2023 article
An <i>S</i>=1 Iron(IV) Intermediate Revealed in a Non-Heme Iron Enzyme-Catalyzed Oxidative C-S Bond Formation
Paris, J. C., Hu, S., Wen, A., Weitz, A. C., Cheng, R., Gee, L. B., … Guo, Y. (2023, September 13). ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
author keywords: Ergothioneine; Ferryl Intermediates; High-Valent Iron; Ovothiol A; Oxidative C-S Bond Formation
TL;DR:
The identification and characterization of a kinetically competent S = 1 iron(IV) intermediate supported by a four-histidine ligand environment in enabling C-S bond formation in OvoA from Methyloversatilis thermotoleran, which represents the first experimentally observed intermediate spin iron( IV) species in non-heme iron enzymes.
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doi.org (publisher)
UN Sustainable Development Goal Categories
3. Good Health and Well-being
(Web of Science)
Source: Web Of Science
Added: October 10, 2023
Abstract