Works (8)

Updated: July 5th, 2023 15:56

2008 journal article

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes

CHEMICAL COMMUNICATIONS, (1), 111–113.

By: C. Munro-Leighton n, S. Delp n, N. Alsop n, E. Blue n & T. Gunnoe n

TL;DR: Monomeric Cu(I) amido and thiolate complexes that are supported by the N-heterocyclic carbene ligand 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) catalyze the hydroamination and hydrothiolation of electron-deficient vinylarenes with reactivity patterns that are consistent with an intermolecular nucleophilic addition. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2007 journal article

Addition of N-H and O-H bonds of amines and alcohols to electron-deficient olefins catalyzed by monomeric copper(I) systems: Reaction scope, mechanistic details, and comparison of catalyst efficiency

ORGANOMETALLICS, 26(6), 1483–1493.

By: C. Munro-Leighton n, S. Delp n, E. Blue n & T. Gunnoe n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Anti-Markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(5), 1446–1447.

By: C. Munro-Leighton n, E. Blue n & T. Gunnoe n

TL;DR: Catalytic activity has been observed for olefins CH2C(H)(X) with X = CN, C(O)Me, or CO2Me as well as crotononitrile. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Chemistry surrounding monomeric copper(I) methyl, phenyl, anilido, ethoxide, and phenoxide complexes supported by N-heterocyclic carbene ligands: Reactivity consistent with both early and late transition metal systems

Inorganic Chemistry, 45(22), 9032–9045.

By: L. Goj n, E. Blue n, S. Delp n, T. Gunnoe n, T. Cundari n, A. Pierpont n, J. Petersen n, P. Boyle n

TL;DR: DFT calculations suggest that the HOMO for the series of Cu anilido complexes is localized primarily on the amido nitrogen with some ppi(anilido)-dpi(Cu) pi-character. (via Semantic Scholar)
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Protonation of N-heterocyclic carbene ligand coordinated to copper(I): Coordination mode of imidazolium cation as a function of counterion as determined by solid-state structures

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691(26), 5988–5993.

author keywords: copper; N-heterocyclic carbene; imidazolium
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2006 journal article

Single-electron oxidation of monomeric copper(I) alkyl complexes: Evidence for reductive elimination through bimolecular formation of Alkanes

ORGANOMETALLICS, 25(17), 4097–4104.

By: L. Goj n, E. Blue n, S. Delp n, T. Gunnoe n, T. Cundari n & J. Petersen n

UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

2005 journal article

Cleavage of X-H bonds (X = N, O, or C) by copper(I) alkyl complexes to form monomeric two-coordinate copper(I) systems

INORGANIC CHEMISTRY, 44(24), 8647–8649.

By: L. Goj n, E. Blue n, C. Munro-Leighton n, T. Gunnoe n & J. Petersen n

TL;DR: Solid-state X-ray crystal structures of the anilido, ethoxide, and phenoxide complexes confirm that they are monomeric systems. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Source: Web Of Science
Added: August 6, 2018

2002 journal article

Synthesis, spectroscopy, and solid-state structural characterization of the hexanuclear copper macrocycle [Cu6Cl6(mu-PCHP)(6)]

Angewandte Chemie [International Edition in English], 41(14), 2571-.

By: E. Blue, T. Gunnoe & N. Brooks

Source: NC State University Libraries
Added: August 6, 2018

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