Works (8)

Updated: July 5th, 2023 15:56

2007 article

Addition of N−H and O−H Bonds of Amines and Alcohols to Electron-Deficient Olefins Catalyzed by Monomeric Copper(I) Systems:  Reaction Scope, Mechanistic Details, and Comparison of Catalyst Efficiency

Munro-Leighton, C., Delp, S. A., Blue, E. D., & Gunnoe, T. B. (2007, February 9). Organometallics.

By: C. Munro-Leighton n, S. Delp n, E. Blue n & T. Gunnoe n

topics (OpenAlex): Asymmetric Hydrogenation and Catalysis; Synthetic Organic Chemistry Methods
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Source: Web Of Science
Added: August 6, 2018

2007 article

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(i) amido and thiolate complexes

Munro-Leighton, C., Delp, S. A., Alsop, N. M., Blue, E. D., & Gunnoe, T. B. (2007, October 24). Chemical Communications.

By: C. Munro-Leighton n, S. Delp n, N. Alsop n, E. Blue n & T. Gunnoe n

topics (OpenAlex): Sulfur-Based Synthesis Techniques; Chemical Synthesis and Reactions
TL;DR: Monomeric Cu(I) amido and thiolate complexes that are supported by the N-heterocyclic carbene ligand 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) catalyze the hydroamination and hydrothiolation of electron-deficient vinylarenes with reactivity patterns that are consistent with an intermolecular nucleophilic addition. (via Semantic Scholar)
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2006 article

Anti-Markovnikov N−H and O−H Additions to Electron-Deficient Olefins Catalyzed by Well-Defined Cu(I) Anilido, Ethoxide, and Phenoxide Systems

Munro-Leighton, C., Blue, E. D., & Gunnoe, T. B. (2006, January 12). Journal of the American Chemical Society.

By: C. Munro-Leighton n, E. Blue n & T. Gunnoe n

topics (OpenAlex): Asymmetric Hydrogenation and Catalysis; Chemical Synthesis and Reactions
TL;DR: Catalytic activity has been observed for olefins CH2C(H)(X) with X = CN, C(O)Me, or CO2Me as well as crotononitrile. (via Semantic Scholar)
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Source: Web Of Science
Added: August 6, 2018

2006 article

Chemistry Surrounding Monomeric Copper(I) Methyl, Phenyl, Anilido, Ethoxide, and Phenoxide Complexes Supported by N-Heterocyclic Carbene Ligands:  Reactivity Consistent with Both Early and Late Transition Metal Systems

Goj, L. A., Blue, E. D., Delp, S. A., Gunnoe, T. B., Cundari, T. R., Pierpont, A. W., … Boyle, P. D. (2006, September 27). Inorganic Chemistry.

By: L. Goj n, E. Blue n, S. Delp n, T. Gunnoe n, T. Cundari n, A. Pierpont n, J. Petersen n, P. Boyle n

topics (OpenAlex): N-Heterocyclic Carbenes in Organic and Inorganic Chemistry; Catalytic Cross-Coupling Reactions; Asymmetric Hydrogenation and Catalysis
TL;DR: DFT calculations suggest that the HOMO for the series of Cu anilido complexes is localized primarily on the amido nitrogen with some ppi(anilido)-dpi(Cu) pi-character. (via Semantic Scholar)
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Source: NC State University Libraries
Added: August 6, 2018

2006 article

Protonation of N-heterocyclic carbene ligand coordinated to copper(I): Coordination mode of imidazolium cation as a function of counterion as determined by solid-state structures

Blue, E. D., Gunnoe, T. B., Petersen, J. L., & Boyle, P. D. (2006, October 2). Journal of Organometallic Chemistry.

By: E. Blue n, T. Gunnoe n, J. Petersen* & P. Boyle n

author keywords: copper; N-heterocyclic carbene; imidazolium
topics (OpenAlex): N-Heterocyclic Carbenes in Organic and Inorganic Chemistry; Synthetic Organic Chemistry Methods; Catalytic Cross-Coupling Reactions
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Source: Web Of Science
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2006 article

Single-Electron Oxidation of Monomeric Copper(I) Alkyl Complexes:  Evidence for Reductive Elimination through Bimolecular Formation of Alkanes

Goj, L. A., Blue, E. D., Delp, S. A., Gunnoe, T. B., Cundari, T. R., & Petersen, J. L. (2006, July 21). Organometallics.

topics (OpenAlex): Organometallic Complex Synthesis and Catalysis; N-Heterocyclic Carbenes in Organic and Inorganic Chemistry; Asymmetric Hydrogenation and Catalysis
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Source: Web Of Science
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2005 article

Cleavage of X−H Bonds (X = N, O, or C) by Copper(I) Alkyl Complexes To Form Monomeric Two-Coordinate Copper(I) Systems

Goj, L. A., Blue, E. D., Munro-Leighton, C., Gunnoe, T. B., & Petersen, J. L. (2005, November 1). Inorganic Chemistry.

topics (OpenAlex): Cyclopropane Reaction Mechanisms; N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
TL;DR: Solid-state X-ray crystal structures of the anilido, ethoxide, and phenoxide complexes confirm that they are monomeric systems. (via Semantic Scholar)
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Source: Web Of Science
Added: August 6, 2018

2002 journal article

Synthesis, spectroscopy, and solid-state structural characterization of the hexanuclear copper macrocycle [Cu6Cl6(mu-PCHP)(6)]

Angewandte Chemie [International Edition in English], 41(14), 2571-.

By: E. Blue, T. Gunnoe & N. Brooks

Source: NC State University Libraries
Added: August 6, 2018

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