Chemistry

Works Published in 2016

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Displaying works 201 - 220 of 254 in total

Sorted by most recent date added to the index first, which may not be the same as publication date order.

2016 journal article

Theoretical assessment of bonaccordite formation in pressurized water reactors

JOURNAL OF NUCLEAR MATERIALS, 474, 62–64.

By: Z. Rak n , C. O'Brien n, D. Shin *, A. Andersson*, C. Stanek* & D. Brenner n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2016 journal article

Nonmicrobial Nitrophenol Degradation via Peroxygenase Activity of Dehaloperoxidase-Hemoglobin fromAmphitrite ornata

Biochemistry, 55(17), 2465–2478.

By: N. McCombs n, J. D’Antonio n, D. Barrios n, L. Carey n & R. Ghiladi n 

Contributors: N. McCombs n, . J. D'Antonio, D. Barrios n, L. Carey n & R. Ghiladi n 

MeSH headings : Animals; Catalysis; Hemoglobins / metabolism; Hydrogen Peroxide / metabolism; Mixed Function Oxygenases / metabolism; Nitrophenols; Oxidation-Reduction; Oxygen / metabolism; Peroxidases / metabolism; Polychaeta / enzymology
TL;DR: The results demonstrate that there may be a much larger number of nonmicrobial enzymes that are underrepresented when it comes to understanding the degradation of persistent organic pollutants such as nitrophenols in the environment. (via Semantic Scholar)
UN Sustainable Development Goal Categories
14. Life Below Water (OpenAlex)
Sources: Web Of Science, ORCID, Crossref
Added: August 6, 2018

2016 journal article

Non-directed, carbonate-mediated C-H activation and aerobic C-H oxygenation with Cp*Ir catalysts

DALTON TRANSACTIONS, 45(24), 9942–9947.

By: M. Kerr*, I. Ahmed *, A. Gunay *, N. Venditto*, F. Zhu *, E. Ison n , M. Emmert *

TL;DR: Based on these studies, Cp*Ir/carbonate systems are developed that catalyze the aerobic Csp(3)-H oxygenation of alkyl arenes, employing air as oxidant. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Moving Kinetics of Nanocars with Hydrophobic Wheels on Solid Surfaces at Ambient Conditions

JOURNAL OF PHYSICAL CHEMISTRY C, 120(20), 10887–10894.

By: F. Chen n, V. Garcia-Lopez *, T. Jin n, B. Neupane n, P. Chu*, J. Tour *, G. Wang n

UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2016 journal article

Genetically encoded optical activation of DNA recombination in human cells

CHEMICAL COMMUNICATIONS, 52(55), 8529–8532.

By: J. Luo *, E. Arbely *, J. Zhang n, C. Chou n, R. Uprety n, J. Chin *, A. Deiters *

MeSH headings : Amino Acyl-tRNA Synthetases / genetics; Amino Acyl-tRNA Synthetases / metabolism; Catalytic Domain; HEK293 Cells; Humans; Integrases / chemistry; Integrases / metabolism; Lysine / metabolism; Methanosarcina / enzymology; Models, Molecular; Optical Phenomena; RNA, Transfer / metabolism; Recombination, Genetic; Tyrosine / metabolism
TL;DR: Two precisely regulated, light-activated Cre recombinase enzymes were generated through the site-specific incorporation of two genetically encoded photocaged amino acids in human cells. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2016 journal article

Enhanced photophysics from self-assembled cyclometalated Ir(III) complexes in water

CHEMICAL COMMUNICATIONS, 52(50), 7846–7849.

By: M. McGoorty n, R. Khnayzer * & F. Castellano n 

Contributors: M. McGoorty n, R. Khnayzer * & F. Castellano n 

TL;DR: Concentration-induced aggregation enhances the excited-state properties of both complexes, blue-shifting the photoluminescence emission energies as well as increasing the corresponding excited state lifetimes and quantum yields up to a factor of 5. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 article

Using Two Frameworks to Promote E-Leadership and Teacher Development

ICT IN EDUCATION IN GLOBAL CONTEXT: COMPARATIVE REPORTS OF INNOVATIONS IN K-12 EDUCATION, pp. 233–248.

By: D. Slykhuis* & J. Lee n 

author keywords: Professional development; TPACK; 21CLD
TL;DR: This chapter explores the application of TPACK and 21CLD as well as the decision-making behind and implications for expanding the focus of TEI. (via Semantic Scholar)
UN Sustainable Development Goal Categories
4. Quality Education (Web of Science)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Unmasking the Effects of L-DOPA on Rapid Dopamine Signaling with an Improved Approach for Nafion Coating Carbon-Fiber Microelectrodes

ANALYTICAL CHEMISTRY, 88(16), 8129–8136.

By: L. Qi n, E. Thomas n, S. White n, S. Smith n, C. Lee n, L. Wilson n, L. Sombers n 

MeSH headings : Animals; Brain / drug effects; Brain / metabolism; Carbon / chemistry; Carbon Fiber; Dopamine / analysis; Electrochemical Techniques; Electrodes, Implanted; Evoked Potentials / drug effects; Levodopa / pharmacology; Male; Microelectrodes; Parkinson Disease / metabolism; Parkinson Disease / pathology; Rats; Rats, Sprague-Dawley; Signal Transduction / drug effects
TL;DR: Overall, this work describes a reliable tool that allows a better measure of L-DOPA augmented dopamine release in vivo, measured using fast-scan cyclic voltammetry. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Transition-Metal Oxos as the Lewis Basic Component of Frustrated Lewis Pairs

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 138(14), 4832–4842.

By: N. Lambic n, R. Sommer n  & E. Ison n 

TL;DR: It is demonstrated for the first time that the incorporation of a transition-metal oxo in a frustrated Lewis pair can have a synergistic effect and results in enhanced catalytic activity at olefin hydrogenation. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Structural comparison of suberanilohydroxamic acid (SAHA) and other zinc-enzyme inhibitors bound to a monomeric zinc species

POLYHEDRON, 114, 344–350.

By: P. Cao *, R. Sommer n  & K. Grice *

author keywords: Biomimetic zinc; Tris-pyrazolyl borate ligands; Zinc enzyme structural mimics; Zinc binding groups; Hydroxamic acids
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 review

Stable N- and N/S-rich heterocyclic radicals: Synthesis and applications

[Review of ]. Heterocyclic chemistry in the 21st century: a tribute to alan katritzky, 119, 173–207.

By: C. Constantinides & P. Koutentis

Source: NC State University Libraries
Added: August 6, 2018

2016 journal article

Identification of Epigenetic Factor Proteins Expressed in Human Embryonic Stem Cell-Derived Trophoblasts and in Human Placental Trophoblasts

JOURNAL OF PROTEOME RESEARCH, 15(8), 2433–2444.

By: P. Sarkar n, A. Mischler n, S. Randall n, T. Collier n, K. Dorman*, K. Boggess*, D. Muddiman n , B. Rao n

author keywords: quantitative mass spectrometry; SILAC; human embryonic stem cell; trophoblast; epigenetic factor
MeSH headings : Cell Differentiation; DNA (Cytosine-5-)-Methyltransferases / genetics; Epigenomics; Female; Gene Expression / genetics; Human Embryonic Stem Cells / cytology; Humans; Placenta / chemistry; Placenta / cytology; Pregnancy; Transcription Factors / genetics; Trophoblasts / chemistry; Trophoblasts / cytology
TL;DR: The results support the use of hESC-derived trophoblasts as a model for placental troPHoblasts, which will enable further investigation of epigenetic factors involved in human trophoblast development, and hypothesized that nuclear proteomics of h ESPCs may be used for screening epigenetic factor proteins expressed by primary trophblasts in human placental tissue. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Exposing the Excited-State Equilibrium in an Ir-III Bichromophore: A Combined Time Resolved Spectroscopy and Computational Study

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016(12), 1808–1818.

By: J. Yarnell n, C. McCusker n, A. Leeds*, J. Breaux* & F. Castellano n 

Contributors: J. Yarnell n, C. McCusker n, A. Leeds*, J. Breaux* & F. Castellano n 

author keywords: Iridium; Chromophores; Luminescence; Photophysics; Electronic structure; Density functional calculations; Triplet states; Transient absorption kinetics
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Evaluation of ethyl N-(2-phenethyl) carbamate analogues as biofilm inhibitors of methicillin resistant Staphylococcus aureus

ORGANIC & BIOMOLECULAR CHEMISTRY, 14(28), 6853–6856.

By: M. Stephens n, N. Yodsanit * & C. Melander n

MeSH headings : Anti-Bacterial Agents / chemistry; Anti-Bacterial Agents / pharmacology; Biofilms / drug effects; Carbamates / chemistry; Carbamates / pharmacology; Humans; Methicillin-Resistant Staphylococcus aureus / drug effects; Methicillin-Resistant Staphylococcus aureus / physiology; Microbial Sensitivity Tests; Small Molecule Libraries / chemistry; Small Molecule Libraries / pharmacology; Staphylococcal Infections / drug therapy
TL;DR: A small molecule library consisting of 45 compounds was synthesized based on the bacterial metabolite ethyl N-(2-phenethyl) carbamate which revealed a potent analogue capabale of inhibiting several strains of Methicillin Resistant S. aureus biofilms with low to moderate micromolar IC50 values. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2016 journal article

Electronic Absorption Spectra of Tetrapyrrole-Based Pigments via TD-DFT: A Reduced Orbital Space Study

JOURNAL OF PHYSICAL CHEMISTRY A, 120(29), 5816–5825.

By: K. Shrestha n, K. Virgil n & E. Jakubikova n 

MeSH headings : Quantum Theory; Tetrapyrroles / chemistry
TL;DR: Tetrapyrrole-based pigments play a crucial role in photosynthesis as principal light absorbers in light-harvesting chemical systems, and accurate theoretical descriptions of the electronic absorption spectra of these pigments will aid in the proper description and understanding of the overall photophysics of photosynthesis. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Composition of Rosenthal Fibers, the Protein Aggregate Hallmark of Alexander Disease

JOURNAL OF PROTEOME RESEARCH, 15(7), 2265–2282.

By: M. Heaven, D. Flint, S. Randall n, A. Sosunov, L. Wilson, S. Barnes, J. Goldman, D. Muddiman n , M. Brenner

author keywords: Rosenthal fiber; Alexander disease; protein aggregates; neurodegenerative disease; astrocyte; proteomics; mass spectrometry (MS); stress granules
MeSH headings : Alexander Disease; Animals; Astrocytes; Cyclin D2 / analysis; DEAD-box RNA Helicases / analysis; GTP-Binding Proteins / analysis; Humans; Immunohistochemistry; Mice; Neoplasm Proteins / analysis; Neuropeptides / analysis; Protein Aggregates; Protein Aggregation, Pathological; Proteome / analysis; RNA Helicases / analysis; Receptors for Activated C Kinase; Receptors, Cell Surface / analysis
TL;DR: No support was obtained for the sequestration hypothesis for AxD, but the association of several of the RF proteins with stress granules suggests a role for stressgranules in the origin of RFs. (via Semantic Scholar)
UN Sustainable Development Goal Categories
3. Good Health and Well-being (Web of Science; OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Adsorptive recovery of an essential rose oil component from aqueous solution by nanoporous carbon (CMK-3)

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 13(7), 1315–1324.

By: A. Koolivand n, A. Badiei *, P. Arab* & G. Ziarani *

author keywords: 2-Phenylethanol; Rosewater; Adsorption; CMK-3; Adsorptive recovery
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2016 journal article

A Quantitative Glycomics and Proteomics Combined Purification Strategy

Journal of Visualized Experiments, 3(109).

By: E. Hecht n, J. McCord n & D. Muddiman n 

author keywords: Chemistry; Issue 109; Glycomics; proteomics; glycosylation-site analysis; deamidation; hydrazide tagging; relative quantitation
MeSH headings : Animals; Chickens; Chromatography, Liquid / methods; Glycomics / methods; Glycopeptides / analysis; Glycopeptides / blood; Glycosylation; Humans; Mass Spectrometry / methods; Peptides / analysis; Peptides / blood; Polysaccharides / analysis; Polysaccharides / blood; Protein Processing, Post-Translational; Proteins / analysis; Proteomics / methods; Solid Phase Extraction / methods; Swine
TL;DR: A new in-line high-throughput, unbiased, filter based protocol for quantitative glycomics and proteomics analysis and showed that N-glycans purified on filter and derivatized by hydrophobic hydrazide tags were comparable in terms of abundance and class to those by solid phase extraction (SPE); the latter is considered a gold standard in the field. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Crossref, ORCID, NC State University Libraries
Added: August 6, 2018

2016 article

What if you could only publish 50 papers your entire career?

Muddiman, D. C. (2016, January). ANALYTICAL AND BIOANALYTICAL CHEMISTRY, Vol. 408, pp. 663–664.

By: D. Muddiman n 

TL;DR: Though this shift to the highest publishable unit (HPU) will not mean every paper is a blockbuster, it would guarantee that each manuscript fulfills one or more of three goals: Regardless of journal type or impact factor, each manuscript should detail a complete and significant study. (via Semantic Scholar)
Sources: Web Of Science, ORCID
Added: August 6, 2018

2016 journal article

Wall modified photonic crystal fibre capillaries as porous layer open tubular columns for in-capillary micro-extraction and capillary chromatography

ANALYTICA CHIMICA ACTA, 905, 1–7.

By: A. Kazarian n, E. Rodriguez *, J. Deverell*, J. McCord n, D. Muddiman n  & B. Paull *

author keywords: Polymer monolith; Porous layer open tubular column; Fused silica photonic crystal fibres; In-capillary extraction; Bioseparations
MeSH headings : Chromatography, Liquid / instrumentation; Chromatography, Liquid / methods; Equipment Design; Photons; Porosity; Reproducibility of Results; Spectrometry, Fluorescence
TL;DR: The modified multi-channel capillaries were applied to the in-capillary micro-extraction of water samples, proving chromatographic potential of the new column format, with run-to-run retention time reproducibility of below 1%. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Sources: Web Of Science, ORCID
Added: August 6, 2018

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