TY - RPRT TI - Literature Review: Bubble Evolution and Its Effect on Electrochemical Systems AU - Fedkiw, P. AU - Yan, J-F A3 - DuPont Company DA - 1994/1// PY - 1994/1// PB - DuPont Company ER - TY - CONF TI - Effects of Toluene and Benzoic Acid on the Kinetics of Ferrous Oxidation on Pt and Nafion-Coated Pt Electrodes AU - Fedkiw, P. AU - Ye, J-H T2 - Douglas N. Bennion Memorial Symposium A2 - Bennion, D.N. A2 - Newman, J.S. A2 - White, R.E. C2 - 1994/5// C3 - Proceedings of the Douglas N. Bennion Memorial Symposium : topics in electrochemical engineering CY - San Francisco, CA DA - 1994/5// PY - 1994/// PB - Electrochemical Society ER - TY - RPRT TI - A Simplified Model for a Parallel-Plate Water Electrolyzer AU - Fedkiw, P. AU - Yan, J-F A3 - DuPont Company DA - 1994/3// PY - 1994/3// PB - DuPont Company ER - TY - CHAP TI - PROGRESS IN LARGE AREA SELECTIVE SILICON DEPOSITION FOR TFT LCD APPLICATIONS AU - SOUK, JH AU - PARSONS, GN AU - Schiff, EA AU - Hack, M AU - Madan, A AU - Powell, M AU - Matsuda, A T2 - Amorphous Silicon Technology-1994 PY - 1994/// VL - 336 SP - 19-24 PB - SE - UR - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:A1994BC30G00003&KeyUID=WOS:A1994BC30G00003 ER - TY - JOUR TI - Extremely Thermophilic Microorganisms: Metabolic strategies, genetic characteristics and biotechnological potential of extremely thermophilic microorganisms AU - Kelly, R.M. AU - Peeples, T.L. AU - Halio, S.B. AU - Rinker, K.D. AU - Duffaud, G.D. T2 - Annals of the New York Academy of Sciences DA - 1994/// PY - 1994/// DO - 10.1111/j.1749-6632.1994.tb44393.x Citations: 5 VL - 745 IS - 1 SP - 409–425 ER - TY - JOUR TI - Life in boiling water AU - Adams, M.W.W. AU - Baross, J.A. AU - Kelly, R.M. T2 - Chemistry in Britain DA - 1994/// PY - 1994/// VL - 30 IS - 7 SP - 555–558 ER - TY - BOOK TI - Biochemical Engineering VIII - Proceedings A3 - Kelly, R.M. A3 - Wittrup, K.D. A3 - Karkare, S. DA - 1994/// PY - 1994/// VL - 745 SP - 461 PB - New York Academy of Sciences ER - TY - RPRT TI - Effects of Solar UV Radiation on Materials AU - Andrady, A.L. AU - Amin, M.B. AU - Hamid, S.H. AU - Hu, X. AU - Torikai, A. T2 - UNEP Environmental Effects Panel Report: 1991 A3 - United Nations Environmental Programme DA - 1994/// PY - 1994/// PB - United Nations Environmental Programme ER - TY - JOUR TI - Thermostability and thermoactivity of enzymes from hyperthermophilic archaea AU - Adams, M.W.W. AU - Kelly, R.M. T2 - Bioorganic & Medicinal Chemistry AB - Enzymes from hyperthermophilic microorganisms are characteristically thermostable and thermoactive at extremely high temperatures. Information about the basis for the structure and function of these novel proteins is beginning to emerge. However, there are very few generalizations that can be drawn at this point that can be derived from the limited number of studies that have focused on biocatalysis and thermostability at extremely high tempratures. Enzymes from hyperthennophilic microorganisms are characteristically thermostable and thermoactive at extremely high temperatures. Information about the basis for the structure and function of these novel proteins is beginning to emerge. However, there are very few generalizations that can be drawn at this point that can be derived from the limited number of studies that have focused on biocatalysis and thermostability at extremely high temperatures. DA - 1994/7// PY - 1994/7// DO - 10.1016/0968-0896(94)85015-1 VL - 2 IS - 7 SP - 659-667 J2 - Bioorganic & Medicinal Chemistry LA - en OP - SN - 0968-0896 UR - http://dx.doi.org/10.1016/0968-0896(94)85015-1 DB - Crossref ER - TY - JOUR TI - Studies on enhanced degradable plastics. III. The effect of weathering of polyethylene and (ethylene-carbon monoxide) copolymers on moisture and carbon dioxide permeability AU - Nakatsuka, Shuji AU - Andrady, Anthony T2 - Journal of Environmental Polymer Degradation DA - 1994/4// PY - 1994/4// DO - 10.1007/bf02074784 VL - 2 IS - 2 SP - 161-167 J2 - J Environ Polym Degr LA - en OP - SN - 1064-7564 1572-8900 UR - http://dx.doi.org/10.1007/bf02074784 DB - Crossref ER - TY - JOUR TI - Assessment of Environmental Biodegradation of Synthetic Polymers AU - Andrady, Anthony L. T2 - Journal of Macromolecular Science, Part C: Polymer Reviews AB - Abstract The large-scale commercial use of synthetic polymers and their disposal in the environment is a phenomenon less than half a century old, a duration which is minuscule in the evolutionary time scale required for microbial evolution on earth. Consequently, unlike their naturally-occurring counterparts, the biopolymers, which enjoyed long-term interactions with the microbial biosphere, synthetic polymers never had the opportunity to serve as a source of a microbial nutrient of any significance. Hence, few, if any, of the microorganisms are biochemically equipped to catabolize synthetic macromolecules. This lack of development of metabolic pathways capable of utilizing synthetic polymers is often cited as the main reason for recalcitrance of synthetic polymers in the environment [1]. The term “recalcitrant” is used here to describe organic compounds that persist for extended periods of time in the environment, but not necessarily as a result of microbial fallibility. DA - 1994/2// PY - 1994/2// DO - 10.1080/15321799408009632 VL - 34 IS - 1 SP - 25-76 J2 - Journal of Macromolecular Science, Part C: Polymer Reviews LA - en OP - SN - 1532-1797 1520-5746 UR - http://dx.doi.org/10.1080/15321799408009632 DB - Crossref ER - TY - JOUR TI - Fluorocarbon-Based Heterophase Polymeric Materials. 1. Block Copolymer Surfactants for Carbon Dioxide Applications AU - Guan, Zhibin AU - DeSimone, J. M. T2 - Macromolecules AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFluorocarbon-Based Heterophase Polymeric Materials. 1. Block Copolymer Surfactants for Carbon Dioxide ApplicationsZhibin Guan and J. M. DeSimoneCite this: Macromolecules 1994, 27, 20, 5527–5532Publication Date (Print):September 1, 1994Publication History Published online1 May 2002Published inissue 1 September 1994https://doi.org/10.1021/ma00098a002RIGHTS & PERMISSIONSArticle Views419Altmetric-Citations90LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (605 KB) Get e-AlertsSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts DA - 1994/9// PY - 1994/9// DO - 10.1021/ma00098a002 VL - 27 IS - 20 SP - 5527-5532 J2 - Macromolecules LA - en OP - SN - 0024-9297 1520-5835 UR - http://dx.doi.org/10.1021/ma00098a002 DB - Crossref ER - TY - JOUR TI - Homogeneous free-radical polymerizations in carbon dioxide. 3. Telomerization of 1,1-difluoroethylene in supercritical carbon dioxide AU - Combes, J. R. AU - Guan, Z. AU - DeSimone, J. M. T2 - Macromolecules AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHomogeneous free-radical polymerizations in carbon dioxide. 3. Telomerization of 1,1-difluoroethylene in supercritical carbon dioxideJ. R. Combes, Z. Guan, and J. M. DeSimoneCite this: Macromolecules 1994, 27, 3, 865–867Publication Date (Print):January 1, 1994Publication History Published online1 May 2002Published inissue 1 January 1994https://doi.org/10.1021/ma00081a036RIGHTS & PERMISSIONSArticle Views208Altmetric-Citations49LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (363 KB) Get e-Alertsclose Get e-Alerts DA - 1994/5// PY - 1994/5// DO - 10.1021/ma00081a036 VL - 27 IS - 3 SP - 865-867 J2 - Macromolecules LA - en OP - SN - 0024-9297 1520-5835 UR - http://dx.doi.org/10.1021/ma00081a036 DB - Crossref ER - TY - JOUR TI - Thiophene-based poly(arylene ether)s: 5. Imide-arylene ether statistical copolymers AU - Sheares, V.V. AU - DeSimone, J.M. AU - Hedrick, J.L. AU - Carter, K.R. AU - Labadie, J.W. T2 - Polymer AB - Abstract Imide-aryl ether thiophene copolymers were prepared and their thermal and mechanical properties were investigated. A key feature of these copolymers is the incorporation of the 2,5-thiophene moiety using 5,5′-bis[(3-aminophenoxy)thienyl-2] Ketone or 5,5′-bis[(4-aminophenoxy)thienyl-2] ketone as diamines in polyimide syntheses. The preparation of these thiophene diamines involved the nucleophilic aromatic substitution of bis(5-chlorothienyl-2) ketone with either 3- or 4-aminophenol in N -methyl-2-pyrrolidinone using potassium carbonate. These diamines were reacted with various compositions of pyromellitic dianhydride and 4,4′-oxydianiline to synthesize the desired poly(amic acid)s. Films were cast and cured (300°C) to effect the imide formation, and the resulting films showed tough ductile mechanical properties with high glass transition temperatures that decreased with increasing thiophene diamine content. DA - 1994/8// PY - 1994/8// DO - 10.1016/0032-3861(94)90562-2 VL - 35 IS - 17 SP - 3782-3785 J2 - Polymer LA - en OP - SN - 0032-3861 UR - http://dx.doi.org/10.1016/0032-3861(94)90562-2 DB - Crossref KW - THIOPHENE-BASED POLYMERS KW - IMIDE ARYLENE ETHER COPOLYMERS KW - SYNTHESIS ER - TY - JOUR TI - End-Functionalized Polymers. 2. Quantification of Functionalization by Time-of-Flight Secondary Ion Mass Spectrometry AU - Belu, A. M. AU - Hunt, M. O. AU - DeSimone, J. M. AU - Linton, R. W. T2 - Macromolecules AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEnd-Functionalized Polymers. 2. Quantification of Functionalization by Time-of-Flight Secondary Ion Mass SpectrometryA. M. Belu, M. O. Hunt Jr., J. M. DeSimone, and R. W. LintonCite this: Macromolecules 1994, 27, 7, 1905–1910Publication Date (Print):March 1, 1994Publication History Published online1 May 2002Published inissue 1 March 1994https://doi.org/10.1021/ma00085a037RIGHTS & PERMISSIONSArticle Views95Altmetric-Citations-LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (675 KB) Get e-Alerts Get e-Alerts DA - 1994/3// PY - 1994/3// DO - 10.1021/ma00085a037 VL - 27 IS - 7 SP - 1905-1910 J2 - Macromolecules LA - en OP - SN - 0024-9297 1520-5835 UR - http://dx.doi.org/10.1021/ma00085a037 DB - Crossref ER - TY - JOUR TI - Structural Characterization of a Polymer Substituted Fullerene (Flagellene) by Small Angle Neutron Scattering AU - Affholter, K.A. AU - Bunick, G.J. AU - Desimone, J.M. AU - Hunt, M.O., JR. AU - Menceloglu, Y.Z. AU - Samulski, E.T. AU - Wignall, G.D. T2 - MRS Proceedings AB - ABSTRACT Small-angle neutron scattering (SANS) can structurally characterize fullerenes 1 in solvents with strong SANS contrast (e.g. CS 2 ). Deuterated solvents (e.g. toluene-d 8 ) have a high scattering length density (SLD), which is close to that of C 60 and C 70 moieties. Hence, there is virtually no SANS contrast with the solvent and these particles are practically “invisible” in such media. On the other hand, the negative scattering length of hydrogen means that the SLD of H 1 -containing materials is much lower, so they have strong contrast with toluene-d 8 . Thus, SANS makes it possible to study the size and shapes of modified buckyballs such as the polymer-substituted fullerenes, or flagellenes 2 . These consist of C 60 cores to which 1-4 polystyrene chains (with a molecular weight, MW ≃ 2000) are attached. The extrapolated cross section at zero angle of scatter [dΣ/dΩ(0)]s is a function of the number of pendant chains, so SANS can be used to assess the number of “arms” which are covalently attached to the fullerene “sphere”. Close agreement (± 4%) between the measured and calculated values of dΣ/dΩ(0) along with independent estimates of the radius of gyration (R g ) and second virial coefficient (A 2 ) for a calibration linear polystyrene sample serves as a cross check on the validity of this methodology. DA - 1994/// PY - 1994/// DO - 10.1557/proc-359-335 VL - 359 SP - 335-340 SN - 0272-9172 1946-4274 UR - http://dx.doi.org/10.1557/proc-359-335 ER - TY - CHAP TI - Flame Inhibition Chemistry and the Search for Additional Fire Fighting Chemicals AU - Nyden, M.R. AU - Linteris, G.T. AU - Burgess, D.R.F., Jr. AU - Westmoreland, P.R. AU - Tsang, W. AU - Zachariah, M.R. T2 - Evaluation of Alternative In-Flight Fire Suppressants for Full-Scale Testing in Simulated Aircraft Engine Nacelles and Dry Bays A2 - Grosshandler, W.L. A2 - Gann, R.G. A2 - Pitts, W.M. T3 - National Institute of Standards and Technology Special Publication PY - 1994/// SP - 467–641 PB - National Institute of Standards and Technology SV - 861 ER - TY - JOUR TI - Isomeric Poly(benzophenone)s: synthesis of Highly Crystalline Poly(4,4'-benzophenone) and Amorphous Poly(2,5-benzophenone), a Soluble Poly(p-phenylene) Derivative AU - Phillips, R. W. AU - Sheares, V. V. AU - Samulski, E. T. AU - DeSimone, J. M. T2 - Macromolecules AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIsomeric Poly(benzophenone)s: synthesis of Highly Crystalline Poly(4,4'-benzophenone) and Amorphous Poly(2,5-benzophenone), a Soluble Poly(p-phenylene) DerivativeR. W. Phillips, V. V. Sheares, E. T. Samulski, and J. M. DeSimoneCite this: Macromolecules 1994, 27, 8, 2354–2356Publication Date (Print):April 1, 1994Publication History Published online1 May 2002Published inissue 1 April 1994https://doi.org/10.1021/ma00086a064RIGHTS & PERMISSIONSArticle Views378Altmetric-Citations46LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (326 KB) Get e-Alerts Get e-Alerts DA - 1994/4// PY - 1994/4// DO - 10.1021/ma00086a064 VL - 27 IS - 8 SP - 2354-2356 J2 - Macromolecules LA - en OP - SN - 0024-9297 1520-5835 UR - http://dx.doi.org/10.1021/ma00086a064 DB - Crossref ER - TY - JOUR TI - Dispersion Polymerizations in Supercritical Carbon Dioxide AU - DeSimone, J. M. AU - Maury, E. E. AU - Menceloglu, Y. Z. AU - McClain, J. B. AU - Romack, T. J. AU - Combes, J. R. T2 - Science AB - Conventional heterogeneous dispersion polymerizations of unsaturated monomers are performed in either aqueous or organic dispersing media with the addition of interfacially active agents to stabilize the colloidal dispersion that forms. Successful stabilization of the polymer colloid during polymerization results in the formation of high molar mass polymers with high rates of polymerization. An environmentally responsible alternative to aqueous and organic dispersing media for heterogeneous dispersion polymerizations is described in which supercritical carbon dioxide (CO2) is used in conjunction with molecularly engineered free radical initiators and amphipathic molecules that are specifically designed to be interfacially active in CO2. Conventional lipophilic monomers, exemplified by methyl methacrylate, can be quantitatively (>90 percent) polymerized heterogeneously to very high degrees of polymerization (>3000) in supercritical CO2 in the presence of an added stabilizer to form kinetically stable dispersions that result in micrometer-sized particles with a narrow size distribution. DA - 1994/7/15/ PY - 1994/7/15/ DO - 10.1126/science.265.5170.356 VL - 265 IS - 5170 SP - 356-359 J2 - Science LA - en OP - SN - 0036-8075 1095-9203 UR - http://dx.doi.org/10.1126/science.265.5170.356 DB - Crossref ER - TY - CONF TI - Behavior of Fluids in Micropores AU - Gubbins, K.E. T2 - Summer Course on Recent Advances in Fluid Physics A2 - Velarde, M.G. A2 - Christov, C.I. C2 - 1994/// C3 - Fluid Physics, Lecture Notes of Summer Schools, Proceedings of the Summer Course on Recent Advances in Fluid Physics CY - Almeria, Spain DA - 1994/// PY - 1990/8// SP - 124–134 PB - World Scientific ER - TY - CONF TI - Statistical Mechanical Treatment of Inhomogeneous Fluids: Molecular Simulation and Density Functional Theory AU - Gubbins, K.E. T2 - Summer Course on Recent Advances in Fluid Physics A2 - Velarde, M.G. A2 - Christov, C.I. C2 - 1994/// C3 - Fluid Physics, Lecture Notes of Summer Schools, Proceedings of the Summer Course on Recent Advances in Fluid Physics CY - Almeria, Spain DA - 1994/// PY - 1990/8// SP - 88–115 PB - World Scientific ER - TY - CHAP TI - Application of Molecular Theory to Phase Equilibrium Predictions AU - Gubbins, K.E. T2 - Models for Thermodynamic and Phase Equilibrium Calculations A2 - Sandler, S.I. PY - 1994/// SP - 507–600 PB - Marcel Dekker ER - TY - JOUR TI - Book Review of "Gas cleaning for advanced coal-based power generation" AU - Westmoreland, P.R. T2 - Energy and Fuels DA - 1994/// PY - 1994/// VL - 8 SP - 1528 ER - TY - CHAP TI - FT-infrared spectroscopic and molecular simulation studies of adsorption of simple gases, methanol and water on aluminophosphates AU - Koh, Carolyn A. AU - Zollweg, John A. AU - Gubbins, Keith E. T2 - Characterization of Porous Solids III AB - We report an in-situ spectroscopic study of the chemical nature of the adsorbed species present in porous solids, such as aluminophosphates, during adsorption of simple gases, methanol, and water. Diffuse reflectance FTIR spectroscopy was used to distinguish between chemisorbed and physisorbed surface OH groups and identify their connection with surface protionic properties. Information on the extents of hydrogen-bonding, e.g. fraction of non-hydrogen-bonded and hydrogen-bonded species, and the adsorbate-adsorbate and adsorbate-adsorbent interactions were obtained, together with details on the structures of the various hydrogen-bonded species present. Experimental data obtained from adsorption measurements on VPI-5 were in qualitative agreement with results obtained from Grand Canonical Monte Carlo (GCMC) molecular simulations. Density profile plots were also obtained from the GCMC results. PY - 1994/// DO - 10.1016/s0167-2991(08)63065-7 SP - 61-70 OP - PB - Elsevier SN - 9780444814913 UR - http://dx.doi.org/10.1016/s0167-2991(08)63065-7 DB - Crossref ER - TY - CHAP TI - Pore Size Distribution Analysis and Networking: Studies of Microporous Sorbents AU - Lastoskie, Christian AU - Gubbins, Keith E. AU - Quirke, Nicholas T2 - Characterization of Porous Solids III AB - We present an impioved method, based upon nonlocal density functional theory, for determining the pore size distribution (PSD) of microporous materials from adsorption measurements. The analysis method is applied to adsorption data for nitrogen on porous carbon. The PSDs obtained using nonlocal theory are compared to PSDs calculated from the Kelvin equation and from the Horvath-Kawazoe method. Our results indicate that nonlocal theory provides a much more accurate interpretation of the PSD than previous methods have accorded, particularly for highly microporous sorbents. Neither the Kelvin equation nor the Horvath-Kawazoe method adequately reproduces the low pressure region of the carbon isotherm, while nonlocal theory gives a quantitatively accurate fit over the full range of the isotherm. Nonlocal theory predictions of pore filling pressures also compare favorably with Gibbs ensemble Monte Carlo simulation results. In a second study, we report preliminary results of an investigation of adsorption hysteresis in porous networks. We apply a new simulation technique, grand canonical molecular dynamics, to examine adsorption in a simplified model network. It is observed that the potential gradient at the junction between two pores of different width imposes a barrier to diffusion, preventing adsorption within a pore that would otherwise fill. The permutation of pore widths from the external surface to the internal pore space affects the observed uptake, particularly in microporous networks with strong solid-fluid forces. PY - 1994/// DO - 10.1016/s0167-2991(08)63064-5 SP - 51-60 OP - PB - Elsevier SN - 9780444814913 UR - http://dx.doi.org/10.1016/s0167-2991(08)63064-5 DB - Crossref ER - TY - CHAP TI - The effect of pore geometry on adsorption behavior AU - Balbuena, Perk B. AU - Gubbins, Keith E. T2 - Characterization of Porous Solids III AB - We compare the adsorption behavior (adsorption isotherms, phase equilibria and heats of adsorption) for simple fluids in pores of slit and cylindrical geometry. Calculations are based on an accurate non-local density functional theory, together with Lennard- Jones (LJ) interactions. For each pore geometry we examine the effects of intermolecular parameters, temperature and pore size. Well known experimental phenomena such as the crossing of isotherms is addressed in our discussion. Key signatures of different pore geometries are described. For small pores slits show qualitative different behavior from, the cylindrical geometry, since as pore size goes to zero the slit approaches a two-dimensional limit, whereas cylindrical pores go to a one dimensional limit. The implications of this behavior on properties such as the isosteric heat are studied. PY - 1994/// DO - 10.1016/s0167-2991(08)63063-3 SP - 41-50 OP - PB - Elsevier SN - 9780444814913 UR - http://dx.doi.org/10.1016/s0167-2991(08)63063-3 DB - Crossref ER - TY - RPRT TI - Industrial Applications of Computational Chemistry AU - Tsang, W. AU - Zachariah, M.R. AU - Westmoreland, P.R. A3 - National Institute of Standards and Technology DA - 1994/// PY - 1994/// M1 - NISTIR-5450 M3 - Workshop Report PB - National Institute of Standards and Technology SN - NISTIR-5450 ER - TY - BOOK TI - Gas-Phase and Surface Chemistry in Electronic Materials Processing A3 - Mountziaris, T.J. A3 - Paz-Pujalt, G. A3 - Smith, F.T.J. A3 - Westmoreland, P.R. DA - 1994/// PY - 1994/// SP - 556 PB - Materials Research Society SN - 1-55899-233-2 ER - TY - JOUR TI - The Oscillations of Solvation Forces in a Spherical Hard-Wall Pore AU - Suh, S.-H. AU - Kim, S.-C. AU - Kim, J.-P. AU - Shin, B.-S. AU - Gubbins, K.E. T2 - Bulletin of the Korean Chemical Society DA - 1994/// PY - 1994/// VL - 15 SP - 274–275 ER - TY - JOUR TI - The Oscillation of Solvation Forces in a Spherical Hard-Wall Pore AU - Suh, S.-H. AU - Kim, S.C. AU - Kim, J.P. AU - Gubbins, K.E. T2 - Bulletin of the Korean Chemical Society DA - 1994/// PY - 1994/// VL - 15 IS - 4 SP - 274–275 ER - TY - JOUR TI - Theory and simulation of associating fluids: Lennard-Jones chains with association sites AU - Müller, Erich A. AU - Vega, Lourdes F. AU - Gubbins, Keith E. T2 - Molecular Physics AB - A perturbation approach based on Wertheim's first order theory for associating fluids is applied to predict the thermodynamic properties of chain molecules with association sites. A Lennard-Jones chain is used as a reference to account for the repulsive, dispersive and anisotropic (shape) contributions, while the short range directional attraction peculiar to associating fluids, modelled as spherical square-well sites, are treated as a perturbation over the chain reference fluid. Isobaric-isothermal Monte Carlo simulations were performed for model fluids composed of a chain of four tangently bonded Lennard-Jones spheres. Three cases are considered: one-site models with the association site placed either in an end sphere or in a central sphere, and a two-site model with sites placed at both ends. Subcritical and supercritical temperatures and several association strengths were studied. While the theory is seen to predict accurately the simulation results, its practical accuracy is subject to the limitations of the reference equation of state and the approximations made regarding the reference fluid. DA - 1994/12/20/ PY - 1994/12/20/ DO - 10.1080/00268979400101881 VL - 83 IS - 6 SP - 1209-1222 J2 - Molecular Physics LA - en OP - SN - 0026-8976 1362-3028 UR - http://dx.doi.org/10.1080/00268979400101881 DB - Crossref ER - TY - JOUR TI - Theoretical studies on VPI-5. Origin of the hydrophilicity AU - Kitao, Osamu AU - Gubbins, Keith E. T2 - Chemical Physics Letters AB - The hydrophilic property of VPI-5 is investigated using cluster models by an ab initio MO method. The four cluster models of Al(ON)4 studied differ from each other in the original locations of the aluminum atom and in whether they are for the hydrate or the dehydrate. Only one model, which has an aluminum site at the center of the fused four-membered rings in the hydrated VPI-5, can adsorb a water molecule with an attractive interaction energy of over 25 kcal/mol. The other models show only repulsive interaction energies. DA - 1994/9// PY - 1994/9// DO - 10.1016/0009-2614(94)00868-x VL - 227 IS - 6 SP - 545-550 J2 - Chemical Physics Letters LA - en OP - SN - 0009-2614 UR - http://dx.doi.org/10.1016/0009-2614(94)00868-x DB - Crossref ER - TY - JOUR TI - Molecular simulation of fluid adsorption in buckytubes and MCM-41 AU - Maddox, M. W. AU - Gubbins, K. E. T2 - International Journal of Thermophysics DA - 1994/11// PY - 1994/11// DO - 10.1007/bf01458820 VL - 15 IS - 6 SP - 1115-1123 J2 - Int J Thermophys LA - en OP - SN - 0195-928X 1572-9567 UR - http://dx.doi.org/10.1007/bf01458820 DB - Crossref KW - ADSORPTION KW - ALUMINOSILICATES KW - BUCKYTUBES KW - GRAND CANONICAL MONTE CARLO KW - ISOTHERMS KW - MCM-41 KW - MESOPOROUS ER - TY - JOUR TI - Equation of State for Lennard-Jones Chains AU - Johnson, J. Karl AU - Mueller, Erich A. AU - Gubbins, Keith E. T2 - The Journal of Physical Chemistry AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEquation of State for Lennard-Jones ChainsJ. Karl Johnson, Erich A. Mueller, and Keith E. GubbinsCite this: J. Phys. Chem. 1994, 98, 25, 6413–6419Publication Date (Print):June 1, 1994Publication History Published online1 May 2002Published inissue 1 June 1994https://doi.org/10.1021/j100076a028Request reuse permissionsArticle Views1395Altmetric-Citations225LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (2 MB) Get e-Alerts DA - 1994/6// PY - 1994/6// DO - 10.1021/j100076a028 VL - 98 IS - 25 SP - 6413-6419 J2 - J. Phys. Chem. LA - en OP - SN - 0022-3654 1541-5740 UR - http://dx.doi.org/10.1021/j100076a028 DB - Crossref ER - TY - JOUR TI - Spectroscopic Data on the Kinetics of Hydrate Formation and Decomposition AU - Koh, Carolyn A. AU - Müller, Erich A. AU - Zollweg, John A. AU - Gubbins, Keith E. AU - Savidge, Jeffrey L. T2 - Annals of the New York Academy of Sciences AB - Annals of the New York Academy of SciencesVolume 715, Issue 1 p. 561-563 Spectroscopic Data on the Kinetics of Hydrate Formation and Decomposition CAROLYN A. KOH, CAROLYN A. KOH Cornell University School of Chemical Engineering Ithaca, New York 14853Search for more papers by this authorERICH A. MÜLLER, ERICH A. MÜLLER Cornell University School of Chemical Engineering Ithaca, New York 14853Search for more papers by this authorJOHN A. ZOLLWEG, JOHN A. ZOLLWEG Cornell University School of Chemical Engineering Ithaca, New York 14853Search for more papers by this authorKEITH E. GUBBINS, KEITH E. GUBBINS Cornell University School of Chemical Engineering Ithaca, New York 14853Search for more papers by this authorJEFFREY L. SAVIDGE, JEFFREY L. SAVIDGE Gas Research Institute Physical Sciences Department Chicago, Illinois 60631Search for more papers by this author CAROLYN A. KOH, CAROLYN A. KOH Cornell University School of Chemical Engineering Ithaca, New York 14853Search for more papers by this authorERICH A. MÜLLER, ERICH A. MÜLLER Cornell University School of Chemical Engineering Ithaca, New York 14853Search for more papers by this authorJOHN A. ZOLLWEG, JOHN A. ZOLLWEG Cornell University School of Chemical Engineering Ithaca, New York 14853Search for more papers by this authorKEITH E. GUBBINS, KEITH E. GUBBINS Cornell University School of Chemical Engineering Ithaca, New York 14853Search for more papers by this authorJEFFREY L. SAVIDGE, JEFFREY L. SAVIDGE Gas Research Institute Physical Sciences Department Chicago, Illinois 60631Search for more papers by this author First published: April 1994 https://doi.org/10.1111/j.1749-6632.1994.tb38887.xCitations: 3AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat No abstract is available for this article.Citing Literature Volume715, Issue1Natural Gas HydratesApril 1994Pages 561-563 RelatedInformation DA - 1994/4// PY - 1994/4// DO - 10.1111/j.1749-6632.1994.tb38887.x VL - 715 IS - 1 Natural Gas H SP - 561-563 J2 - Ann NY Acad Sci LA - en OP - SN - 0077-8923 1749-6632 UR - http://dx.doi.org/10.1111/j.1749-6632.1994.tb38887.x DB - Crossref ER - TY - JOUR TI - Chemical potentials and adsorption isotherms of polymers confined between parallel plates AU - Vega, Lourdes F. AU - Panagiotopoulos, Athanassios Z. AU - Gubbins, Keith E. T2 - Chemical Engineering Science AB - Abstract We present the results of Monte Carlo simulations of chains confined in a very narrow slit, in the limit of strongly attractive walls. Simulations are performed in the canonical ensemble, and the chain increment method of Kumar ( Phys. Rev. Lett. , 66 , 2935, 1991) is applied to obtain the chemical potentials of the polymers in the pore and the bulk. Results are summarized in three groups: conformation of chains inside the pore, chemical potentials of confined polymers and adsorption isotherms. Due to the proximity between the walls and the strong attraction they exert on the polymers, a strong bridging effect is observed. The incremental chemical potential of a chain in the pore becomes independent of chain length for long chains, as seen previously for chains in the bulk. The influence of the pore width on the adsorption behavior is also discussed. DA - 1994/9// PY - 1994/9// DO - 10.1016/0009-2509(94)e0110-c VL - 49 IS - 17 SP - 2921-2929 J2 - Chemical Engineering Science LA - en OP - SN - 0009-2509 UR - http://dx.doi.org/10.1016/0009-2509(94)e0110-c DB - Crossref ER - TY - JOUR TI - Theory of Adsorption of Trace Components AU - Jiang, Shaoyi AU - Gubbins, Keith E. AU - Balbuena, Perla B. T2 - The Journal of Physical Chemistry AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheory of Adsorption of Trace ComponentsShaoyi Jiang, Keith E. Gubbins, and Perla B. BalbuenaCite this: J. Phys. Chem. 1994, 98, 9, 2403–2411Publication Date (Print):March 1, 1994Publication History Published online1 May 2002Published inissue 1 March 1994https://doi.org/10.1021/j100060a030Request reuse permissionsArticle Views176Altmetric-Citations44LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (828 KB) Get e-Alerts DA - 1994/3// PY - 1994/3// DO - 10.1021/j100060a030 VL - 98 IS - 9 SP - 2403-2411 J2 - J. Phys. Chem. LA - en OP - SN - 0022-3654 1541-5740 UR - http://dx.doi.org/10.1021/j100060a030 DB - Crossref ER - TY - JOUR TI - High-Pressure Adsorption of Methane and Ethane in Activated Carbon and Carbon Fibers AU - Jiang, Shaoyi AU - Zollweg, John A. AU - Gubbins, Keith E. T2 - The Journal of Physical Chemistry AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-Pressure Adsorption of Methane and Ethane in Activated Carbon and Carbon FibersShaoyi Jiang, John A. Zollweg, and Keith E. GubbinsCite this: J. Phys. Chem. 1994, 98, 22, 5709–5713Publication Date (Print):June 1, 1994Publication History Published online1 May 2002Published inissue 1 June 1994https://doi.org/10.1021/j100073a023RIGHTS & PERMISSIONSArticle Views636Altmetric-Citations73LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-Alerts DA - 1994/6// PY - 1994/6// DO - 10.1021/j100073a023 VL - 98 IS - 22 SP - 5709-5713 J2 - J. Phys. Chem. LA - en OP - SN - 0022-3654 1541-5740 UR - http://dx.doi.org/10.1021/j100073a023 DB - Crossref ER - TY - JOUR TI - Monte Carlo Implementation on the Connection Machine 2; Water in Graphite Pores AU - Ulberg, Dima E. AU - Gubbins, Keith E. T2 - Molecular Simulation AB - Abstract The implementation of Monte Carlo (Canonical and Grand Canonical Ensembles) codes on the Single Instruction Multi Data parallel supercomputer Connection Machine 2 are discussed and demonstrated. The program was developed for the simulation of water behavior in slit graphite pores in CM FORTRAN. A one dimensional data layout is the most suitable for MC realization on the CM-2. The code performance is compared with the performance of sequential and parallel codes on other computers. Preliminary results of the simulations are reported. DA - 1994/9// PY - 1994/9// DO - 10.1080/08927029408021984 VL - 13 IS - 3 SP - 205-219 J2 - Molecular Simulation LA - en OP - SN - 0892-7022 1029-0435 UR - http://dx.doi.org/10.1080/08927029408021984 DB - Crossref KW - CONNECTION MACHINE-2 KW - ALGORITHM KW - GRAND CANONICAL MONTE-CARLO SIMULATION KW - WATER ADSORPTION KW - GRAPHITE PORE ER - TY - JOUR TI - Reactive canonical Monte Carlo AU - Johnson, J. Karl AU - Panagiotopoulos, Athanassios Z. AU - Gubbins, Keith E. T2 - Molecular Physics AB - A new simulation technique is developed for calculating the properties of chemically reactive and associating (hydrogen bonding, charge transfer) systems. We call this new method reactive canonical Monte Carlo (RCMC). In contrast to previous methods for treating chemical reactions, this algorithm is applicable to reactions involving a change in mole number. Stoichiometrically balanced reactions are attempted in the forward and reverse directions to achieve chemical equilibrium. The transition probabilities do not depend on the chemical potentials or chemical potential differences of any of the components. We also extend RCMC to work in concert with the isothermal-isobaric ensemble for simulating chemical reactions at constant pressure, and with the Gibbs ensemble for simultaneous calculation of phase and chemical equilibria. Association is treated as a chemical reaction in the RCMC formalism. Results are presented for dimerization of simple model associating fluids. In contrast to previous methods, the reactive Gibbs ensemble can be used to calculate phase equilibrium for associating fluids with very strong bonding sites. RCMC simulations are performed for nitric oxide dimerization and results are compared with available experimental data in the liquid phase. Agreement with experiment is excellent. Results for a vapour phase simulation are also in remarkable agreement with estimates based on second virial coefficient data. DA - 1994/2/20/ PY - 1994/2/20/ DO - 10.1080/00268979400100481 VL - 81 IS - 3 SP - 717-733 J2 - Molecular Physics LA - en OP - SN - 0026-8976 1362-3028 UR - http://dx.doi.org/10.1080/00268979400100481 DB - Crossref ER - TY - JOUR TI - Structural properties of mixtures of highly asymmetrical electrolytes and uncharged particles using the hypernetted chain approximation AU - Forciniti, Daniel AU - Hall, Carol K. T2 - The Journal of Chemical Physics AB - We have solved the Ornstein–Zernike equation in the hypernetted chain (HNC) approximation for several mixtures of electrolytes and uncharged hard spheres. The mixtures that we studied range from a simple restricted primitive model plus hard spheres of the same size to highly asymmetric electrolytes plus hard spheres of different sizes. We monitored the radial distribution function and thermodynamic properties. We find that the presence of neutral particles changes the nature of the interaction between the charged particles. We also find a strong correlation between nonelectrostatic and electrostatic contributions to the free energy of the mixtures. Potential applications of this approach to the study of protein solubility in solutions of nonionic polymers are discussed. DA - 1994/5/15/ PY - 1994/5/15/ DO - 10.1063/1.467264 VL - 100 IS - 10 SP - 7553-7566 J2 - The Journal of Chemical Physics LA - en OP - SN - 0021-9606 1089-7690 UR - http://dx.doi.org/10.1063/1.467264 DB - Crossref ER - TY - JOUR TI - Monte Carlo Simulation of Off-Lattice Polymer Chains: Effective Pair Potentials in Dilute Solution AU - Dautenhahn, James AU - Hall, Carol K. T2 - Macromolecules AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMonte Carlo Simulation of Off-Lattice Polymer Chains: Effective Pair Potentials in Dilute SolutionJames Dautenhahn and Carol K. HallCite this: Macromolecules 1994, 27, 19, 5399–5412Publication Date (Print):September 1, 1994Publication History Published online1 May 2002Published inissue 1 September 1994https://doi.org/10.1021/ma00097a021Request reuse permissionsArticle Views692Altmetric-Citations154LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-Alertsclose Get e-Alerts DA - 1994/9// PY - 1994/9// DO - 10.1021/ma00097a021 VL - 27 IS - 19 SP - 5399-5412 J2 - Macromolecules LA - en OP - SN - 0024-9297 1520-5835 UR - http://dx.doi.org/10.1021/ma00097a021 DB - Crossref ER - TY - JOUR TI - Generalized flory equation of state for hard chain—hard monomer mixtures of unequal segment diameter AU - Wichert, John M. AU - Hall, Carol K. T2 - Chemical Engineering Science AB - A generalized Flory equation of state is derived for hard chain—hard monomer mixtures, where the monomer diameter is different from the chain segment diameters. An alternate derivation of the osmotic equation of state for binary mixtures is also presented; the equation is derived by inserting both species simultaneously into the fluid. The alternative osmotic equation of state, combined with the generalized Flory theory, predicts the conformal solution mixing rule when the monomer and chain segments are of the same diameter. Chain insertion probabilities, required in the osmotic equation of state in order to predict thermodynamic properties, are estimated using monomer mixture insertion probabilities based on the equation of state of Mansoori and the generalized Flory theory. An extensive set of hard 4-mer—monomer and hard 8-mer—monomer Monte Carlo simulations have also been performed. Simulation compressibility factors are compared to the new equation of state's predictions; agreement is quite good. DA - 1994/9// PY - 1994/9// DO - 10.1016/0009-2509(94)e0098-b VL - 49 IS - 17 SP - 2793-2804 J2 - Chemical Engineering Science LA - en OP - SN - 0009-2509 UR - http://dx.doi.org/10.1016/0009-2509(94)e0098-b DB - Crossref ER - TY - JOUR TI - Second Virial Coefficient Calculations for Square-Well Chain Molecules AU - Wichert, John M. AU - Hall, Carol K. T2 - Macromolecules AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSecond Virial Coefficient Calculations for Square-Well Chain MoleculesJohn M. Wichert and Carol K. HallCite this: Macromolecules 1994, 27, 10, 2744–2756Publication Date (Print):May 1, 1994Publication History Published online1 May 2002Published inissue 1 May 1994https://doi.org/10.1021/ma00088a015RIGHTS & PERMISSIONSArticle Views276Altmetric-Citations24LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-Alerts Get e-Alerts DA - 1994/5// PY - 1994/5// DO - 10.1021/ma00088a015 VL - 27 IS - 10 SP - 2744-2756 J2 - Macromolecules LA - en OP - SN - 0024-9297 1520-5835 UR - http://dx.doi.org/10.1021/ma00088a015 DB - Crossref ER - TY - JOUR TI - Application of a Modified Generalized Flory Dimer Theory to Normal Alkanes AU - Bokis, Costas P. AU - Donohue, Marc D. AU - Hall, Carol K. T2 - Industrial & Engineering Chemistry Research AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTApplication of a Modified Generalized Flory Dimer Theory to Normal AlkanesCostas P. Bokis, Marc D. Donohue, and Carol K. HallCite this: Ind. Eng. Chem. Res. 1994, 33, 5, 1290–1298Publication Date (Print):May 1, 1994Publication History Published online1 May 2002Published inissue 1 May 1994https://doi.org/10.1021/ie00029a027RIGHTS & PERMISSIONSArticle Views91Altmetric-Citations36LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (970 KB) Get e-Alerts Get e-Alerts DA - 1994/5// PY - 1994/5// DO - 10.1021/ie00029a027 VL - 33 IS - 5 SP - 1290-1298 J2 - Ind. Eng. Chem. Res. LA - en OP - SN - 0888-5885 1520-5045 UR - http://dx.doi.org/10.1021/ie00029a027 DB - Crossref ER - TY - JOUR TI - Second virial coefficients for chain molecules AU - Bokis, Costas P. AU - Donohue, Marc D. AU - Hall, Carol K. T2 - Industrial & Engineering Chemistry Research AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSecond virial coefficients for chain moleculesCostas P. Bokis, Marc D. Donohue, and Carol K. HallCite this: Ind. Eng. Chem. Res. 1994, 33, 1, 146–150Publication Date (Print):January 1, 1994Publication History Published online1 May 2002Published inissue 1 January 1994https://doi.org/10.1021/ie00025a019RIGHTS & PERMISSIONSArticle Views167Altmetric-Citations7LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (500 KB) Get e-Alertsclose Get e-Alerts DA - 1994/1// PY - 1994/1// DO - 10.1021/ie00025a019 VL - 33 IS - 1 SP - 146-150 J2 - Ind. Eng. Chem. Res. LA - en OP - SN - 0888-5885 1520-5045 UR - http://dx.doi.org/10.1021/ie00025a019 DB - Crossref ER - TY - CHAP TI - Concentrations in PECVD of Diamondlike Carbon Using Molecular-Beam Mass Spectrometry AU - Graff, I.B. AU - Pugliese, R.A., Jr. AU - Westmoreland, P.R. T2 - Gas-Phase and Surface Chemistry in Electronic Materials Processing A2 - Mountziaris, T.J. A2 - Westmoreland, P.R. A2 - Paz-Pujalt, G. A2 - Smith, F.T.J. PY - 1994/// VL - 334 SP - 129–134 PB - Materials Research Society ER - TY - JOUR TI - Fluoromethane chemistry and its role in flame suppression AU - Westmoreland, Phillip R. AU - Burgess, Donald R.F., Jr. AU - Zachariah, Michael R. AU - Tsang, Wing T2 - Symposium (International) on Combustion AB - A detailed reaction set is composed for fluoromethanes in flames, and the competing roles of suppression chemistry, oxidation chemistry, and heat capacity are analyzed. The set is constructed using (1) thermochemistry from the literature, from group additivity, and from BAC-MP4 ab initio-based calculations and (2) kinetics from the literature, from simple analogies, from thermochemical kinetics, from BAC-MP4 transition-state calculations, and from Quantum-RRK and RRKM/Master Equation calculations. Structures of freely propagating laminar flames are then predicted and analyzed. A 6.4% CH4/air flame(equivalence ratio 0.65) is the base case with dopant CF4, CHF3, CH2F2, or CH4 to make up 1 ppm to 2 mol% of the feed. CF4, which proves to be inert, slows the adiabatic flame speed and reduces the adiabatic flame temperature by dilution and its heat capacity. CHF3 causes chemical suppression effects, slowing adiabatic flame speed below that with CF4, despite increasing adiabatic flame temperature. Adding CH2F2, CH3F, or CH4 increases both flame speed and temperature. The chemical cause is competition between chain termination, primarily by chemically activated HFelimination, and chain propagation by normal oxidation pathways. Like methane, fluoromethane flame chemistry is dominated by abstraction and by chemically activated reactions. However, abstraction of H is greatly favored over abstraction of F, due to the higher bond strength of C−F, and chemically activated species containing H and F can rapidly eliminate HF. Thus, OH+CH3→CH3OHo slowly forms CH3OH by third-body stabilization, but OH+CF3→CF3OHo goes rapidly to CF2O+HF. Slow destruction of CF2O formed by this reaction and by CF3+O helps suppress the CHF3-doped flame, but CH2F2 and CH3F are accelerants because they are oxidized easily. DA - 1994/1// PY - 1994/1// DO - 10.1016/s0082-0784(06)80795-2 VL - 25 IS - 1 SP - 1505-1511 J2 - Symposium (International) on Combustion LA - en OP - SN - 0082-0784 UR - http://dx.doi.org/10.1016/s0082-0784(06)80795-2 DB - Crossref ER - TY - JOUR TI - Effects of Toluene and Benzoic Acid on the Kinetics of Ferrous Oxidation on Pt and Nafion-Coated Pt Electrodes AU - Ye, Jian-Hui AU - Fedkiw, Peter S. T2 - Journal of The Electrochemical Society AB - The electrochemical kinetics of Fe2+ oxidation to Fe3+ have been investigated by cyclic and ring disk electrode voltammetry in the absence and presence of the contaminants toluene (7 mM, saturated solution) or benzoic acid (16 mM) in 1M electrolyte on (i) smooth Pt electrodes, (ii) Nafion‐coated smooth Pt electrodes, and (iii) Pt electrodes electrodeposited within a Nafion film coated onto a glassy carbon (GC) substrate. On uncoated Pt, the kinetics are adversely affected by these two organics: both the anodic transfer coefficient and the apparent standard rate constant are decreased. A 3.7 μm Nafion coating, however, effectively buffers the smooth Pt electrode from toluene, but, nevertheless, benzoic acid still affects the reaction rate. In contrast, the transfer coefficient and rate constant for Fe2+ oxidation on the Pt/Nafion/GC electrode are esseentially unaffected by either toluene or benzoic acid. Qualitative features of the voltammograms also indicate that the Nafion film protects the Pt from contamination by these aromatics: two current plateaus are observed using an uncoated Pt electrode in the presence of toluene or benzoic acid with a ratio which increases with rotation rate; with the Nafion coating on a smooth Pt electrode and in the presence of toluene, however, there is only one current plateau; in the presence of benzoic acid, two current plateaus remain, but the ratio is nearer unity and less sensitive to rotation rate. In contrast, only a single plateau current is observed using the Pt/Nafion/GC electrode. The Nafion coating is apparently an effective buffer layer against these two aromatics, but concurrently affects a decrease in the mass‐transfer limited current due to the diffusional resistance of the film. DA - 1994/// PY - 1994/// DO - 10.1149/1.2054950 VL - 141 IS - 6 SP - 1483 SN - 0013-4651 UR - http://dx.doi.org/10.1149/1.2054950 ER - TY - JOUR TI - Optimal time-varying cell-voltage control of a parallel-plate reactor AU - Bakshi, R. AU - Fedkiw, P.S. T2 - Journal of Applied Electrochemistry DA - 1994/11// PY - 1994/11// DO - 10.1007/bf00241309 VL - 24 IS - 11 J2 - J Appl Electrochem LA - en OP - SN - 0021-891X 1572-8838 UR - http://dx.doi.org/10.1007/bf00241309 DB - Crossref ER - TY - JOUR TI - Formation of two-dimensional structures from colloidal particles on fluorinated oil substrate AU - Lazarov, G.S. AU - Denkov, N.D. AU - Velev, O.D. AU - Kralchevsky, P.A. AU - Nagayama, K. T2 - Journal of the Chemical Society, Faraday Transactions AB - We propose a new type of liquid substrate, perfluorinated oil (F-oil), for the formation of two-dimensional arrays from colloidal particles. The appropriate conditions for particle ordering (experimental cell, type and concentration of surfactants, etc.) are reported. Large and well ordered structures from µm-sized latex particles are obtained. Ordered clusters of globular protein (ferritin) macromolecules are also observed. The structures formed are directly transferred (after the F-oil evaporation) onto a solid substrate for subsequent study by means of optical and electron microscopy. The mechanism of the ordering process is studied and the advantages and disadvantages of the liquid substrates (in comparison with the solid ones) are discussed. Some possible ways for control of the ordering process and for improvement of the quality of the arrays are pointed out. DA - 1994/// PY - 1994/// DO - 10.1039/FT9949002077 VL - 90 IS - 14 SP - 2077-2083 UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-5544328419&partnerID=MN8TOARS ER - TY - JOUR TI - Formation of two-dimensional colloid crystals in liquid films under the action of capillary forces AU - Kralchevsky, P.A. AU - Denkov, N.D. AU - Paunov, V.N. AU - Velev, O.D. AU - Ivanov, I.B. AU - Yoshimura, H. AU - Nagayama, K. T2 - Journal of Physics: Condensed Matter AB - When two similar small particles are attached to a liquid interface they attract each other due to a lateral capillary force. This force appears because the gravitational potential energy of the floating particles decreases when they are approaching each other. This force is proportional to R6 (R is the particle radius), so it decreases very fast with particle size and becomes negligible for R<10 mu m. We found that the situation is quite different when the particles (instead of being freely floating) are partially immersed in a liquid layer on a substrate. In this case the energy of capillary attraction is proportional to R2 and turns out to be much larger than kT even with particles of diameter about 10 nm. The effect is related to the particle three-phase contact angle, i.e. to the intermolecular forces, rather than to gravity. The experiments show that the lateral capillary forces can bring about the formation of a two-dimensional array (2D-crystal) from both micrometre-size and submicrometre particles: latex spheres, protein globules, etc. DA - 1994/// PY - 1994/// DO - 10.1088/0953-8984/6/23A/065 VL - 6 IS - 23A UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-0028766442&partnerID=MN8TOARS ER - TY - JOUR TI - Experimental investigations on model emulsion systems stabilized with non-ionic surfactant blends AU - Velev, O.D. AU - Gurkov, T.D. AU - Chakarova, Sv.K. AU - Dimitrova, B.I. AU - Ivanov, I.B. AU - Borwankar, R.P. T2 - Colloids and Surfaces A: Physicochemical and Engineering Aspects AB - We have performed experimental research into model oil-in-water emulsion systems stabilized with non-ionic surfactant blends: thin aqueous films between oil phases and oil drops coalescing against their homophase. Xylene was chosen as the oil phase, and Tween 20 and Span 20, alone or in mixtures at different molar ratios, were used as stabilizers. The roles of the surfactant mole ratio, the electrolyte concentration and pH were studied. It was shown that there is considerable electrostatic repulsion within the aqueous films. The results obtained on thin film stability and on drop lifetime at constant electrolyte concentration indicate that Tween 20 (when present) is the emulsifier that predominantly determines the stability of the systems. This conclusion can be related to the higher surface activity and higher adsorption of Tween as deducted from interfacial tension data. Some evidence of synergism was observed only at an electrolyte concentration of 10−3 M (NaCl). We also carried out stability tests on shaken and homogenized batch emulsion systems and the results show good correlation with the data from the model investigations. DA - 1994/// PY - 1994/// DO - 10.1016/0927-7757(93)02639-V VL - 83 IS - 1 SP - 43-55 UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-0037963852&partnerID=MN8TOARS KW - EMULSIFIER BLENDS KW - EMULSION STABILITY KW - MIXED SURFACTANTS KW - NONIONIC SURFACTANTS KW - THIN LIQUID FILMS ER - TY - JOUR TI - Capillary image forces. II. Experiment AU - Velev, Orlin D. AU - Denkov, Nikolai D. AU - Paunov, Vesselin N. AU - Kralchevsky, Peter A. AU - Nagayama, Kuniaki T2 - Journal of Colloid and Interface Science AB - The capillary meniscus interaction between a floating submillimeter particle and a vertical wall is experimentally studied. It is proven that the interplay of the capillary image force from one side and the gravity and buoyancy forces from the other side can lead to the appearance of a stable equilibrium position of the particle at a finite distance from the wall. The dependence of the equilibrium separation on the particle size, three-phase contact angle, and other parameters is investigated and compared with the theory developed in the first part of this study. The agreement between the experimental results and the theoretical predictions is very good. A simple method for determination of the three-phase contact angle of millimeter- and submillimeter-size particles, floating attached to a fluid interface, is described. DA - 1994/// PY - 1994/// DO - 10.1006/jcis.1994.1333 VL - 167 IS - 1 SP - 66-73 UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-0028516242&partnerID=MN8TOARS ER - TY - JOUR TI - THE TORSION ROTATIONAL SPECTRAL STRUCTURE OF ETHANOL MOLECULES ADSORBED ON POLYCRYSTALLINE SILVER SUBSTRATE AU - WANG, ZY AU - NG, CF AU - LIM, PK AU - LEUNG, HW AU - WU, JG AU - CHEN, HF T2 - JOURNAL OF PHYSICS-CONDENSED MATTER AB - A laser photoacoustic spectrometer (LPAS) using a branch-tunable carbon dioxide laser source and a piezoelectric transducer as a detector was employed to study the adsorption of ethanol on a polycrystalline silver surface at 108 K. The strength of bonding between adsorbate and substrate was found to lie between physisorption and chemisorption according to the values of heat of adsorption (33.2 kJ mol-1, 38.8 kJ mol-1, 39.5 W mol-1 and 44.2 kJ mol-1 obtained by thermal-desorption spectroscopy). A fine spectral structure of seven peaks was obtained in the region of 1045-1054 cm-1, which bears striking resemblance to that obtained by Fourier-transform infrared spectroscopy for gaseous ethanol. Taking into consideration the results of the thermal-desorption study, which suggests weak bonding between ethanol and the silver surface, this fine spectral structure was attributed to the internal torsional rotation of the ethanol adsorbates. To our knowledge, this work is the first report on a torsional-rotational fine spectral structure of ethanol adsorbate on a silver surface. Thus our findings show that torsional-rotational structure exists not only in free molecules as in the gas phase, but also in the adsorbate phase. The set-up used in this experiment was capable of providing 1 cm-1 fine spectral resolution at 1 L exposure sensitivity. The LPAS technique developed here has potential for studying other systems as well. DA - 1994/9/5/ PY - 1994/9/5/ DO - 10.1088/0953-8984/6/36/005 VL - 6 IS - 36 SP - 7207-7215 SN - 0953-8984 ER - TY - JOUR TI - Stimulation of berberine secretion and growth in cell cultures of Thalictrum minus AU - Smolko, D. D. AU - Peretti, S. W. T2 - Plant Cell Reports DA - 1994/// PY - 1994/// DO - 10.1007/bf00233776 VL - 14 IS - 2/3 SP - 131-136 ER - TY - JOUR TI - IMPROVED HYDROGEN AND DEUTERIUM DEPTH PROFILING IN POLYMERS USING LOW-ENERGY FORWARD RECOIL SPECTROMETRY AU - GENZER, J AU - ROTHMAN, JB AU - COMPOSTO, RJ T2 - NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS AB - We demonstrate that the hydrogen and deuterium depth resolution of forward recoil spectrometry (FRES) is greatly improved by utilizing 1.3 MeV 4He ions and sample tilting. The near-surface depth resolution is measured on samples of alternating deuterated and protonated polystyrene layers, each ca 250 Å thick. The depth resolution at the surface is dramatically improved (from 800 Å to 250 Å) as the incident beam energy decreases from 3.0 to 1.3 MeV. We call this technique low-energy FRES (LE-FRES) to differentiate it from standard FRES, which uses 3 MeV 4He ions incident at θ = 75°. Furthermore, by using a glancing incident or exit geometry, the LE-FRES depth resolution is improved to ca 125 Å, which is comparable to the resolution of secondary ion mass spectrometry and nuclear reaction analysis. Measurements of the energy and glancing angle dependence of the depth resolution are in quantitative agreement with theoretical predictions. The probing depth of LE-FRES is found to have a maximum at θ ≈ 71° and decreases at glancing exit and incident angles. A contour plot illustrates the relationship between depth resolution and probing depth and provides guidance for future users of LE-FRES. DA - 1994/4// PY - 1994/4// DO - 10.1016/0168-583x(94)95300-7 VL - 86 IS - 3-4 SP - 345-354 SN - 0168-583X ER - TY - JOUR TI - EFFECTS OF MEDIUM CARBON-TO-NITROGEN RATIO ON BIOFILM FORMATION AND PLASMID STABILITY AU - HUANG, CT AU - PERETTI, SW AU - BRYERS, JD T2 - BIOTECHNOLOGY AND BIOENGINEERING AB - Abstract Biofilm formation and plasmid segregational instability in biofilm cultures of Escherichia coli DH5α (pMJR1750) were investigated under different medium‐carbon‐to‐nitrogen (C/N) ratios. At C/N ratios of 0.07 and 1, net accumulation of both biofilm plasmid‐bearing and plasmid‐free cells continued through the entire experiment without attaining any apparent steady state. At C/N ratios of 5 and 10, net biofilm cell accumulation for the two populations reached apparent steady states after 84 and 72 h, respectively. At C/N ratios of 0.07 and 1, polysaccharide production increased slowly and reached about 2g alginate equivalent/cm 2 by the end of both experiments. At a C/N ratio of 5, polysaccharide increase significantly after 84 h, reaching about 7μg alginate equivalent/cm 2 prior to termination. At a C/N ratio of 10, polysaccharide increased significantly after 72 h and reached 21 μg alginate equivalent/cm 2 at 108 h. At C/N ratios of 0.07 and 1, protein production reached 6.5 and 4 μg/cm 2 , respectively. At C/N ratios of 5 and 10, protein production increased slightly for the first 84 h and reached a maximum at 108 h, at 3 and 2 μg/cm 2 , respectively, then decreased over the last 12 h of the experiment. Ratios of polysaccharide to protein increased with increasing C/N ratios. At C/N ratios of 0.07 and 1, the ratios between extracellular polysaccharide (EP) and protein were no more than 205 μg polysaccharide/μg protein, whereas those at C/N ratios of 5 and 10 increased to about 7 and 12 μg polysaccharide/μg protein, respectively. Probabilities of plasmid loss in the biofilm cultures increased with increasing C/N ratios. At C/N ratios of 0.07, 1, and 5, the probabilities of plasmid loss were 0.0013 ± 0.011, 0.020 ± 0.006 and 0.122 ± 0.021, respectively. At a C/N ratio of 10, the probability of plasmid loss was significantly higher, reaching 0.38 ± 0.125. The increase of probability of plasmid loss at higher C/N ratios results from competition between cell replication and extracellular polysaccharide production. © 1994 John Wiley & Sons, Inc. DA - 1994/7// PY - 1994/7// DO - 10.1002/bit.260440310 VL - 44 IS - 3 SP - 329-336 SN - 1097-0290 KW - BIOFILM FORMATION KW - ESCHERICHIA COLI KW - C/N RATIO KW - PLASMID RETENTION KW - EXTRACELLULAR POLYSACCHARIDE ER - TY - JOUR TI - EFFECTS OF INDUCER LEVELS ON A RECOMBINANT BACTERIAL BIOFILM FORMATION AND GENE-EXPRESSION AU - HUANG, CT AU - PERETTI, SW AU - BRYERS, JD T2 - BIOTECHNOLOGY LETTERS DA - 1994/9// PY - 1994/9// DO - 10.1007/bf00128622 VL - 16 IS - 9 SP - 903-908 SN - 0141-5492 ER - TY - JOUR TI - On the kinetics of vinyl + O2 AU - Westmoreland, P. R. AU - Hennessey, D. J. T2 - Chemical and Physical Processes in Combustion DA - 1994/// PY - 1994/// SP - 425-428 ER - TY - JOUR TI - Reduced Kinetic Mechanisms for applications in combustion systems by N. Peters and B. Rogg AU - Westmoreland, Phillip T2 - AIChE Journal AB - AIChE JournalVolume 40, Issue 11 p. 1926-1927 Book Review Reduced kinetic mechanisms for applications in combustion systems. Edited by N. Peters and B. Rogg, Spring-Verlag, New York, Lecture Notes in Physics, Monograph 15, 1993, 360 pp. Phillip R. Westmoreland, Phillip R. Westmoreland Dept. fo Chemical Engineering, University of Massachusetts at Amherst, Amherst, MA 01003Search for more papers by this author Phillip R. Westmoreland, Phillip R. Westmoreland Dept. fo Chemical Engineering, University of Massachusetts at Amherst, Amherst, MA 01003Search for more papers by this author First published: November 1994 https://doi.org/10.1002/aic.690401122AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume40, Issue11November 1994Pages 1926-1927 RelatedInformation DA - 1994/// PY - 1994/// DO - 10.1002/aic.690401122 VL - 40 IS - 11 SP - 1926–1927 ER - TY - JOUR TI - PLATINUM-MORDENITE CATALYSTS FOR N-HEXANE ISOMERIZATION - CHARACTERIZATION BY X-RAY-ABSORPTION SPECTROSCOPY AND CHEMICAL PROBES AU - OTTEN, MM AU - CLAYTON, MJ AU - LAMB, HH T2 - JOURNAL OF CATALYSIS AB - Platinum-mordenite (Pt-MOR) catalysts were prepared from NH4-MOR by ion exchange with [PtII(NH3)4][OH]2, calcination in O2 at 350°C, and reduction in H2 at 350°C. The resultant Pt-H-MOR was active for n-hexane isomerization and hydrocracking via bifunctional catalysis at 240-300°C and 1 atm. The observed activation energies for C6 branched-isomer formation are unusually low, suggesting that the isomerization rates were controlled by pore diffusion. A Pt-KH-MOR catalyst was prepared by ion exchange with aqueous KNO3 and re-reduction at 350°C; elemental analysis evidenced 90% exchange of protons for K+ ions. The product distribution and observed activation energies for C6 branched-isomer formation over Pt-KH-MOR are consistent with n-hexane isomerization via bifunctional catalysis. Hydrocracking was strongly suppressed, and light hydrocarbons were formed primarily by Pt-catalyzed hydrogenolysis. From in situ extended X-ray absorption fine structure spectroscopy and H2 temperature-programmed desorption, we conclude that the Pt-MOR catalysts consist of small Pt clusters hosted within the mordenite crystals. The Pt LIII X-ray absorption near-edge structure (XANES) spectra of Pt-H-MOR and Pt-KH-MOR are closely similar, suggesting that the electronic structure of the Pt clusters is unaffected by mordenite acid-base chemistry. For the freshly reduced catalysts, a XANES feature at 10 eV relative energy is assigned to Pt-H antibonding states. The infrared spectrum of CO adsorbed on Pt-H-MOR contains an intense band at 2084 cm−1, which is assigned to linear CO moieties on Pt clusters. A small peak at 2124 cm−1 is assigned to isolated PtI-CO species, which we infer are formed by oxidative fragmentation of Pt clusters. The infrared spectrum of CO adsorbed on Pt-KH-MOR evidences a red shift of the linear CO band, which we suggest is due to electrostatic interactions between carbonyl O atoms and nearby K+ ions. DA - 1994/9// PY - 1994/9// DO - 10.1006/jcat.1994.1287 VL - 149 IS - 1 SP - 211-222 SN - 0021-9517 ER - TY - PAT TI - Direct Calcium Magnesium Acetate Production AU - Flickinger, M.C. AU - Hanson, R.S. AU - Schendel, F.J. AU - Anderson, C.R. AU - August, P.R. C2 - 1994/// DA - 1994/// PY - 1994/// ER - TY - JOUR TI - C-BONDED AND O-BONDED CARBON-MONOXIDE ON SURFACES - INTERACTIONS OF [CPW(CO)(3)](-) WITH CATIONS ON MAGNESIA, ALUMINA, AND POTASSIUM-MODIFIED ALUMINA AU - OTTEN, MM AU - LAMB, HH T2 - JOURNAL OF THE AMERICAN CHEMICAL SOCIETY AB - ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTC- and O-Bonded Carbon Monoxide on Surfaces: Interactions of [CpW(CO)3]- with Cations on Magnesia, Alumina, and Potassium-Modified AluminaMark M. Otten and H. Henry LambCite this: J. Am. Chem. Soc. 1994, 116, 4, 1372–1381Publication Date (Print):February 1, 1994Publication History Published online1 May 2002Published inissue 1 February 1994https://doi.org/10.1021/ja00083a024Request reuse permissionsArticle Views91Altmetric-Citations13LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. 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Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (2 MB) Get e-Alertsclose Get e-Alerts DA - 1994/2/23/ PY - 1994/2/23/ DO - 10.1021/ja00083a024 VL - 116 IS - 4 SP - 1372-1381 SN - 0002-7863 ER - TY - JOUR TI - PHOTODEGRADATION OF TCDD IN SOIL CONTAINING ORGANIC-SOLVENTS AU - ZHONG, YP AU - OVERCASH, MR AU - MCPETERS, AL T2 - ENVIRONMENTAL GEOCHEMISTRY AND HEALTH DA - 1994/12// PY - 1994/12// DO - 10.1007/BF01747921 VL - 16 IS - 3-4 SP - 235-240 SN - 0269-4042 ER - TY - JOUR TI - METABOLISM IN HYPERTHERMOPHILIC MICROORGANISMS AU - KELLY, RM AU - ADAMS, MWW T2 - ANTONIE VAN LEEUWENHOEK INTERNATIONAL JOURNAL OF GENERAL AND MOLECULAR MICROBIOLOGY DA - 1994/// PY - 1994/// DO - 10.1007/BF00871643 VL - 66 IS - 1-3 SP - 247-270 SN - 0003-6072 KW - ARCHAEA KW - HYPERTHERMOPHILES KW - PROTEOLYTIC KW - SACCHAROLYTIC KW - SULFUR ER - TY - JOUR TI - Plant growth response to Olestra as related to beneficial use of municipal sludge AU - Overcash, M. R. AU - Versteeg, D. J. AU - Koerwer, J. AU - Li, Y. AU - Li, P. T2 - Archives of Environmental Contamination and Toxicology DA - 1994/// PY - 1994/// VL - 26 IS - 3 SP - 408 ER -