Photodriven Elimination of Chlorine From Germanium and Platinum in a Dinuclear Pt-II -> Ge-IV Complex
Karimi, M., Tabei, E. S., Fayad, R., Saber, M. R., Danilov, E. O., Jones, C., … Gabbai, F. P. (2021, September 8). ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
author keywords: charge-transfer complexes; chlorine radicals; germanium; photochemistry; platinum
TL;DR:
Studying the photochemistry of newly isolated isomeric complexes shows that, in the presence of a chlorine trap, both isomers convert cleanly into the platinum germyl complex, a rare example of a light induced transition metal-main group element bond forming process.
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Source: Web Of Science
Added: September 20, 2021