@article{hussain_liu_roberts_2012, title={Synthesis of cross-linked, partially neutralized poly(acrylic acid) by suspension polymerization in supercritical carbon dioxide}, volume={51}, number={35}, journal={Industrial & Engineering Chemistry Research}, author={Hussain, Y. A. and Liu, T. and Roberts, G. W.}, year={2012}, pages={11401–11408} } @article{carla_hussain_grant_sarti_carbonell_doghieri_2009, title={Modeling Sorption Kinetics of Carbon Dioxide in Glassy Polymeric Films Using the Nonequilibrium Thermodynamics Approach}, volume={48}, ISSN={["0888-5885"]}, DOI={10.1021/ie800655w}, abstractNote={The nonequilibrium thermodynamics of glassy polymers (NET-GP) approach (Macromolecules 2005, 38, 10299.) has been applied to the development of a one-dimensional transport model aimed at describing the kinetics of sorption and dilation of polymeric films in supercritical carbon dioxide. The NET-GP model was combined with a simple rheological constitutive equation to build a sorption-diffusion-relaxation model able to describe mass uptake and swelling kinetics of polymeric films in contact with carbon dioxide over a wide range of pressures and temperatures. The model calculations are compared with data on mass sorption kinetics for CO2 in supported glassy poly(methyl methacrylate) (PMMA) films, measured in a high-pressure quartz crystal microbalance (QCM).}, number={8}, journal={INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, author={Carla, Vito and Hussain, Yazan and Grant, Christine and Sarti, Giulio C. and Carbonell, Ruben G. and Doghieri, Ferruccio}, year={2009}, month={Apr}, pages={3844–3854} } @article{hussain_wu_ampaw_grant_2007, title={Dissolution of polymer films in supercritical carbon dioxide using a quartz crystal microbalance}, volume={42}, ISSN={["1872-8162"]}, DOI={10.1016/j.supflu.2007.03.011}, abstractNote={Abstract The dissolution kinetics of polymeric materials in CO 2 is crucial to the understanding, design and control of CO 2 -based environmentally benign lithography processes. This study utilizes the quartz crystal microbalance (QCM) to monitor and evaluate the dissolution of poly(1,1-dihydroperfluorooctyl methacrylate- r -2-tetrahydropyranyl methacrylate), poly(FOMA- r -THPMA), polymer films in supercritical CO 2 over a range of temperatures and pressures. Polymer dissolution rates at the range of pressures studied were evaluated to quantify the dissolution kinetics for the polymer. The experiments revealed that the polymer dissolution in supercritical CO 2 undergoes two apparent processes: a rapid absorption of CO 2 into the polymer film followed by a gradual dissolution of polymer film into the CO 2 at the polymer–CO 2 interface. The nature of these interfacial phenomena and their associated effect on the rate are discussed.}, number={2}, journal={JOURNAL OF SUPERCRITICAL FLUIDS}, author={Hussain, Yazan and Wu, You-Ting and Ampaw, Paa-Joe and Grant, Christine S.}, year={2007}, month={Sep}, pages={255–264} } @article{carla_wang_hussain_efimenko_genzer_grant_sarti_carbonell_doghieri_2005, title={Nonequilibrium model for sorption and swelling of bulk glassy polymer films with Supercritical carbon dioxide}, volume={38}, ISSN={["1520-5835"]}, DOI={10.1021/ma0506684}, abstractNote={A new procedure is introduced for the calculation of solubility isotherms of plasticizing agents in glassy polymer matrices with particular application to the case of absorption of supercritical gases in bulk glassy polymer films. The model presented is an extension of the nonequilibrium thermodynamics for glassy polymers (NET-GP) approach, modified to allow for the calculation of the effects of pressure, temperature, and gas concentration on the glass transition. Mass sorption and one- dimensional swelling behavior are analyzed for the carbon dioxide (CO2)-poly(methyl methacrylate) (PMMA) system at high pressure. A quantitative comparison is presented between the model performance and experimental data measured using quartz crystal microbalance (QCM) and high-pressure ellipsometry (HPE).}, number={24}, journal={MACROMOLECULES}, author={Carla, V and Wang, K and Hussain, Y and Efimenko, K and Genzer, J and Grant, C and Sarti, GC and Carbonell, RG and Doghieri, F}, year={2005}, month={Nov}, pages={10299–10313} } @article{hussain_krim_grant_2005, title={OTS adsorption: A dynamic QCM study}, volume={262}, ISSN={["1873-4359"]}, url={http://www.scopus.com/inward/record.url?eid=2-s2.0-22144447874&partnerID=MN8TOARS}, DOI={10.1016/j.colsurfa.2005.03.016}, abstractNote={The uptake of octadecyltrichlorosilane (OTS) from an organic solution has been studied in situ and in real time by means of a quartz crystal microbalance (QCM) technique. Changes in both QCM frequency and resistance are reported for a range of OTS concentrations. In addition, the time dependence of OTS uptake has been used to calculate reaction constants. Silicon surfaces overall are characterized by higher levels of material uptake than gold.}, number={1-3}, journal={COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS}, author={Hussain, Y and Krim, J and Grant, C}, year={2005}, month={Jul}, pages={81–86} }