2023 journal article

<i>In situ</i> Stress Monitoring Reveals Tension and Wrinkling Evolutions during Halide Perovskite Film Formation

ACS ENERGY LETTERS, 9(1), 75–84.

By: B. Guo n, M. Chauhan n, N. Woodward n, G. McAndrews, G. Thapa n, B. Lefler n, R. Li*, T. Wang n ...

Source: Web Of Science
Added: February 12, 2024

Metal halide perovskites (MHPs) are promising candidates for next-generation thin film photovoltaics and high-performance tandems. Solution-processed MHP films are susceptible to residual stress that can induce undesirable surface wrinkles. However, the origins and evolution of stress during solution processing remain elusive. In this work, we utilize multimodal in situ characterizations, including substrate curvature, reflectance, absorbance, and photoluminescence, to monitor stress and morphology evolution during MHP film formation. A film formation model emerges, consisting of a perovskite top crust on a semirigid sol with the ability to transfer mechanical forces. The phase transformation induces tension in the MHP crust, while shrinkage of the sol causes additional compression and surface wrinkles. Wrinkle-free films are formed through dynamically balancing forces between the crust and the sol. This study provides a powerful toolkit for the fast-growing area of stress engineering in MHP photovoltaics to achieve dynamic control of film stress and surface morphology.