2008 article

A Bipodal-Tethered Porphyrin for Attachment to Silicon Surfaces in Studies of Molecular Information Storage

Schmidt, I., Jiao, J., Bocian, D. F., & Lindsey, J. S. (2008, September). JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, Vol. 8, pp. 4813–4817.

By: I. Schmidt n, J. Jiao, D. Bocian & J. Lindsey*

author keywords: Porphyrin; Bipod; Silicon; Memory; DRAM
MeSH headings : Amino Acid Motifs; Electrochemistry / methods; Electronics; Information Storage and Retrieval; Materials Testing; Models, Chemical; Nanotechnology / methods; Oxidation-Reduction; Porphyrins / chemistry; Pyrroles / chemistry; Semiconductors; Silicon / chemistry; Software
TL;DR: The observation that the bipodal anchor does not provide enhanced stability is surprising given that attachment is achieved via two versus one covalent linkage. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2008 journal article

Comparison of Electron-Transfer Rates for Metal- versus Ring-Centered Redox Processes of Porphyrins in Monolayers on Au(111)

LANGMUIR, 24(20), 12047–12053.

By: J. Jiao n, I. Schmidt n, M. Taniguchi n, J. Lindsey n & D. Bocian n

Contributors: J. Jiao n, I. Schmidt n, M. Taniguchi n, J. Lindsey n & D. Bocian n

TL;DR: The faster rates for the ring- versus metal-centered redox process are attributed to the participating molecular orbitals and their proximity to the surface (given that the porphyrins are relatively upright on the surface): a pi molecular orbital that has significant electron density at the meso-carbon atoms. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2008 journal article

Comprehensive characterization of hybrid junctions comprised of a porphyrin monolayer sandwiched between a coinage metal overlayer and a Si(100) substrate

JOURNAL OF PHYSICAL CHEMISTRY C, 112(25), 9474–9485.

Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2008 journal article

Metal-molecule interactions upon deposition of copper overlayers on reactively functionalized porphyrin monolayers on Si(100)

LANGMUIR, 24(13), 6698–6704.

By: F. Anariba n, L. Schmidt n, A. Muresan n, J. Lindsey n & D. Bocian n

TL;DR: Porphyrin monolayers are amenable to direct deposition of Cu overlayers and that functionalization of the porphyrins can be used to mediate the attributes of the metal-molecule junction. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2007 journal article

Characterization of porphyrin surface orientation in monolayers on au(111) and si(100) using spectroscopically labeled molecules

JOURNAL OF PHYSICAL CHEMISTRY C, 111(34), 12693–12704.

By: J. Jiao n, P. Thamyongkit n, I. Schmidt n, J. Lindsey n & D. Bocian n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2007 journal article

Synthesis and photophysical characterization of porphyrin, chlorin and bacteriochlorin molecules bearing tethers for surface attachment

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 83(6), 1513–1528.

By: C. Muthiah n, M. Taniguchi n, H. Kim n, I. Schmidt n, H. Kee*, D. Holten*, D. Bocian*, J. Lindsey n

Contributors: C. Muthiah n, M. Taniguchi n, H. Kim n, I. Schmidt n, H. Kee*, D. Holten*, D. Bocian*, J. Lindsey n

MeSH headings : Molecular Structure; Photochemistry; Porphyrins / chemical synthesis; Porphyrins / chemistry; Spectrophotometry; Surface Properties
TL;DR: The synthesis and characterization of the tetrapyrrole compounds underpin their use as sensitizers in molecular‐based solar cells and hold promise for diverse studies in artificial photosynthesis. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, ORCID
Added: August 6, 2018

2007 journal article

Synthesis of porphyrins for metal deposition studies in molecular information storage applications

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 11(10), 699–712.

By: O. Kulikov n, I. Schmidt n, A. Muresan n, M. Lee n, D. Bocian* & J. Lindsey n

author keywords: molecular electronics; surface; dipyrrin; tripod; thiol
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2006 journal article

Diverse porphyrin dimers as candidates for high-density charge-storage molecules

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 10(1), 22–32.

author keywords: memory; information storage; redox active; capacitor; porphyrin; dimer
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2006 journal article

Investigation of stepwise covalent synthesis on a surface yielding porphyrin-based multicomponent architectures

JOURNAL OF ORGANIC CHEMISTRY, 71(8), 3033–3050.

TL;DR: The ability to prepare covalently linked constructs on a surface without protecting groups in a stepwise manner augurs well for the systematic preparation of a wide variety of functional molecular devices. (via Semantic Scholar)
UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2006 journal article

Stepwise formation and characterization of covalently linked multiporphyrin-imide architectures on Si(100)

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(21), 6965–6974.

TL;DR: These studies demonstrate that high charge density, ultrathin, multiporphyrin films of relatively well-controlled thickness can be grown in a stepwise fashion using the imide-forming reaction, and may prove important for the fabrication of molecular-based information-storage devices. (via Semantic Scholar)
Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2005 journal article

Synthesis and Film-Forming Properties of Ethynylporphyrins

Chemistry of Materials, 17(14), 3728–3742.

By: Z. Liu n, I. Schmidt n, P. Thamyongkit n, R. Loewe n, D. Syomin n, J. Diers n, Q. Zhao n, V. Misra n, J. Lindsey n, D. Bocian n

UN Sustainable Development Goal Categories
Sources: Web Of Science, NC State University Libraries, Crossref
Added: August 6, 2018

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