TY - CONF TI - Synthesis and Properties of Partially Substituted Polyacetylenes Derived from the Ring-Opening Metathesis Polymerization of Monosubstituted Cyclooctatetraenes AU - Gorman, C.B. AU - Ginsburg, E.J. AU - Moore, J.S. AU - Grubbs, R.H. C2 - 1991/// C3 - Polymer Preprints DA - 1991/// VL - 32 SP - 714–715 M1 - 3 ER - TY - CONF TI - Soluble polyacetylenes derived from the ring-opening metathesis polymerization (ROMP) of substituted cyclooctatetraenes: electrochemical characterization and Schottky barrier devices AU - Jozefiak, T.H. AU - Sailor, M.J. AU - Ginsburg, E.J. AU - Gorman, C.B. AU - Lewis, N.S. AU - Grubbs, R. AB - Recent developments in ring-opening metathesis polymerization (ROMP) have enabled the synthesis of poly-cyclooctatetraene (poly-COT), a material which is isostructural to polyacetylene. This liquid-phase polymerization method allows facile construction of interfaces, films, and devices with polyacetylene-like materials. The ROMP method also allows the preparation of soluble, yet highly conjugated polyacetylene analogs from substituted cyclooctatetraenes (R-COT). The redox characteristics of R-COT polymers were investigated at electrodes modified with thin polymer films. Voltammetric methods were used to characterize the redox response, band gap, electrochemical doping, and cis-trans isomerization properties of these polyenes. We have applied poly-COT technology to the fabrication of Schottky diodes and photoelectrochemical cells, by forming poly-COT films on semiconductor surfaces. The resultant semiconductor/organic-metal interfaces behave more ideally than semiconductor contacts with conventional metals, in that changes in the work function of the conducting polymer exert a large and predictable effect on the electrical properties of the resulting Schottky diodes. Transparent films of the solution-processible polymer poly- trimethylsilyl-cyclooctatetraene (poly-TMS-COT) have been cast onto n-silicon substrates and doped with iodine to form surface barrier solar cells. These devices produce photovoltages that are much larger than can be obtained from n-silicon contacts with conventional metals. C2 - 1991/3/1/ C3 - Proceedings of SPIE DA - 1991/3/1/ DO - 10.1117/12.45109 VL - 1436 SP - 8–19 M1 - Photochemistry and Photoelectrochemistry of Organic and Inorganic Molecular Thin Film ER - TY - CONF TI - Electrochemical Characterization of Soluble Polyacetylenes Derived from the Ring-Opening Metathesis Polymerization (ROMP) of Substituted Cyclooctatatraenes AU - Jozefiak, T.H. AU - Ginsburg, E.J. AU - Gorman, C.B. AU - Sailor, M.J. AU - Grubbs, R.H. AU - Lewis, N.S. C2 - 1991/// C3 - Annual Technical Conference of the Society of Plastics Engineers DA - 1991/// VL - 49 SP - 872–874 ER - TY - CHAP TI - Conjugated Polymers: The Interplay Between Synthesis, Structure, and Properties AU - Gorman, C.B. AU - Grubbs, R. T2 - Conjugated Polymers: The Novel Science and Technology of Conducting and Nonlinear Optically Active Materials A2 - Brédas, J.L. A2 - Silbey, R.R. PY - 1991/// SP - 1–48 PB - Kluwer Academic Publishers ER - TY - JOUR TI - Effect of allyl methyl substituents on the preparation, dynamics, and reactivity of zirconium complexes (.eta.5-C5Me5)(allyl)ZrX2 (X = Cl, Br): structure of (.eta.5-C5Me5)(C3H5)ZrCl2 and (.eta.5-C5Me5)(1,2-Me2(butadiene))(.eta.2-CH2PPh2)Zr. Dynamics of (.eta.5-C5Me5)(2,3-Me2(butadiene))(.eta.2-CH2PPh2)Zr AU - Vance, Peter J. AU - Prins, Thomas J. AU - Hauger, Bryan E. AU - Wemple, Michael E. AU - Pederson, Lori M. AU - Kort, David A. AU - Kannisto, Michael R. AU - Geerligs, Steven J. AU - Kelly, Richard S. AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of allyl methyl substituents on the preparation, dynamics, and reactivity of zirconium complexes (.eta.5-C5Me5)(allyl)ZrX2 (X = Cl, Br): structure of (.eta.5-C5Me5)(C3H5)ZrCl2 and (.eta.5-C5Me5)(1,2-Me2(butadiene))(.eta.2-CH2PPh2)Zr. Dynamics of (.eta.5-C5Me5)(2,3-Me2(butadiene))(.eta.2-CH2PPh2)ZrPeter J. Vance, Thomas J. Prins, Bryan E. Hauger, Michael E. Wemple, Lori M. Pederson, David A. Kort, Michael R. Kannisto, Steven J. Geerligs, Richard S. Kelly, and Cite this: Organometallics 1991, 10, 4, 917–924Publication Date (Print):April 1, 1991Publication History Published online1 May 2002Published inissue 1 April 1991https://doi.org/10.1021/om00050a023RIGHTS & PERMISSIONSArticle Views71Altmetric-Citations14LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts DA - 1991/// PY - 1991/// DO - 10.1021/om00050a023 UR - http://dx.doi.org/10.1021/om00050a023 ER - TY - JOUR TI - Ab initio Studies of Silane Decomposition on Si(100) AU - Jing, Z. AU - Whitten, J.L. T2 - Physical Review B AB - The mechanism of silane decomposition on the Si(100)-(2\ifmmode\times\else\texttimes\fi{}1) surface is investigated in the context of a many-electron theory that permits the accurate computation of molecule-solid surface interactions at an ab initio configuration-interaction level. The adsorbate and local surface region are treated as embedded in the remainder of the lattice electronic distribution, which is modeled as a three-layer, 19-Si--plus--21-H cluster. A possible energetic pathway is found for the reaction ${\mathrm{SiH}}_{4}$\ensuremath{\rightarrow}${\mathrm{SiH}}_{3}$+H on the surface. It involves two separate steps: (1) scission of one Si-H bond; (2) formation of two bonds to ${\mathrm{SiH}}_{3}$ and H from two surface dangling bonds. The energy barrier, which is calculated to be 9 kcal/mol, occurs in the first step at a distance of 3.6 \AA{} from the Si in ${\mathrm{SiH}}_{4}$ to a Si surface atom with a Si-H bond aligned with a surface dangling-bond direction. The overall dissociation process ${\mathrm{SiH}}_{4}$\ensuremath{\rightarrow}${\mathrm{SiH}}_{3}$+H on the surface is found to be 2.8 eV exothermic. Quantum tunneling is found to play an important role in the process at room temperature. A symmetrical Eckart potential is used to estimate the quantum tunneling effect and the reaction probability is calculated to be small (on the order of ${10}^{\mathrm{\ensuremath{-}}5}$) and relatively insensitive to the silane temperature. DA - 1991/7/15/ PY - 1991/7/15/ DO - 10.1103/PhysRevB.44.1741 VL - 44 IS - 4 SP - 1741–1746 ER - TY - JOUR TI - Chemical Induction Effects: O-incorporation in, and Substitutional Doping of a Si:H AU - Lucovsky, G. AU - Jing, Z. AU - Whitten, J.L. T2 - Journal of Non-Crystalline Solids AB - This paper identifies several important non-statistical bonding environments in alloyed and doped a-Si:H. These include O-Si-H linkages in a-Si,O:H alloys, and P+-Si-H and Si-B--H linkages that play a significant role in the doping processes in a-Si:H. We present the experimental evidence for these bonding arrangements, and a model that accounts for their creation during film deposition. DA - 1991/// PY - 1991/// DO - 10.1016/S0022-3093(05)80071-7 VL - 137-138 IS - 1 SP - 119–122 ER - TY - JOUR TI - Ab initio chemisorption studies of methyl on nickel(111) AU - Yang, H. AU - Whitten, J.L. T2 - Journal of the American Chemical Society AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAb initio chemisorption studies of methyl on nickel(111)Hong Yang and Jerry L. WhittenCite this: J. Am. Chem. Soc. 1991, 113, 17, 6442–6449Publication Date (Print):August 1, 1991Publication History Published online1 May 2002Published inissue 1 August 1991https://doi.org/10.1021/ja00017a013Request reuse permissionsArticle Views200Altmetric-Citations80LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (2 MB) Get e-Alertsclose Get e-Alerts DA - 1991/// PY - 1991/// DO - 10.1021/ja00017a013 VL - 113 IS - 17 SP - 6442–6449 ER - TY - JOUR TI - The adsorption of benzene on Ni(111) AU - Jing, Ze AU - Whitten, Jerry L. T2 - Surface Science AB - Using a many-electron embedding theory, the present work treats the adsorption of benzene on Ni(111) by modelling the lattice as a 28-atom, three-layer cluster. Ab initio valence orbital CI calculations carried out on a local surface region permit an accurate description of bonding at the surface. Benzene is found to be adsorbed molecularly, parallel to the surface, at a threefold site, bonding primarily through its π electron system. The equilibrium distance is 2.2 Å from the surface. The calculations show no distortion of the benzene ring, other than a 2% expansion. CH bonds tilt away from the surface 8.5°. The adsorption energy is calculated to be 1.2 eV. Adsorption at the threefold hollow site gives a slightly higher energy than the hep site, but the difference may be within the uncertainty of the calculation. The energy of the bridge adsorption site is higher than that of the hcp site, by 0.8 eV. Atop atom sites were not investigated. Due to the limited number of geometries investigated, particularly those involving Kekule and buckling distortions, some aspects of the benzene geometry and energetics of different sites remain uncertain. DA - 1991/7// PY - 1991/7// DO - 10.1016/0039-6028(91)90717-7 VL - 250 IS - 1-3 SP - 147-158 J2 - Surface Science LA - en OP - SN - 0039-6028 UR - http://dx.doi.org/10.1016/0039-6028(91)90717-7 DB - Crossref ER - TY - JOUR TI - Chemisorption of atomic H and CHx fragments on Ni(111) AU - Yang, Hong AU - Whitten, Jerry L. T2 - Surface Science AB - The adsorption of atomic hydrogen, methylidyne, methylene and methyl on the (111) surface of nickel is treated using a many-electron embedding theory to describe bonding, modelling the lattice as a 28-atom, three-layer cluster. Ab initio valence orbital configuration interaction (multiple parent) calculations carried out on a local surface region permit an accurate description of bonding at the surface. All adsorbed species are found to bind strongly to the Ni(111) surface at three-fold and bridge sites with adsorption energies ranging from 1.5 to 3.1 eV. Atop Ni adsorption sites have significantly higher energy. Bond lengths, angles and vibrational frequencies for adsorbates on the surface are calculated. The geometries of the adsorbed species and the nature of the bonding to the surface are discussed. DA - 1991/9// PY - 1991/9// DO - 10.1016/0039-6028(91)90021-j VL - 255 IS - 1-2 SP - 193-207 J2 - Surface Science LA - en OP - SN - 0039-6028 UR - http://dx.doi.org/10.1016/0039-6028(91)90021-j DB - Crossref ER - TY - CHAP TI - Approaches to Magnetic Organic Materials AU - Dougherty, D. A. AU - Grubbs, R. H. AU - Kaisaki, D. A. AU - Chang, W. AU - Jacobs, S. J. AU - Shultz, D. A. AU - Anderson, K. K. AU - Jain, R. AU - Ho, P. T. AU - Stewart, E. G. T2 - Magnetic Molecular Materials PY - 1991/// DO - 10.1007/978-94-011-3254-1_6 SP - 105-120 OP - PB - Springer Netherlands SN - 9789401054355 9789401132541 UR - http://dx.doi.org/10.1007/978-94-011-3254-1_6 DB - Crossref ER - TY - JOUR TI - Understanding reactivity trends by structural and theoretical studies of distortions in ground-state reagents AU - Jackson, S.A. AU - Eisenstein, O. AU - Martin, J.D. AU - Albeniz, A.C. AU - Crabtree, R.H. T2 - Organometallics DA - 1991/// PY - 1991/// VL - 10 IS - 9 SP - 3062-3069 UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-0001105120&partnerID=MN8TOARS ER - TY - JOUR TI - Antiperovskite structure with ternary tetrathiafulvalenium salts: Construction, distortion, and antiferromagnetic ordering AU - Batail, P. AU - Livage, C. AU - Parkin, S.S.P. AU - Coulon, C. AU - Martin, J.D. AU - Canadell, E. T2 - Angewandte Chemie (International Edition in English) DA - 1991/// PY - 1991/// VL - 30 IS - 11 SP - 1498-1500 UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-33748215379&partnerID=MN8TOARS ER - TY - CHAP TI - New Polymeric Materials with Cubic Optical Nonlinearities Derived from Ring-Opening Metathesis Polymerization AU - Grubbs, R. H. AU - Gorman, C. B. AU - Ginsburg, E. J. AU - Perry, Joseph W. AU - Marder, Seth R. T2 - ACS Symposium Series AB - Partially substituted derivatives of polyacetylene are synthesized via the ring-opening metathesis polymerization (ROMP) of cyclooctatetraene (COT) and its derivatives. Certain poly-COT derivatives afford soluble, highly conjugated poly acetylenes. These materials exhibit large third-order optical nonlinearities and low scattering losses. PY - 1991/3/11/ DO - 10.1021/bk-1991-0455.ch045 SP - 672-682 OP - PB - American Chemical Society SN - 0841219397 0841213119 UR - http://dx.doi.org/10.1021/bk-1991-0455.ch045 DB - Crossref ER - TY - JOUR TI - Kinetics and mechanism of the hydrolysis of 2,4,6-trimethylbenzosulfonic acid in concentrated hydrochloric and sulfuric acid solution AU - Vinnik, M.I. AU - Smirnov, A.I. T2 - Kinetics and Catalysis DA - 1991/// PY - 1991/// VL - 32 IS - 3 pt 1 SP - 534-540 UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-0026259936&partnerID=MN8TOARS ER - TY - JOUR TI - EPR imaging with natural spin probes AU - Smirnov, Alex I AU - Yakimchenko, Olga E AU - Golovina, Helen A AU - Bekova, Shakhrazada Kh AU - Lebedev, Yakob S T2 - Journal of Magnetic Resonance (1969) AB - Food spoilage by chemical oxidation represents one of the major problems for society. Typically, an exposure of a food or beverage to oxygen would trigger a chain of chemical reactions involving proteins, pigments, fatty acids, and lipids, producing other compounds with undesirable biochemical properties including toxicity, as well as undesirable taste, smell, and color. Many of these processes occur via free radical mechanisms and involve chain reactions. This chapter reviews current progress in the use of electron paramagnetic resonance (EPR) spectroscopy to characterize endogenous free radicals and paramagnetic metal ion complexes in liquid food and beverages, as well as reactive radical species directly involved in chemical reactions leading to food degradation. This field has experienced enormous growth over the last two decades. We also review the expanding use of EPR to characterize antioxidants present in food, and commercial applications of EPR methods to predict the shelf life of beer. The remaining problems, potential solutions, and future directions for using this powerful and informative spectroscopic method in characterizing liquid food and beverages are also discussed. DA - 1991/2// PY - 1991/2// DO - 10.1016/0022-2364(91)90201-4 VL - 91 IS - 2 SP - 386-391 UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-0009579211&partnerID=MN8TOARS ER - TY - JOUR TI - Nonadiabatic dynamics of excited excess electrons in simple fluids AU - Space, B. AU - Coker, D. F. T2 - The Journal of Chemical Physics AB - We present a surface hopping trajectory method for studying nonadiabatic excess electronic relaxation in condensed systems. This approach is used to explore the nonadiabatic relaxation after photoexciting an equilibrated excess electron in dense fluid helium. We survey the different types of nonadiabatic phenomena which are important in excess electronic relaxation. Very rapid diabatic processes are common when the nuclear dynamics provides only weak couplings between the adiabatic states. This is generally the case when the states are localized in different regions of space. We find that the nuclear dynamics provides a mechanism for strong coupling between s- and p-like states localized in the same solvent cavity. These strong nonadiabatic interactions can persist over a wide range of nuclear configurations and for many hundreds of femtoseconds. DA - 1991/2// PY - 1991/2// DO - 10.1063/1.459920 VL - 94 IS - 3 SP - 1976-1984 J2 - The Journal of Chemical Physics LA - en OP - SN - 0021-9606 1089-7690 UR - http://dx.doi.org/10.1063/1.459920 DB - Crossref ER - TY - JOUR TI - SYNTHESIS AND PROPERTIES OF PARTIALLY SUBSTITUTED POLYACETYLENES DERIVED FROM THE RING-OPENING METATHESIS POLYMERIZATION OF MONOSUBSTITUTED CYCLOCTATETRAENES AU - GORMAN, CB AU - GINSBURG, EJ AU - MOORE, JS AU - al., T2 - ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY DA - 1991/// PY - 1991/// VL - 202 SP - 329-POLY ER - TY - JOUR TI - SYNTHESIS AND CHARACTERIZATION OF ELECTRONIC INTERFACES DERIVED FROM SOLUBLE, CONDUCTING, POLYACETYLENES AU - SAILOR, MJ AU - GINSBURG, EJ AU - GORMAN, CB AU - al., T2 - ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY DA - 1991/// PY - 1991/// VL - 201 SP - 102-INOR ER - TY - JOUR TI - SUBSTITUTED POLYACETYLENES THROUGH THE RING-OPENING METATHESIS POLYMERIZATION (ROMP) OF SUBSTITUTED CYCLOOCTATETRAENES - A ROUTE INTO SOLUBLE POLYACETYLENE AU - GORMAN, CB AU - GINSBURG, EJ AU - SAILOR, MJ AU - al., T2 - SYNTHETIC METALS DA - 1991/// PY - 1991/// VL - 41 IS - 3 SP - 1033-1038 ER - TY - JOUR TI - SOLUBLE, CHIRAL POLYACETYLENES - SYNTHESES AND INVESTIGATION OF THEIR SOLUTION CONFORMATION AU - MOORE, JS AU - GORMAN, CB AU - GRUBBS, RH T2 - JOURNAL OF THE AMERICAN CHEMICAL SOCIETY DA - 1991/// PY - 1991/// VL - 113 IS - 5 SP - 1704-1712 ER - TY - JOUR TI - NEW POLYMERIC MATERIALS WITH CUBIC OPTICAL NONLINEARITIES DERIVED FROM RING-OPENING METATHESIS POLYMERIZATION AU - GRUBBS, RH AU - GORMAN, CB AU - GINSBURG, EJ AU - al., T2 - ACS SYMPOSIUM SERIES DA - 1991/// PY - 1991/// VL - 455 SP - 672-682 ER - TY - JOUR TI - Matrix selection in the FAB mass spectral analysis of synthetic dyes AU - Freeman, H. S. AU - Hao, Z. AU - Sokolowska-Gajda, J. AU - VanBreemen, R. B. T2 - Dyes and Pigments DA - 1991/// PY - 1991/// VL - 16 IS - 4 SP - 317 ER - TY - JOUR TI - ORGANOPHOSPHORUS INHIBITORS OF INSECT JUVENILE-HORMONE ESTERASE AU - LINDERMAN, RJ AU - TSHERING, T AU - VENKATESH, K AU - GOODLETT, DR AU - DAUTERMAN, WC AU - ROE, RM T2 - PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY AB - Abstract Three classes of organophosphorus inhibitors, O -alkyl ethylphosphonates, enol phosphates, and α-thioalkylphosphonates have been prepared and assayed as inhibitors of insect juvenile hormone (JH) esterase. The O -alkyl ethylphosphonates were prepared from ethylphosphonic dichloride by sequential addition of sodium 4-nitrophenoxide and the appropriate lithium alkoxide. The enol phosphates were prepared via the Perkow reaction from α-chloro aldehydes. Ethyl O -4-nitrophenyl octylthiomethylphosphonate (ENOSP) and ethyl S -phenyl octylthiomethylphosphonothioate (EPOSP) were prepared from diethyl thiomethylphosphonate. The O -alkyl phosphonate series exhibited in vitro activity ( I 50 = 10 −6 to 10 −8 M ) as inhibitors for JH esterase. In in vivo studies, n -hexyl O -4-nitrophenyl ethylphosphonate (ONEP) was a persistent but nonselective inhibitor of JH esterase. The enol phosphates were ineffective JH esterase inhibitors in in vitro and in vivo studies. The α-thioalkylphosphonates ENOSP and EPOSP were very potent JH esterase inhibitors, I 50 = 1.0 × 10 −9 and 4.9 × 10 −9 M , respectively. Both ENOSP and EPOSP were also persistent in vivo inhibitors which exhibited considerable selectivity for JH esterase over α-naphthyl acetate esterase. A kinetic analysis of ENOSP determined that inhibition followed pseudo-first-order kinetics in which a reversible enzyme/inhibitor complex precedes irreversible phosphorylation. The bimolecular rate constant ( k i ) was 6.52 × 10 7 M −1 min −1 , the phosphorylation rate constant ( k 2 ) was 2.66 min −1 , and the dissociation constant ( K d ) was 4.08 × 10 −8 M . The enhanced inhibitory potency of the α-thioalkylphosphonates may be due to anchimeric assistance of the S atom in the phosphorylation step, or to enhanced stability of the EI complex by hydrogen bonding. DA - 1991/1// PY - 1991/1// DO - 10.1016/0048-3575(91)90214-7 VL - 39 IS - 1 SP - 57-73 SN - 0048-3575 ER - TY - JOUR TI - High-performance liquid chromatography-continuous-flow fast atom bombardment mass spectrometry of chlorophyll derivatives AU - Van Breeman, R. B. AU - Canjura, F. L. AU - Schwantz, S. J. T2 - Journal of Chromatography. A DA - 1991/// PY - 1991/// VL - 542 IS - 2 SP - 373 ER - TY - PAT TI - Storage stable, readily reconstituted comestible AU - Bernacchi, D. B. AU - Loewe, R. J. AU - Immel, D. L. C2 - 1991/// DA - 1991/// PY - 1991/// ER - TY - JOUR TI - ORGANIC SUPERCONDUCTORS - NEW BENCHMARKS AU - WILLIAMS, JM AU - SCHULTZ, AJ AU - GEISER, U AU - CARLSON, KD AU - KINI, AM AU - WANG, HH AU - KWOK, WK AU - WHANGBO, MH AU - SCHIRBER, JE T2 - SCIENCE AB - Recent advances in the design and synthesis of organic synthetic metals have yielded materials that have the highest superconducting transition temperatures (T(c) approximately 13 kelvin) reported for these systems. These materials have crystal structures consisting of alternating layers of organic donor molecules and inorganic anions. Organic superconductors have various electronic and magnetic properties and crystal structures that are similar to those of the inorganic copper oxide superconductors (which have high T(c) values); these similarities include highly anisotropic conductivities, critical fields, and short coherence lengths. The largest number of organic superconductors, including those with the highest T(c) values, are charge-transfer salts derived from the electron donor molecule BEDT-TTF or ET [bis(ethylenedithio)-tetrathiafulvalene]. The synthesis and crystal structures of these salts are discussed; their electrical, magnetic, and band electronic structure properties and their many similarities to the copper oxide superconductors are treated as well. DA - 1991/6/14/ PY - 1991/6/14/ DO - 10.1126/science.252.5012.1501 VL - 252 IS - 5012 SP - 1501-1508 SN - 1095-9203 ER - TY - JOUR TI - ELECTRON-TRANSFER REACTION OF CYTOCHROME-C ADSORBED ON CARBOXYLIC-ACID TERMINATED ALKANETHIOL MONOLAYER ELECTRODES AU - TARLOV, MJ AU - BOWDEN, EF T2 - JOURNAL OF THE AMERICAN CHEMICAL SOCIETY AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron-transfer reaction of cytochrome c adsorbed on carboxylic acid terminated alkanethiol monolayer electrodesMichael J. Tarlov and Edmond F. BowdenCite this: J. Am. Chem. Soc. 1991, 113, 5, 1847–1849Publication Date (Print):February 1, 1991Publication History Published online1 May 2002Published inissue 1 February 1991https://doi.org/10.1021/ja00005a068Request reuse permissionsArticle Views967Altmetric-Citations324LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (471 KB) Get e-Alertsclose Get e-Alerts DA - 1991/2/27/ PY - 1991/2/27/ DO - 10.1021/ja00005a068 VL - 113 IS - 5 SP - 1847-1849 SN - 0002-7863 ER - TY - JOUR TI - CONCEPTUAL ASPECTS OF STRUCTURE PROPERTY CORRELATIONS AND ELECTRONIC INSTABILITIES, WITH APPLICATIONS TO LOW-DIMENSIONAL TRANSITION-METAL OXIDES AU - CANADELL, E AU - WHANGBO, MH T2 - CHEMICAL REVIEWS AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConceptual aspects of structure-property correlations and electronic instabilities, with applications to low-dimensional transition-metal oxidesEnric. Canadell and Myung Hwan. WhangboCite this: Chem. Rev. 1991, 91, 5, 965–1034Publication Date (Print):July 1, 1991Publication History Published online1 May 2002Published inissue 1 July 1991https://doi.org/10.1021/cr00005a015RIGHTS & PERMISSIONSArticle Views1576Altmetric-Citations263LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (7 MB) Get e-Alerts Get e-Alerts DA - 1991/// PY - 1991/// DO - 10.1021/cr00005a015 VL - 91 IS - 5 SP - 965-1034 SN - 0009-2665 ER -