Sergey Vladimirovich Tsukanov

Works (3)

Updated: July 6th, 2023 21:15

2016 journal article

Studies toward the Synthesis of Lepadiformine A

JOURNAL OF ORGANIC CHEMISTRY, 81(21), 10433–10443.

By: S. Tsukanov n, L. Marks n & D. Comins n

MeSH headings : Alkaloids / chemical synthesis; Alkaloids / chemistry; Animals; Carbon-13 Magnetic Resonance Spectroscopy; Cyclization; Molecular Structure; Proton Magnetic Resonance Spectroscopy; Stereoisomerism; Urochordata / chemistry
TL;DR: An original approach to access a tricyclic framework of the lepadiformine-type alkaloids using a Grignard/N-acylpyridinium salt reaction to establish the desired absolute stereochemistry at the C2 position of the target alkaloid. (via Semantic Scholar)
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Source: Web Of Science
Added: August 6, 2018

2014 journal article

Total Synthesis of Alkaloid 205B

JOURNAL OF ORGANIC CHEMISTRY, 79(19), 9074–9085.

By: S. Tsukanov n & D. Comins n

MeSH headings : Alkaloids / chemical synthesis; Alkaloids / chemistry; Catalysis; Heterocyclic Compounds, 3-Ring / chemical synthesis; Heterocyclic Compounds, 3-Ring / chemistry; Molecular Structure; Pyridines / chemical synthesis; Pyridines / chemistry; Stereoisomerism
TL;DR: The synthesis features the use of an N-acylpyridinium salt reaction to introduce the first stereocenter and an unprecedented trifluoroacetic anhydride-mediated addition of an allylstannane to a vinylogous amide with complete facial selectivity. (via Semantic Scholar)
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Source: Web Of Science
Added: August 6, 2018

2011 journal article

Concise Total Synthesis of the Frog Alkaloid (-)-205B

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 50(37), 8626–8628.

By: S. Tsukanov n & D. Comins n

author keywords: alkaloids; dihydropyridones; natural products; total synthesis; Tsuji-Trost reaction
MeSH headings : Alkaloids / chemical synthesis; Alkaloids / chemistry; Animals; Anura; Heterocyclic Compounds, 3-Ring / chemical synthesis; Heterocyclic Compounds, 3-Ring / chemistry; Molecular Conformation; Stereoisomerism
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Source: Web Of Science
Added: August 6, 2018

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