@article{mauk_unrath_blankenship_1990, title={DEVELOPMENT OF A STRONG CATION-EXCHANGE METHOD FOR PURIFICATION AND HPLC ASSAY OF GIBBERELLIN-STEROL INHIBITORS IN PLANT-TISSUE}, volume={28}, ISSN={["0021-9665"]}, DOI={10.1093/chromsci/28.12.621}, abstractNote={An enhanced purification method is developed for the gibberellin-sterol inhibitor, paclobutrazol (PP333; [(2RS,3RS)- 1-(4-chlorophenyl)-4,4-dimethyl-2-(1,2,4 triazol-1-yl) pentan-3-ol]), utilizing solid-phase, strong cation exchange (SCX) chromatography. Exogenous paclobutrazol is derived from treated apple foliage (Malus domestica Borkh.) and quantitated by C18 reverse-phase high-performance liquid chromatography (HPLC) following sample purification on C18 and SCX sorbents. Several methods are evaluated for the elution of paclobutrazol from an SCX column including counter ions (Ba, Ca, Na) with and without acetonitrile. The optimum elution system is ammoniacal—methanol at 60:40 (v/v). Addition of the SCX sorbent purification step in paclobutrazol analysis results in a high recovery rate and substantial degree of purity which easily facilitates separation and quantitation by HPLC.}, number={12}, journal={JOURNAL OF CHROMATOGRAPHIC SCIENCE}, author={MAUK, CS and UNRATH, CR and BLANKENSHIP, SM}, year={1990}, month={Dec}, pages={621–623} } @article{mauk_unrath_blankenship_lehman_1990, title={INFLUENCE OF METHOD OF APPLICATION OF PACLOBUTRAZOL ON SOIL RESIDUES AND GROWTH-RETARDATION IN A STARKRIMSON-DELICIOUS APPLE ORCHARD}, volume={9}, ISSN={["0167-6903"]}, DOI={10.1007/BF00025276}, number={1}, journal={PLANT GROWTH REGULATION}, author={MAUK, CS and UNRATH, CR and BLANKENSHIP, SM and LEHMAN, LJ}, year={1990}, month={Feb}, pages={27–35} } @article{mauk_unrath_blankenship_1990, title={Rapid quantitative analysis of a gibberellin-sterol inhibitor using high-performance liquid chromatographic cartridge columns}, volume={9}, DOI={10.1007/BF02041959}, number={3}, journal={Journal of Plant Growth Regulation}, author={Mauk, C. S. and Unrath, C. R. and Blankenship, S. M.}, year={1990}, pages={181} } @article{mauk_unrath_blankenship_yelenosky_1989, title={Improved chemical analysis of exogenously-applied 1,2,4-triazoles [paclobutrazol] derived from apple tree tissues and soil residues}, number={239}, journal={Acta Horticulturae}, author={Mauk, C. S. and Unrath, C. R. and Blankenship, S. M. and Yelenosky, G.}, year={1989}, pages={77} }