@article{aykut_2013, title={Electrospun MgO-loaded carbon nanofibers: Enhanced field electron emission from the fibers in vacuum}, volume={74}, number={2}, journal={Journal of Physics and Chemistry of Solids}, author={Aykut, Y.}, year={2013}, pages={328–337} } @article{aykut_pourdeyhimi_khan_2013, title={Synthesis and characterization of silver/lithium cobalt oxide (Ag/LiCoO2) nanofibers via sol-gel electrospinning}, volume={74}, ISSN={["1879-2553"]}, DOI={10.1016/j.jpcs.2013.05.021}, abstractNote={We report on the preparation and characterization of Ag/LiCoO2 nanofibers (NFs) via the sol–gel electrospinning (ES) technique. Ag nanoparticles (NPs) were produced in an aqueous polyvinyl pyrrolidone (PVP) solution by using AgNO3 precursor. A viscous lithium acetate/cobalt acetate/polyvinylalcohol/water (LiAc/(CoAc)2/PVA/water) solution was prepared separately. A Ag NPs/PVP/water solution was prepared and added to this viscous solution and magnetically stirred to obtain the final homogeneous electrospinning solution. After establishing the proper electrospinning conditions, as-spun precursor Ag/LiAc/Co(Ac)2/PVA/PVP NFs were formed and calcined in air at a temperature of 600 °C for 3 h to form well-crystallized porous Ag/LiCoO2 NFs. Various analytical characterization techniques such as UV–vis, SEM, TEM, TGA, XRD, and XPS were performed to analyze Ag NPs, as-spun and calcined NFs. It was established that Ag NPs in the precursor Ag/LiAc/Co(Ac)2/PVA/PVP NFs are highly self-aligned as a result of the behavior of Ag in the electric field of the electrospinning setup and the interaction of Ag ions with Li and Co ions in the NF. Ag/LiCoO2 NFs exhibit a nanoporous structure compared with un-doped LiCoO2 NFs because the atomic radius of Ag is larger than the radius of Co and Li ion; thus, no substitution between Ag and Li or Ag and Co atoms occurs, and Ag NPs are located at the interlayer of LiCoO2 while some are left in the fiber.}, number={11}, journal={JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS}, author={Aykut, Yakup and Pourdeyhimi, Behnam and Khan, Saad A.}, year={2013}, month={Nov}, pages={1538–1545} } @article{aykut_parsons_pourdeyhimi_khan_2013, title={Synthesis of Mixed Ceramic MgxZn1–xO Nanofibers via Mg2+ Doping Using Sol–Gel Electrospinning}, volume={29}, ISSN={0743-7463 1520-5827}, url={http://dx.doi.org/10.1021/LA400281C}, DOI={10.1021/la400281c}, abstractNote={We report on the synthesis of tuned energy band gap Mg(x)Zn(1-x)O nanofibers (NFs) with different Mg(2+) content via the sol-gel electrospinning (ES) technique wherein the addition of the doping material affects not only the morphologies of as-spun ZnAc/PVA and MgAc/ZnAc/PVA nanofibers but also the crystal microstructure and optical properties of calcined ZnO and Mg(x)Zn(1-x)O nanofibers. Following an appropriate aqueous solution preparation of magnesium acetate (MgAc) and zinc acetate (ZnAc) with poly(vinyl alcohol) (PVA), electrospinning is performed and then as-spun nanofibers are calcined in an air atmosphere at 600 °C for 3 h. As-spun and calcined nanofiber diameters and morphologies are evaluated with scanning (SEM) and transmission (TEM) electron microscopies, whereas crystalline microstructural interpretations of ZnO and Mg(x)Zn(1-x)O are conducted with wide-angle X-ray diffraction spectra (XRD). Surface chemical composition and elemental evaluation of calcined nanofibers are examined with X-ray photoelectron spectroscopy (XPS), and optical properties and crystal defect analyses of the calcined nanofibers are conducted with photoluminescence spectra (PL). We observe a sharp reduction in fiber diameter upon calcination as a result of the removal of organic species from the fibers and conversion of ceramic precursors into ceramic nanofibers, and the appearance of a range of fiber morphologies from "bead in a string" to "sesame seed" coverage depending on fiber composition. Because Zn(2+) and Mg(2+) have similar ionicity and atomic radii, some Zn(2+) atoms are replaced by Mg(2+) atoms in the crystals, leading to a change in the properties of crystal lattices. The band gap energy of the calcined fibers increases significantly with addition of Mg(2+) along with an increase in the ultraviolet (UV) photoluminescence emission of the fibers.}, number={12}, journal={Langmuir}, publisher={American Chemical Society (ACS)}, author={Aykut, Yakup and Parsons, Gregory N. and Pourdeyhimi, Behnam and Khan, Saad A.}, year={2013}, month={Mar}, pages={4159–4166} } @article{aykut_2012, title={Enhanced field electron emission from electrospun co-loaded activated porous carbon nanofibers}, volume={4}, number={7}, journal={ACS Applied Materials & Interfaces}, author={Aykut, Y.}, year={2012}, pages={3405–3415} } @article{aykut_saquing_pourdeyhimi_parsons_khan_2012, title={Templating Quantum Dot to Phase-Transformed Electrospun TiO2 Nanofibers for Enhanced Photo-Excited Electron Injection}, volume={4}, ISSN={["1944-8252"]}, url={http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000307698600011&KeyUID=WOS:000307698600011}, DOI={10.1021/am300524a}, abstractNote={We report on the microstructural crystal phase transformation of electrospun TiO(2) nanofibers generated via sol-gel electrospinning technique, and the incorporation of as-synthesized CdSe quantum dots (QDs) to different phases of TiO(2) nanofibers (NFs) via bifunctional surface modification. The effect of different phases of TiO(2) on photo-excited electron injection from CdSe QDs to TiO(2) NFs, as measured by photoluminescence spectroscopy (PL) is also discussed. Nanofiber diameter and crystal structures are dramatically affected by different calcination temperatures due to removal of polymer carrier, conversion of ceramic precursor into ceramic nanofibers, and formation of different TiO(2) phases in the fibers. At a low calcination temperature of 400 (o)C only anatase TiO(2) nanofiber are obtained; with increasing calcination temperature (up to 500 (o)C) these anatase crystals became larger. Crystal transformation from the anatase to the rutile phase is observed above 500(o)C, with most of the crystals transforming into the rutile phase at 800(o)C. Bi-functional surface modification of calcined TiO(2) nanofibers with 3-mercaptopropionic acid (3-MPA) is used to incorporate as-synthesized CdSe QD nanoparticles on to TiO(2) nanofibers. Evidence of formation of CdSe/TiO(2) composite nanofibers is obtained from elemental analysis using Energy Dispersive X-ray spectroscopy (EDS) and TEM microscopy that reveal templated quantum dots on TiO(2) nanofibers. Photoluminescence emission intensities increase considerably with the addition of QDs to all TiO(2) nanofiber samples, with fibers containing small amount of rutile crystals with anatase crystals showing the most enhanced effect.}, number={8}, journal={ACS APPLIED MATERIALS & INTERFACES}, author={Aykut, Yakup and Saquing, Carl D. and Pourdeyhimi, Behnam and Parsons, Gregory N. and Khan, Saad A.}, year={2012}, month={Aug}, pages={3837–3845} }