Matthew Jarrod Truitt

Works (4)

Updated: July 5th, 2023 15:58

2008 journal article

In-situ NMR studies of isobutane activation and exchange in zeolite beta

SOLID STATE NUCLEAR MAGNETIC RESONANCE, 35(2), 100–103.

By: M. Truitt n & J. White*

author keywords: Isobutane; Alkane activation; C-H bond activation; In-situ NMR; Catalysis; Zeolite; Mechanism
MeSH headings : Butanes / analysis; Butanes / chemistry; Computer Simulation; Magnetic Resonance Spectroscopy / methods; Models, Chemical; Models, Molecular; Molecular Conformation; Zeolites / analysis; Zeolites / chemistry
TL;DR: Estimation of true activation energies using heat of adsorption data from the literature combined with the experimentally measured apparent E(a) suggests that the true activation barrier differs by only 6-7kJ/mole in the two catalysts. (via Semantic Scholar)
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Source: Web Of Science
Added: August 6, 2018

2007 review

Heterogeneous catalysis in solid acids

[Review of ]. Progress in Nuclear Magnetic Resonance Spectroscopy, 51(2), 139–154.

By: J. White & M. Truitt

Source: NC State University Libraries
Added: August 6, 2018

2006 journal article

Weak hydrogen bonding can initiate alkane C-H bond activation in acidic zeolites

JOURNAL OF PHYSICAL CHEMISTRY B, 110(42), 20762–20764.

By: L. Sremaniak n, J. Whitten n , M. Truitt n & J. White n

TL;DR: The mechanism described in this contribution demonstrates that weak C-H to O hydrogen bonding leads to complexes at the zeolite acid site that can facilitate C- H bond activation. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2004 journal article

Identification of an adsorption complex between an alkane and zeolite active sites

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 126(36), 11144–11145.

By: M. Truitt n, S. Toporek n, R. Rovira-Hernandez n, K. Hatcher n & J. White n

TL;DR: Direct observation of the Bronsted acid site signal in an active zeolite catalyst following adsorption of stoichiometric quantities of isobutane reveals the presence of a specific Adsorption complex, proposed as a route to C-H bond activation in solid acids. (via Semantic Scholar)
UN Sustainable Development Goals Color Wheel
UN Sustainable Development Goal Categories
6. Clean Water and Sanitation (OpenAlex)
Source: Web Of Science
Added: August 6, 2018

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