Colleen Munro-Leighton

Works (9)

Updated: July 5th, 2023 15:56

2011 article

Pt(II) and Pt(IV) Amido, Aryloxide, and Hydrocarbyl Complexes: Synthesis, Characterization, and Reaction with Dihydrogen and Substrates that Possess C−H Bonds

Webb, J. R., Munro-Leighton, C., Pierpont, A. W., Gurkin, J. T., Gunnoe, T. B., Cundari, T. R., … Boyle, P. D. (2011, March 28). Inorganic Chemistry.

By: J. Webb*, C. Munro-Leighton n, A. Pierpont*, J. Gurkin n, T. Gunnoe *, T. Cundari *, M. Sabat*, J. Petersen *, P. Boyle n

topics (OpenAlex): Organometallic Complex Synthesis and Catalysis; Asymmetric Hydrogenation and Catalysis; Catalytic Cross-Coupling Reactions
TL;DR: Kinetic studies indicate that the reaction of ((t)bpy)Pt(Me)(NHPh) and phenylacetylene occurs via a pathway that involves [TFA] as a catalyst, and solid-state X-ray diffraction studies of the Pt(IV) complexes reveal that 1,2-addition of dihydrogen across the Pt-NHPh bond is revealed. (via Semantic Scholar)
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Source: Web Of Science
Added: August 6, 2018

2010 article

Net Hydrogenation of Pt−NHPh Bond Is Catalyzed by Elemental Pt

Webb, J. R., Pierpont, A. W., Munro-Leighton, C., Gunnoe, T. B., Cundari, T. R., & Boyle, P. D. (2010, March 11). Journal of the American Chemical Society.

By: J. Webb n, A. Pierpont n, C. Munro-Leighton n, T. Gunnoe  n, T. Cundari  n & P. Boyle n

MeSH headings : Catalysis; Hydrogen / chemistry; Hydrogenation; Models, Molecular; Molecular Structure; Organoplatinum Compounds / chemistry; Platinum / chemistry; Time Factors
topics (OpenAlex): Asymmetric Hydrogenation and Catalysis; Ammonia Synthesis and Nitrogen Reduction; Carbon dioxide utilization in catalysis
TL;DR: Mechanistic studies reveal that 1,2-addition of dihydrogen across the Pt-anilido bond to initially produce ((t)bpy)Pt(Me)(H) and free aniline is catalyzed by elemental Pt rather than through a pathway that involves direct activation of H(2) by Pt and 1, 2-add addition acrossThe Pt-NHPh bond. (via Semantic Scholar)
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Added: August 6, 2018

2010 article

Well-Defined Copper(I) Amido Complex and Aryl Iodides Reacting to Form Aryl Amines

Delp, S. A., Goj, L. A., Pouy, M. J., Munro-Leighton, C., Lee, J. P., Gunnoe, T. B., … Petersen, J. L. (2010, December 6). Organometallics, Vol. 30, pp. 55–57.

By: S. Delp n, L. Goj n, M. Pouy*, C. Munro-Leighton n, J. Lee n , T. Gunnoe*, T. Cundari *, J. Petersen *

topics (OpenAlex): Oxidative Organic Chemistry Reactions; Catalytic Cross-Coupling Reactions
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Sources: Web Of Science, NC State University Libraries
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2008 article

Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex

Colleen Munro-Leighton; Yuee Feng; Jubo Zhang; Nikki Marie Alsop; Thomas Gunnoe; Paul D. Boyle

topics (OpenAlex):
Source: NC State University Libraries
Added: August 6, 2018

2007 article

Addition of N−H and O−H Bonds of Amines and Alcohols to Electron-Deficient Olefins Catalyzed by Monomeric Copper(I) Systems:  Reaction Scope, Mechanistic Details, and Comparison of Catalyst Efficiency

Munro-Leighton, C., Delp, S. A., Blue, E. D., & Gunnoe, T. B. (2007, February 9). Organometallics.

By: C. Munro-Leighton n, S. Delp n, E. Blue n & T. Gunnoe n

topics (OpenAlex): Asymmetric Hydrogenation and Catalysis; Synthetic Organic Chemistry Methods
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2007 article

Addition of S−H Bonds across Electron-Deficient Olefins Catalyzed by Well-Defined Copper(I) Thiolate Complexes

Delp, S. A., Munro-Leighton, C., Goj, L. A., Ramírez, M. A., Gunnoe, T. B., Petersen, J. L., & Boyle, P. D. (2007, March 6). Inorganic Chemistry.

By: S. Delp n, C. Munro-Leighton n, L. Goj n, M. Ramírez n, T. Gunnoe n, J. Petersen  n, P. Boyle n

MeSH headings : Alkenes / chemistry; Catalysis; Copper / chemistry; Electrons; Hydrogen / chemistry; Ligands; Models, Molecular; Molecular Conformation; Sulfhydryl Compounds / chemistry; Sulfur / chemistry
topics (OpenAlex): N-Heterocyclic Carbenes in Organic and Inorganic Chemistry; Catalytic Cross-Coupling Reactions
TL;DR: A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. (via Semantic Scholar)
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2007 article

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(i) amido and thiolate complexes

Munro-Leighton, C., Delp, S. A., Alsop, N. M., Blue, E. D., & Gunnoe, T. B. (2007, October 24). Chemical Communications.

By: C. Munro-Leighton n, S. Delp n, N. Alsop n, E. Blue n & T. Gunnoe n

topics (OpenAlex): Sulfur-Based Synthesis Techniques; Chemical Synthesis and Reactions
TL;DR: Monomeric Cu(I) amido and thiolate complexes that are supported by the N-heterocyclic carbene ligand 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) catalyze the hydroamination and hydrothiolation of electron-deficient vinylarenes with reactivity patterns that are consistent with an intermolecular nucleophilic addition. (via Semantic Scholar)
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2006 article

Anti-Markovnikov N−H and O−H Additions to Electron-Deficient Olefins Catalyzed by Well-Defined Cu(I) Anilido, Ethoxide, and Phenoxide Systems

Munro-Leighton, C., Blue, E. D., & Gunnoe, T. B. (2006, January 12). Journal of the American Chemical Society.

By: C. Munro-Leighton n, E. Blue n & T. Gunnoe n

topics (OpenAlex): Asymmetric Hydrogenation and Catalysis; Chemical Synthesis and Reactions
TL;DR: Catalytic activity has been observed for olefins CH2C(H)(X) with X = CN, C(O)Me, or CO2Me as well as crotononitrile. (via Semantic Scholar)
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2005 article

Cleavage of X−H Bonds (X = N, O, or C) by Copper(I) Alkyl Complexes To Form Monomeric Two-Coordinate Copper(I) Systems

Goj, L. A., Blue, E. D., Munro-Leighton, C., Gunnoe, T. B., & Petersen, J. L. (2005, November 1). Inorganic Chemistry.

By: L. Goj n, E. Blue n, C. Munro-Leighton n, T. Gunnoe n & J. Petersen  n

topics (OpenAlex): Cyclopropane Reaction Mechanisms; N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
TL;DR: Solid-state X-ray crystal structures of the anilido, ethoxide, and phenoxide complexes confirm that they are monomeric systems. (via Semantic Scholar)
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