Tashni-Ann Coote

Works (2)

Updated: July 5th, 2023 15:55

2011 journal article

Synthesis of and structure-property relationships in zinc complexes of bis-metaphenylene semiquinone biradical species

Journal of Physical Organic Chemistry, 25(4), 314–321.

By: J. Sloop *, D. Shultz n , T. Coote n, B. Shepler *, U. Sullivan n, J. Kampf *, P. Boyle n

author keywords: bis(metaphenylene) semiquinone biradicals; electron paramagnetic resonance; SQUID magnetometry; substituent effects
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Added: August 6, 2018

2007 journal article

Substituent Effects on Exchange Coupling:  5-Aryl-Substituted Semiquinones and Their Complexes with MnIIand CuII

Inorganic Chemistry, 46(1), 273–277.

By: D. Shultz n , J. Sloop  n, T. Coote n, M. Beikmohammadi n, J. Kampf  n & P. Boyle n

TL;DR: For the MnII complexes, electron-withdrawing substituents on the phenyl ring have greater ferromagnetic J values than the CuII complexes of SQ ligands with electron-donating substituent, which suggests a FM contribution from MLCT excited states in the copper complexes. (via Semantic Scholar)
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