The Effect of Fluorinated Solvents on the Physicochemical Properties, Ionic Association, and Free Volume of a Prototypical Solvate Ionic Liquid
Burba, C. M., Feightner, K., Liu, M., & Hawari, A. (2022, January 21). CHEMPHYSCHEM.
author keywords: density functional calculations; ionic conductivity; perfluorinated solvents; solvate ionic liquids; vibrational spectroscopy
TL;DR:
This work explores solvent fluorination for a prototypical SIL based on lithium bis(trifluoromethylsulfonyl)imide and triethylene glycol and suggests FTEG does not readily coordinate Li+ ; a conclusion that is reinforced by computational studies of [(TEG)1Li]+ and [(FTEG) 1Li]+ cation stabilities.
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