. (2017). Surface Reconstruction in Li-Rich Layered Oxides of Li-Ion Batteries. Chemistry of Materials, 29(18), 7668–7674. https://doi.org/10.1021/acs.chemmater.7b00120

Li, Y., Wan, S., Veith, G. M., Unocic, R. R., Paranthaman, M. P., Dai, S., & Sun, X. G. (2017). A Novel Electrolyte Salt Additive for Lithium‐Ion Batteries with Voltages Greater than 4.7 V. Advanced Energy Materials, 7(4). https://doi.org/10.1002/aenm.201601397

Unocic, R. R., & More, K. L. (2016). Application of Electrochemical Liquid Cells for Electrical Energy Storage and Conversion Studies. https://doi.org/10.1017/9781316337455.012

Sang, X., Xie, Y., Lin, M.-W., Alhabeb, M., Van Aken, K. L., Gogotsi, Y., … Unocic, R. R. (2016). Atomic Defects in Monolayer Titanium Carbide (Ti<sub>3</sub>C<sub>2</sub>T<sub><i>x</i></sub>) MXene. ACS Nano, 10(10), 9193–9200. https://doi.org/10.1021/acsnano.6b05240

Yoon, K., Rahnamoun, A., Swett, J. L., Iberi, V., Cullen, D. A., Vlassiouk, I. V., … van Duin, A. C. T. (2016). Atomistic-Scale Simulations of Defect Formation in Graphene under Noble Gas Ion Irradiation. ACS Nano, 10(9), 8376–8384. https://doi.org/10.1021/acsnano.6b03036

Smith, T. M., Unocic, R. R., Deutchman, H., & Mills, M. J. (2016). Creep deformation mechanism mapping in nickel base disk superalloys. Materials at High Temperatures, 33(4-5), 372–383. https://doi.org/10.1080/09603409.2016.1180858

Unocic, R. R., Lupini, A. R., Borisevich, A. Y., Cullen, D. A., Kalinin, S. V., & Jesse, S. (2016). Direct-write liquid phase transformations with a scanning transmission electron microscope. Nanoscale, 8(34), 15581–15588. https://doi.org/10.1039/c6nr04994j

Jesse, S., Borisevich, A. Y., Fowlkes, J. D., Lupini, A. R., Rack, P. D., Unocic, R. R., … Ovchinnikova, O. S. (2016). Directing Matter: Toward Atomic-Scale 3D Nanofabrication. ACS Nano, 10(6), 5600–5618. https://doi.org/10.1021/acsnano.6b02489

Boebinger, M. G., Xu, M., Ma, X., Chen, H., Unocic, R. R., & McDowell, M. T. (2017). Distinct nanoscale reaction pathways in a sulfide material for sodium and lithium batteries. Journal of Materials Chemistry A, 5(23), 11701–11709. https://doi.org/10.1039/c6ta09195d

Sang, X., Lupini, A. R., Unocic, R. R., Chi, M., Borisevich, A. Y., Kalinin, S. V., … Jesse, S. (2016). Dynamic scan control in STEM: spiral scans. Advanced Structural and Chemical Imaging, 2(1). https://doi.org/10.1186/s40679-016-0020-3

Baturina, O., Lu, Q., Xu, F., Purdy, A., Dyatkin, B., Sang, X., … Gogotsi, Y. (2017). Effect of nanostructured carbon support on copper electrocatalytic activity toward CO2 electroreduction to hydrocarbon fuels. Catalysis Today, 288, 2–10. https://doi.org/10.1016/j.cattod.2016.11.001

Black, J. M., Zhu, M., Zhang, P., Unocic, R. R., Guo, D., Okatan, M. B., … Balke, N. (2016). Fundamental aspects of electric double layer force-distance measurements at liquid-solid interfaces using atomic force microscopy. Scientific Reports, 6(1). https://doi.org/10.1038/srep32389

Formo, E. V., Potterf, C. B., Yang, M., Unocic, R. R., Leonard, D. N., & Pawel, M. (2016). How a Nanostructure’s Shape Affects its Lifetime in the Environment: Comparing a Silver Nanocube to a Nanoparticle When Dispersed in Aqueous Media. Environmental Science & Technology, 50(13), 7082–7089. https://doi.org/10.1021/acs.est.6b01172

Economy, D. R., Mara, N. A., Schoeppner, R. L., Schultz, B. M., Unocic, R. R., & Kennedy, M. S. (2016). Identifying Deformation and Strain Hardening Behaviors of Nanoscale Metallic Multilayers Through Nano-wear Testing. Metallurgical and Materials Transactions A, 47(3), 1083–1095. https://doi.org/10.1007/s11661-015-3284-7

Weiner, R. G., Chen, D. P., Unocic, R. R., & Skrabalak, S. E. (2016). Impact of Membrane‐Induced Particle Immobilization on Seeded Growth Monitored by In Situ Liquid Scanning Transmission Electron Microscopy. Small, 12(20), 2701–2706. https://doi.org/10.1002/smll.201502974

Xie, J., Huang, B., Yin, K., Pham, H. N., Unocic, R. R., Datye, A. K., & Davis, R. J. (2016). Influence of Dioxygen on the Promotional Effect of Bi during Pt-Catalyzed Oxidation of 1,6-Hexanediol. ACS Catalysis, 6(7), 4206–4217. https://doi.org/10.1021/acscatal.6b00972

Rubio, M. A., Gunduz, I. E., Groven, L. J., Sippel, T. R., Han, C. W., Unocic, R. R., … Son, S. F. (2017). Microexplosions and ignition dynamics in engineered aluminum/polymer fuel particles. Combustion and Flame, 176, 162–171. https://doi.org/10.1016/j.combustflame.2016.10.008

Xie, J., Yin, K., Serov, A., Artyushkova, K., Pham, H. N., Sang, X., … Davis, R. J. (2017). Selective Aerobic Oxidation of Alcohols over Atomically‐Dispersed Non‐Precious Metal Catalysts. ChemSusChem, 10(2), 359–362. https://doi.org/10.1002/cssc.201601364

Wang, C., Chen, D. P., Sang, X., Unocic, R. R., & Skrabalak, S. E. (2016). Size-Dependent Disorder–Order Transformation in the Synthesis of Monodisperse Intermetallic PdCu Nanocatalysts. ACS Nano, 10(6), 6345–6353. https://doi.org/10.1021/acsnano.6b02669

Li, X., Puretzky, A. A., Sang, X., Kc, S., Tian, M., Ceballos, F., … Xiao, K. (2017). Suppression of Defects and Deep Levels Using Isoelectronic Tungsten Substitution in Monolayer MoSe<sub>2. Advanced Functional Materials, 27(19), 1603850. https://doi.org/10.1002/adfm.201603850

John, S. S., Atkinson, R. W., III, Roy, A., Unocic, R. R., Papandrew, A. B., & Zawodzinski, T. A., Jr. (2016). The Effect of Carbonate and pH on Hydrogen Oxidation and Oxygen Reduction on Pt-Based Electrocatalysts in Alkaline Media. Journal of The Electrochemical Society, 163(3), F291–F295. https://doi.org/10.1149/2.1071603jes

Achtyl, J. L., Unocic, R. R., Xu, L., Cai, Y., Raju, M., Zhang, W., … Geiger, F. M. (2015). Aqueous proton transfer across single-layer graphene. Nat Comms, 6, 6539. https://doi.org/10.1038/ncomms7539

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Naguib, M., Unocic, R. R., Armstrong, B. L., & Nanda, J. (2015). Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes.” Dalton Trans., 44(20), 9353–9358. https://doi.org/10.1039/c5dt01247c

Binder, A. J., Toops, T. J., Unocic, R. R., Parks, J. E., & Dai, S. (2015). Low-Temperature CO Oxidation over a Ternary Oxide Catalyst with High Resistance to Hydrocarbon Inhibition. Angew. Chem., 127(45), 13461–13465. https://doi.org/10.1002/ange.201506093

Kercher, A. K., Kolopus, J. A., Carroll, K. J., Unocic, R. R., Kirklin, S., Wolverton, C., … Dudney, N. J. (2015). Mixed Polyanion Glass Cathodes: Glass-State Conversion Reactions. Journal of The Electrochemical Society, 163(2), A131–A137. https://doi.org/10.1149/2.0381602jes

Sacci, R. L., Black, J. M., Balke, N., Dudney, N. J., More, K. L., & Unocic, R. R. (2015). Nanoscale Imaging of Fundamental Li Battery Chemistry: Solid-Electrolyte Interphase Formation and Preferential Growth of Lithium Metal Nanoclusters. Nano Letters, 15(3), 2011–2018. https://doi.org/10.1021/nl5048626

Jesse, S., He, Q., Lupini, A. R., Leonard, D. N., Oxley, M. P., Ovchinnikov, O., … Borisevich, A. Y. (2015). Patterning: Atomic-Level Sculpting of Crystalline Oxides: Toward Bulk Nanofabrication with Single Atomic Plane Precision (Small 44/2015). Small, 11(44), 5854–5854. https://doi.org/10.1002/smll.201570264

John, S. S., Atkinson, R. W., Unocic, K. A., Unocic, R. R., Zawodzinski, T. A., & Papandrew, A. B. (2015). Platinum and Palladium Overlayers Dramatically Enhance the Activity of Ruthenium Nanotubes for Alkaline Hydrogen Oxidation. ACS Catal., 5(11), 7015–7023. https://doi.org/10.1021/acscatal.5b01432

Unocic, R. R., Baggetto, L., Veith, G. M., Aguiar, J. A., Unocic, K. A., Sacci, R. L., … More, K. L. (2015). Probing battery chemistry with liquid cell electron energy loss spectroscopy. Chemical Communications, 51(91), 16377–16380. https://doi.org/10.1039/c5cc07180a

Ievlev, A. V., Jesse, S., Cochell, T. J., Unocic, R. R., Protopopescu, V. A., & Kalinin, S. V. (2015). Quantitative Description of Crystal Nucleation and Growth from in Situ Liquid Scanning Transmission Electron Microscopy. ACS Nano, 9(12), 11784–11791. https://doi.org/10.1021/acsnano.5b03720

Papandrew, A. B., Atkinson, R. W., III, Unocic, R. R., & Zawodzinski, T. A. (2015). Ruthenium as a CO-tolerant hydrogen oxidation catalyst for solid acid fuel cells. J. Mater. Chem. A, 3(7), 3984–3987. https://doi.org/10.1039/c4ta06451h

John, S. S., Atkinson, R. W., Unocic, R. R., Zawodzinski, T. A., & Papandrew, A. B. (2015). Ruthenium-Alloy Electrocatalysts with Tunable Hydrogen Oxidation Kinetics in Alkaline Electrolyte. J. Phys. Chem. C, 119(24), 13481–13487. https://doi.org/10.1021/acs.jpcc.5b03284

Atkinson, R. W., III, St. John, S., Dyck, O., Unocic, K. A., Unocic, R. R., Burke, C. S., … Papandrew, A. B. (2015). Supportless, Bismuth-Modified Palladium Nanotubes with Improved Activity and Stability for Formic Acid Oxidation. ACS Catalysis, 5(9), 5154–5163. https://doi.org/10.1021/acscatal.5b01239

Stehle, Y., Meyer, H. M., Unocic, R. R., Kidder, M., Polizos, G., Datskos, P. G., … Vlassiouk, I. V. (2015). Synthesis of Hexagonal Boron Nitride Monolayer: Control of Nucleation and Crystal Morphology. Chem. Mater., 27(23), 8041–8047. https://doi.org/10.1021/acs.chemmater.5b03607

Atkinson, R. W., III, Unocic, R. R., Unocic, K. A., Veith, G. M., Zawodzinski, T. A., Jr., & Papandrew, A. B. (2015). Vapor Synthesis and Thermal Modification of Supportless Platinum–Ruthenium Nanotubes and Application as Methanol Electrooxidation Catalysts. ACS Applied Materials & Interfaces, 7(19), 10115–10124. https://doi.org/10.1021/am508228b

Surwade, S. P., Smirnov, S. N., Vlassiouk, I. V., Unocic, R. R., Veith, G. M., Dai, S., & Mahurin, S. M. (2015). Water desalination using nanoporous single-layer graphene. Nature Nanotech, 10(5), 459–464. https://doi.org/10.1038/nnano.2015.37

Sun, X.-G., Liao, C., Baggetto, L., Guo, B., Unocic, R. R., Veith, G. M., & Dai, S. (2014). Bis(fluoromalonato)borate (BFMB) anion based ionic liquid as an additive for lithium-ion battery electrolytes. J. Mater. Chem. A, 2(20), 7606. https://doi.org/10.1039/c3ta14943a

Hayes, R. W., Unocic, R. R., & Nasrollahzadeh, M. (2014). Creep Deformation of Allvac 718Plus. Metallurgical and Materials Transactions A, 46(1), 218–228. https://doi.org/10.1007/s11661-014-2564-y

Unocic, R. R., Sun, X.-G., Sacci, R. L., Adamczyk, L. A., Alsem, D. H., Dai, S., … More, K. L. (2014). Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with <i>In Situ</i> Electrochemical Transmission Electron Microscopy. Microscopy and Microanalysis, 20(4), 1029–1037. https://doi.org/10.1017/s1431927614012744

Veith, G. M., Baggetto, L., Sacci, R. L., Unocic, R. R., Tenhaeff, W. E., & Browning, J. F. (2014). Direct measurement of the chemical reactivity of silicon electrodes with LiPF6-based battery electrolytes. Chemical Communications, 50(23), 3081. https://doi.org/10.1039/c3cc49269a

Schultz, B. M., Unocic, R. R., DesJardins, J. D., & Kennedy, M. S. (2014). Formation of a Metallic Amorphous Layer During the Sliding Wear of Ti/TiN Nanolaminates. Tribology Letters, 55(2), 219–226. https://doi.org/10.1007/s11249-014-0350-z

Borisevich, A. Y., Chi, M., & Unocic, R. R. (2014). Functional Electron Microscopy for Electrochemistry Research: From the Atomic to Micro Scale. The Electrochemical Society-Interface, 23(2), 61–67. https://doi.org/10.1149/2.F07142if

Sacci, R. L., Dudney, N. J., More, K. L., & Unocic, R. R. (2014). In operando Transmission Electron Microscopy Imaging of SEI Formation and Structure in Li-Ion and Li-Metal Batteries. Microsc Microanal, 20(S3), 1538–1539. https://doi.org/10.1017/s1431927614009428

Mehdi, B. L., Gu, M., Parent, L. R., Xu, W., Nasybulin, E. N., Chen, X., … Browning, N. D. (2014). In-Situ Electrochemical Transmission Electron Microscopy for Battery Research. Microsc Microanal, 20(02), 484–492. https://doi.org/10.1017/s1431927614000488

Unocic, K. A., Allard, L. F., Coffey, D. W., More, K. L., & Unocic, R. R. (2014). Novel Method for Precision Controlled Heating of TEM Thin Sections to Study Reaction Processes. Microscopy and Microanalysis, 20(S3), 1628–1629. https://doi.org/10.1017/s1431927614009878

Baggetto, L., Carroll, K. J., Hah, H.-Y., Johnson, C. E., Mullins, D. R., Unocic, R. R., … Veith, G. M. (2014). Probing the Mechanism of Sodium Ion Insertion into Copper Antimony Cu 2 Sb Anodes. J. Phys. Chem. C, 118(15), 7856–7864. https://doi.org/10.1021/jp501032d

Unocic, R. R., Sacci, R. L., Brown, G. M., Veith, G. M., Dudney, N. J., More, K. L., … Nackashi, D. P. (2014). Quantitative Electrochemical Measurements Using <i>In Situ</i> ec-S/TEM Devices. Microscopy and Microanalysis, 20(2), 452–461. https://doi.org/10.1017/s1431927614000166

Zhou, H., Nanda, J., Martha, S. K., Unocic, R. R., Meyer, H. M., III, Sahoo, Y., … Albrecht, T. F. (2014). Role of Surface Functionality in the Electrochemical Performance of Silicon Nanowire Anodes for Rechargeable Lithium Batteries. ACS Applied Materials & Interfaces, 6(10), 7607–7614. https://doi.org/10.1021/am500855a

Baggetto, L., Carroll, K. J., Unocic, R. R., Bridges, C. A., Meng, Y. S., & Veith, G. M. (2014). Sodium Manganese Oxide Thin Films as Cathodes for Na-Ion Batteries. ECS Transactions, 58(12), 47–57. https://doi.org/10.1149/05812.0047ecst

Unocic, R. R., Sacci, R. L., Veith, G. M., Dudney, N. J., & More, K. L. (2014). Tuning Electrodeposition Parameters for Tailored Nanoparticle Size, Shape, and Morphology: An In Situ ec-STEM Investigation. Microsc Microanal, 20(S3), 1506–1507. https://doi.org/10.1017/s143192761400926x

Xiao, X., Liu, Z., Baggetto, L., Veith, G. M., More, K. L., & Unocic, R. R. (2014). Unraveling manganese dissolution/deposition mechanisms on the negative electrode in lithium ion batteries. Physical Chemistry Chemical Physics, 16(22), 10398. https://doi.org/10.1039/c4cp00833b

Baggetto, L., Ganesh, P., Meisner, R. P., Unocic, R. R., Jumas, J.-C., Bridges, C. A., & Veith, G. M. (2013). Characterization of sodium ion electrochemical reaction with tin anodes: Experiment and theory. Journal of Power Sources, 234, 48–59. https://doi.org/10.1016/j.jpowsour.2013.01.083

Bridges, C. A., Harrison, K. L., Unocic, R. R., Idrobo, J.-C., Paranthaman, M. P., & Manthiram, A. (2013). Defect chemistry of phospho-olivine nanoparticles synthesized by a microwave-assisted solvothermal process. Journal of Solid State Chemistry, 205, 197–204. https://doi.org/10.1016/j.jssc.2013.07.011

Gu, M., Parent, L. R., Mehdi, B. L., Unocic, R. R., McDowell, M. T., Sacci, R. L., … Wang, C.-M. (2013). Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes. Nano Letters, 13(12), 6106–6112. https://doi.org/10.1021/nl403402q

Sacci, R. L., Dudney, N. J., More, K. L., Parent, L. R., Arslan, I., Browning, N. D., & Unocic, R. R. (2014). Direct visualization of initial SEI morphology and growth kinetics during lithium deposition by in situ electrochemical transmission electron microscopy. Chemical Communications, 50(17), 2104. https://doi.org/10.1039/c3cc49029g

Browning, K. L., Baggetto, L., Unocic, R. R., Dudney, N. J., & Veith, G. M. (2013). Gas evolution from cathode materials: A pathway to solvent decomposition concomitant to SEI formation. Journal of Power Sources, 239, 341–346. https://doi.org/10.1016/j.jpowsour.2013.03.118

Bi, Z., Paranthaman, M. P., Guo, B., Unocic, R. R., Meyer, H. M., III, Bridges, C. A., … Dai, S. (2014). High performance Cr, N-codoped mesoporous TiO2 microspheres for lithium-ion batteries. Journal of Materials Chemistry A, 2(6), 1818–1824. https://doi.org/10.1039/c3ta14535b

Arruda, T. M., Lawton, J. S., Kumar, A., Unocic, R. R., Kravchenko, I. I., Zawodzinski, T. A., … Balke, N. (2013). In Situ Formation of Micron-Scale Li-Metal Anodes with High Cyclability. ECS Electrochemistry Letters, 3(1), A4–A7. https://doi.org/10.1149/2.003401eel

Yoon, S., Bridges, C. A., Unocic, R. R., & Paranthaman, M. P. (2013). Mesoporous TiO2 spheres with a nitridated conducting layer for lithium-ion batteries. Journal of Materials Science, 48(15), 5125–5131. https://doi.org/10.1007/s10853-012-7098-3

Baggetto, L., Allcorn, E., Unocic, R. R., Manthiram, A., & Veith, G. M. (2013). Mo3Sb7 as a very fast anode material for lithium-ion and sodium-ion batteries. Journal of Materials Chemistry A, 1(37), 11163. https://doi.org/10.1039/c3ta12040f

Martha, S. K., Nanda, J., Kim, Y., Unocic, R. R., Pannala, S., & Dudney, N. J. (2013). Solid electrolyte coated high voltage layered–layered lithium-rich composite cathode: Li1.2Mn0.525Ni0.175Co0.1O2. Journal of Materials Chemistry A, 1(18), 5587. https://doi.org/10.1039/c3ta10586e

Qiao, Z.-an, Brown, S. S., Adcock, J., Veith, G. M., Bauer, J. C., Payzant, E. A., … Dai, S. (2012). A Topotactic Synthetic Methodology for Highly Fluorine-Doped Mesoporous Metal Oxides. Angew. Chem., 124(12), 2942–2947. https://doi.org/10.1002/ange.201107812

Qiao, Z., Brown, S. S., Adcock, J., Veith, G. M., Bauer, J. C., Payzant, E. A., … Dai, S. (2012). A Topotactic Synthetic Methodology for Highly Fluorine‐Doped Mesoporous Metal Oxides. Angewandte Chemie International Edition, 51(12), 2888–2893. https://doi.org/10.1002/anie.201107812

Yoon, S., Liao, C., Sun, X.-G., Bridges, C. A., Unocic, R. R., Nanda, J., … Paranthaman, M. P. (2012). Conductive surface modification of LiFePO4 with nitrogen-doped carbon layers for lithium-ion batteries. Journal of Materials Chemistry, 22(11), 4611. https://doi.org/10.1039/c2jm15325d

Unocic, R. R., Baggetto, L., Unocic, K. A., Veith, G. M., Dudney, N. J., & More, K. L. (2012). Coupling EELS/EFTEM Imaging with Environmental Fluid Cell Microscopy. Microscopy and Microanalysis, 18(S2), 1104–1105. https://doi.org/10.1017/s1431927612007374

Baggetto, L., Unocic, R. R., Dudney, N. J., & Veith, G. M. (2012). Fabrication and characterization of Li–Mn–Ni–O sputtered thin film high voltage cathodes for Li-ion batteries. Journal of Power Sources, 211, 108–118. https://doi.org/10.1016/j.jpowsour.2012.03.076

Li, H., Martha, S. K., Unocic, R. R., Luo, H., Dai, S., & Qu, J. (2012). High cyclability of ionic liquid-produced TiO2 nanotube arrays as an anode material for lithium-ion batteries. Journal of Power Sources, 218, 88–92. https://doi.org/10.1016/j.jpowsour.2012.06.096

Alsem, D., Salmon, N. J., Unocic, R. R., Veith, G. M., & More, K. L. (2012). In-situ liquid and gas transmission electron microscopy of nano-scale materials. Microsc Microanal, 18(S2), 1158–1159. https://doi.org/10.1017/s1431927612007647

Phillips, P. J., Unocic, R. R., & Mills, M. J. (2013). Low cycle fatigue of a polycrystalline Ni-based superalloy: Deformation substructure analysis. International Journal of Fatigue, 57, 50–57. https://doi.org/10.1016/j.ijfatigue.2012.11.008

Unocic, R. R., Unocic, K. A., Pint, B. A., & Lipschutz, M. D. (2011). Characterization of Pre- and Post-Service Grain Boundary Phases in a Cast Austenitic Steel. https://doi.org/10.1115/gt2011-46710

Unocic, R. R., Zhou, N., Kovarik, L., Shen, C., Wang, Y., & Mills, M. J. (2011). Dislocation decorrelation and relationship to deformation microtwins during creep of a γ′ precipitate strengthened Ni-based superalloy. Acta Materialia, 59(19), 7325–7339. https://doi.org/10.1016/j.actamat.2011.07.069

Liu, R., Mahurin, S. M., Li, C., Unocic, R. R., Idrobo, J. C., Gao, H., … Dai, S. (2011). Dopamine as a Carbon Source: The Controlled Synthesis of Hollow Carbon Spheres and Yolk-Structured Carbon Nanocomposites. Angew. Chem., 123(30), 6931–6934. https://doi.org/10.1002/ange.201102070

Liu, R., Mahurin, S. M., Li, C., Unocic, R. R., Idrobo, J. C., Gao, H., … Dai, S. (2011). Dopamine as a Carbon Source: The Controlled Synthesis of Hollow Carbon Spheres and Yolk‐Structured Carbon Nanocomposites. Angewandte Chemie International Edition, 50(30), 6799–6802. https://doi.org/10.1002/anie.201102070

Mylavarapu, S. K., Sun, X., Christensen, R. N., Unocic, R. R., Glosup, R. E., & Patterson, M. W. (2012). Fabrication and design aspects of high-temperature compact diffusion bonded heat exchangers. Nuclear Engineering and Design, 249, 49–56. https://doi.org/10.1016/j.nucengdes.2011.08.043

Kim, Y., Veith, G. M., Nanda, J., Unocic, R. R., Chi, M., & Dudney, N. J. (2011). High voltage stability of LiCoO2 particles with a nano-scale Lipon coating. Electrochimica Acta, 56(19), 6573–6580. https://doi.org/10.1016/j.electacta.2011.03.070

Unocic, R., Adamczyk, L., Dudney, N., Alsem, D., Salmon, N., & More, K. (2011). In-situ TEM Characterization of Electrochemical Processes in Energy Storage Systems. Microsc Microanal, 17(S2), 1564–1565. https://doi.org/10.1017/s1431927611008695

Chan‐Thaw, C. E., Villa, A., Veith, G. M., Kailasam, K., Adamczyk, L. A., Unocic, R. R., … Thomas, A. (2011). Influence of Periodic Nitrogen Functionality on the Selective Oxidation of Alcohols. Chemistry – An Asian Journal, 7(2), 387–393. https://doi.org/10.1002/asia.201100565

Liu, H., Bi, Z., Sun, X. G., Unocic, R. R., Paranthaman, M. P., Dai, S., & Brown, G. M. (2011). Mesoporous TiO<sub>2</sub>–B Microspheres with Superior Rate Performance for Lithium Ion Batteries. Advanced Materials, 23(30), 3450–3454. https://doi.org/10.1002/adma.201100599

Rathmell, A., Unocic, R., Howe, J., & Wiley, B. (2011). TEM and In-situ Liquid Cell Characterization of Copper Nanowire Growth Mechanisms. Microsc Microanal, 17(S2), 462–463. https://doi.org/10.1017/s1431927611003187

Unocic, R. R., Unocic, K. A., Hayes, R. W., Daehn, G. S., & Mills, M. J. (2012, August). A TEM Study of Creep Deformation Mechanisms in Allvac 718Plus. Superalloy 718 and Derivatives, pp. 607–615. https://doi.org/10.1002/9781118495223.ch47

Grassman, T. J., Brenner, M. R., Gonzalez, M., Carlin, A. M., Unocic, R. R., Dehoff, R. R., … Ringel, S. A. (2010). Characterization of Metamorphic GaAsP/Si Materials and Devices for Photovoltaic Applications. IEEE Trans. Electron Devices, 57(12), 3361–3369. https://doi.org/10.1109/ted.2010.2082310

Wang, X., Fulvio, P. F., Baker, G. A., Veith, G. M., Unocic, R. R., Mahurin, S. M., … Dai, S. (2010). Direct exfoliation of natural graphite into micrometre size few layers graphene sheets using ionic liquids. Chemical Communications, 46(25), 4487. https://doi.org/10.1039/c0cc00799d

Unocic, K. A., Unocic, R. R., Pint, B. A., & Hayes, R. W. (2012, August). Effect of Microstucture and Environment on the High-Temperature Oxidation Behavior of Alloy 718Plus. Superalloy 718 and Derivatives, pp. 977–991. https://doi.org/10.1002/9781118495223.ch74

Phillips, P. J., Unocic, R. R., Kovarik, L., Mourer, D., Wei, D., & Mills, M. J. (2010). Low cycle fatigue of a Ni-based superalloy: Non-planar deformation. Scripta Materialia, 62(10), 790–793. https://doi.org/10.1016/j.scriptamat.2010.01.044

Phillips, P. J., Kovarik, L., Unocic, R. R., Wei, D., Mourer, D., & Mills, M. J. (2010). The Importance of High-Resolution Scanning Transmission Electron Microscopy For Fine-Scale Dislocation Analysis. Microsc Microanal, 16(S2), 1798–1799. https://doi.org/10.1017/s1431927610060575

Grassman, T. J., Brenner, M. R., Rajagopalan, S., Unocic, R., Dehoff, R., Mills, M., … Ringel, S. A. (2009). Control and elimination of nucleation-related defects in GaP/Si(001) heteroepitaxy. Applied Physics Letters, 94(23). https://doi.org/10.1063/1.3154548

Sandhage, K. H., Allan, S. M., Dickerson, M. B., Gaddis, C. S., Shian, S., Weatherspoon, M. R., … Palenik, B. P. (2014, August). Merging Biological Self-Assembly with Synthetic Chemical Tailoring: The Potential for 3-D Genetically Engineered Micro/Nano-Devices (3-D GEMS). Progress in Nanotechnology, pp. 85–94. https://doi.org/10.1002/9780470588260.ch12

Kovarik, L., Unocic, R. R., Li, J., Sarosi, P., Shen, C., Wang, Y., & Mills, M. J. (2009). Microtwinning and other shearing mechanisms at intermediate temperatures in Ni-based superalloys. Progress in Materials Science, 54(6), 839–873. https://doi.org/10.1016/j.pmatsci.2009.03.010

Kovarik, L., Unocic, R. R., Li, J., & Mills, M. J. (2009). The intermediate temperature deformation of Ni-based superalloys: Importance of reordering. JOM, 61(2), 42–48. https://doi.org/10.1007/s11837-009-0026-6

Grassman, T. J., Brenner, M. R., Carlin, A. M., Rajagopalan, S., Unocic, R., Dehoff, R., … Ringel, S. A. (2009). Toward metamorphic multijunction GaAsP/Si photovoltaics grown on optimized GaP/Si virtual substrates using anion-graded GaAs<inf>y</inf>P<inf>1-y</inf> buffers. 2009 34th IEEE Photovoltaic Specialists Conference (PVSC). https://doi.org/10.1109/pvsc.2009.5411489

Unocic, R. R., Kovarik, L., Shen, C., Sarosi, P. M., Wang, Y., Li, J., … Mills, M. J. (2008). Deformation Mechanisms in Ni-Base Disk Superalloys at Higher Temperatures. Superalloys 2008 (Eleventh International Symposium), 377–385. https://doi.org/10.7449/2008/superalloys_2008_377_385

Kovarik, L., Unocic, R. R., Li, J., & Mills, M. J. (2008). HAADF Imaging and MD Simulations of Microtwining Partial Dislocations in Nickel Based Superalloy Rene 104, Microsc Microanal, 14(S2), 938–939. https://doi.org/10.1017/s1431927608087114

Kovarik, L., Viswanathan, G., Unocic, R., Sarosi, P. M., & Mills, M. (2007). HRTEM and STEM HAADF Study of Microtwining During Creep Deformation in Nickel Based Superalloy Rene 104. MAM, 13(S02). https://doi.org/10.1017/s1431927607076817

Sandhage, K. H., Allan, S. M., Dickerson, M. B., Ernst, E. M., Gaddis, C. S., Shian, S., … Zalar, F. M. (2007). Inorganic Preforms of Biological Origin: Shape‐Preserving Reactive Conversion of Biosilica Microshells (Diatoms). https://doi.org/10.1002/9783527619443.ch37

Unocic, R. R., Viswanathan, G. B., Sarosi, P. M., Karthikeyan, S., Li, J., & Mills, M. J. (2008). Mechanisms of creep deformation in polycrystalline Ni-base disk superalloys. Materials Science and Engineering: A, 483-484, 25–32. https://doi.org/10.1016/j.msea.2006.08.148

Unocic, R., Kovarik, L., Sarosi, P. M., & Mills, M. (2007). Structural and Chemical Analysis of Stacking Faults in the gamma-phase of a Creep Deformed Ni-Base Superalloy. MAM, 13(S02). https://doi.org/10.1017/s1431927607077458

Viswanathan, G. B., Karthikeyan, S., Sarosi, P. M., Unocic, R. R., & Mills, M. J. (2006). Microtwinning during intermediate temperature creep of polycrystalline Ni-based superalloys: mechanisms and modelling. Philosophical Magazine, 86(29-31), 4823–4840. https://doi.org/10.1080/14786430600767750

Sarosi, P. M., Viswanathan, G. B., Demania, W., Unocic, R., & Mills, M. J. (2005). Imaging and Characterization of the Microstructure and Creep Deformation Mechanisms of Commercial Nickel-based Superalloys. MAM, 11(S02). https://doi.org/10.1017/s1431927605509267

Sandhage, K. H., Allan, S. M., Dickerson, M. B., Gaddis, C. S., Shian, S., Weatherspoon, M. R., … Palenik, B. P. (2005). Merging Biological Self‐Assembly with Synthetic Chemical Tailoring: The Potential for 3‐D Genetically Engineered Micro/Nano‐Devices (3‐D GEMS). International Journal of Applied Ceramic Technology, 2(4), 317–326. https://doi.org/10.1111/j.1744-7402.2005.02035.x

Karthikeyan, S., Unocic, R. R., Sarosi, P. M., Viswanathan, G. B., Whitis, D. D., & Mills, M. J. (2006). Modeling microtwinning during creep in Ni-based superalloys. Scripta Materialia, 54(6), 1157–1162. https://doi.org/10.1016/j.scriptamat.2005.11.049

Unocic, R. R., Sarosi, P. M., Viswanathan, G. B., Mills, M. J., & Whitis, D. A. (2005). The Creep Deformation Mechanisms of Nickel Base Superalloy René 104. MAM, 11(S02). https://doi.org/10.1017/s1431927605510031

Unocic, R. R., Zalar, F. M., Sarosi, P. M., Cai, Y., & Sandhage, K. H. (2004). Anatase assemblies from algae: coupling biological self-assembly of 3-D nanoparticle structures with synthetic reaction chemistry. Chemical Communications, (7), 796. https://doi.org/10.1039/b400599f

Unocic, R. R., & DuPont, J. N. (2004). Process efficiency measurements in the laser engineered net shaping process. Metallurgical and Materials Transactions B, 35(1), 143–152. https://doi.org/10.1007/s11663-004-0104-7

Unocic, R. R., & DuPont, J. N. (2003). Composition control in the direct laser-deposition process. Metallurgical and Materials Transactions B, 34(4), 439–445. https://doi.org/10.1007/s11663-003-0070-5

Dickerson, M. B., Unocic, R. R., Guerra, K. T., Timberlake, M. J., & Sandhage, K. H. (2000). The fabrication of dense carbide/refractory metal composites of near net shape at modest temperatures by the PRIMA-DCP process. Ceramics Transactions, 115, 25–31.