@article{narayanan_chung_aguda_boy_hartman_mehraban_gupta_tonelli_2016, title={Correlation of the stoichiometries of poly-(epsilon-caprolactone) and alpha-cyclodextrin pseudorotaxanes with their solution rheology and the molecular orientation, crystallite size, and thermomechanical properties of their nanofibers}, volume={6}, ISSN={["2046-2069"]}, DOI={10.1039/c6ra23536k}, abstractNote={Pseudorotaxane nanofibers based on biomedical polymers, such as poly(ε-caprolactone) (PCL), and α-cyclodextrins (α-CD) open new horizons for a variety of biomedical applications.}, number={112}, journal={RSC ADVANCES}, publisher={Royal Society of Chemistry (RSC)}, author={Narayanan, Ganesh and Chung, Ching-Chang and Aguda, Remil and Boy, Ramiz and Hartman, Matthew and Mehraban, Nahid and Gupta, Bhupender S. and Tonelli, Alan E.}, year={2016}, pages={111326–111336} }
 @article{narayanan_aguda_hartman_chung_boy_gupta_tonelli_2016, title={Fabrication and Characterization of Poly(epsilon-caprolactone)/alpha-Cyclodextrin Pseudorotaxane Nanofibers}, volume={17}, ISSN={["1526-4602"]}, DOI={10.1021/acs.biomac.5b01379}, abstractNote={Multifunctional scaffolds comprising neat poly(ε-caprolactone) (PCL) and α-cyclodextrin pseudorotaxanated in α-cyclodextrin form have been fabricated using a conventional electrospinning process. Thorough in-depth characterizations were performed on the pseudorotaxane nanofibers prepared from chloroform (CFM) and CFM/dimethylformamide (DMF) utilizing scanning electron microscopy (SEM), transmission electron microscopy (TEM), rheology, differential scanning calorimetry (DSC), thermogravimetric analyses (TGA), wide-angle X-ray diffraction (WAXD), and Instron tensile testing. The results indicate the nanofibers obtained from chloroform retain the rotaxanated structure; while those obtained from CFM/DMF had significantly dethreaded during electrospinning. As a consequence, the nanowebs obtained from CFM showed higher moduli and lower elongations at break compared to neat PCL nanowebs and PCL/α-CD nanowebs electrospun from CFM/DMF.}, number={1}, journal={BIOMACROMOLECULES}, publisher={American Chemical Society (ACS)}, author={Narayanan, Ganesh and Aguda, Remil and Hartman, Matthew and Chung, Ching-Chang and Boy, Ramiz and Gupta, Bhupender S. and Tonelli, Alan E.}, year={2016}, month={Jan}, pages={271–279} }
 @article{tombokan_aguda_danehower_kilpatrick_carbonell_2008, title={Three-component phase behavior of the sclareol-ethyl lactate-carbon dioxide system for GAS applications}, volume={45}, ISSN={["0896-8446"]}, DOI={10.1016/j.supflu.2007.12.007}, abstractNote={This paper focuses on the extraction of sclareol from the leaves of Salvia sclarea Lamiaceae, more commonly known as Clary sage. The process involves the extraction of sclareol using a CO2-soluble GRAS solvent such as ethyl lactate, followed by GAS anti-solvent precipitation from ethyl lactate solution with carbon dioxide. The three-component phase behavior of the sclareol–ethyl lactate–CO2 system at various pressures has been determined and indicates a slight cybotactic effect. The ability of thermodynamic models to predict the complex three-component phase behavior of this system is discussed, together with the implications of the thermodynamic behavior of the system on process design.}, number={2}, journal={JOURNAL OF SUPERCRITICAL FLUIDS}, author={Tombokan, Xenia C. and Aguda, Remil M. and Danehower, David A. and Kilpatrick, Peter K. and Carbonell, Ruben G.}, year={2008}, month={Jun}, pages={146–155} }