2009 journal article

Synthesis of Oxorhenium(V) Complexes with Diamido Amine Ancillary Ligands and Their Role in Oxygen Atom Transfer Catalysis

INORGANIC CHEMISTRY, 48(23), 11058–11066.

By: Y. Feng n, J. Aponte n, P. Houseworth n, P. Boyle n & E. Ison n

MeSH headings : Amines / chemistry; Catalysis; Crystallography, X-Ray; Ligands; Models, Molecular; Molecular Structure; Organometallic Compounds / chemical synthesis; Organometallic Compounds / chemistry; Oxygen / chemistry; Rhenium / chemistry; Stereoisomerism
TL;DR: Although the Re(VII) intermediate could not be isolated, its activity in OAT reactions was probed by competition experiments with PPh(3) and four para-substituted triarylphosphines, suggesting that the OAT reaction in these five-coordinate complexes appears to be governed by isomerization of the starting complex. (via Semantic Scholar)
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Added: August 6, 2018

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