Colleen Munro-Leighton

Works (9)

Updated: July 5th, 2023 15:56

2011 journal article

Pt(II) and Pt(IV) Amido, Aryloxide, and Hydrocarbyl Complexes: Synthesis, Characterization, and Reaction with Dihydrogen and Substrates that Possess C-H Bonds

INORGANIC CHEMISTRY, 50(9), 4195–4211.

By: J. Webb*, C. Munro-Leighton n, A. Pierpont*, J. Gurkin n, T. Gunnoe *, T. Cundari *, M. Sabat*, J. Petersen *, P. Boyle n

TL;DR: Kinetic studies indicate that the reaction of ((t)bpy)Pt(Me)(NHPh) and phenylacetylene occurs via a pathway that involves [TFA] as a catalyst, and solid-state X-ray diffraction studies of the Pt(IV) complexes reveal that 1,2-addition of dihydrogen across the Pt-NHPh bond is revealed. (via Semantic Scholar)
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Added: August 6, 2018

2010 journal article

Net Hydrogenation of Pt-NHPh Bond Is Catalyzed by Elemental Pt

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(13), 4520-+.

By: J. Webb n, A. Pierpont n, C. Munro-Leighton n, T. Gunnoe  n, T. Cundari  n & P. Boyle n

MeSH headings : Catalysis; Hydrogen / chemistry; Hydrogenation; Models, Molecular; Molecular Structure; Organoplatinum Compounds / chemistry; Platinum / chemistry; Time Factors
TL;DR: Mechanistic studies reveal that 1,2-addition of dihydrogen across the Pt-anilido bond to initially produce ((t)bpy)Pt(Me)(H) and free aniline is catalyzed by elemental Pt rather than through a pathway that involves direct activation of H(2) by Pt and 1, 2-add addition acrossThe Pt-NHPh bond. (via Semantic Scholar)
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2010 journal article

Well-Defined Copper(I) Amido Complex and Aryl Iodides Reacting to Form Aryl Amines

ORGANOMETALLICS, 30(1), 55–57.

By: S. Delp n, L. Goj n, M. Pouy*, C. Munro-Leighton n, J. Lee n , T. Gunnoe *, T. Cundari *, J. Petersen *

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Sources: Web Of Science, NC State University Libraries
Added: August 6, 2018

2008 journal article

Preparation and reactivity of a monomeric octahedral platinum(IV) amido complex

Inorganic Chemistry, 47(14), 6124–6126.

By: C. Munro-Leighton, Y. Feng, J. Zhang, N. Alsop, T. Gunnoe, P. Boyle, J. Petersen

Source: NC State University Libraries
Added: August 6, 2018

2007 journal article

Addition of N-H and O-H bonds of amines and alcohols to electron-deficient olefins catalyzed by monomeric copper(I) systems: Reaction scope, mechanistic details, and comparison of catalyst efficiency

ORGANOMETALLICS, 26(6), 1483–1493.

By: C. Munro-Leighton n, S. Delp n, E. Blue n & T. Gunnoe  n

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2007 journal article

Addition of s-h bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes

INORGANIC CHEMISTRY, 46(7), 2365–2367.

By: S. Delp n, C. Munro-Leighton n, L. Goj n, M. Ramirez n, T. Gunnoe  n, J. Petersen  n, P. Boyle n

MeSH headings : Alkenes / chemistry; Catalysis; Copper / chemistry; Electrons; Hydrogen / chemistry; Ligands; Models, Molecular; Molecular Conformation; Sulfhydryl Compounds / chemistry; Sulfur / chemistry
TL;DR: A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. (via Semantic Scholar)
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2007 journal article

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes

CHEMICAL COMMUNICATIONS, (1), 111–113.

By: C. Munro-Leighton n, S. Delp n, N. Alsop n, E. Blue n & T. Gunnoe  n

TL;DR: Monomeric Cu(I) amido and thiolate complexes that are supported by the N-heterocyclic carbene ligand 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) catalyze the hydroamination and hydrothiolation of electron-deficient vinylarenes with reactivity patterns that are consistent with an intermolecular nucleophilic addition. (via Semantic Scholar)
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2006 journal article

Anti-Markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128(5), 1446–1447.

By: C. Munro-Leighton n, E. Blue n & T. Gunnoe n

TL;DR: Catalytic activity has been observed for olefins CH2C(H)(X) with X = CN, C(O)Me, or CO2Me as well as crotononitrile. (via Semantic Scholar)
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2005 journal article

Cleavage of X-H bonds (X = N, O, or C) by copper(I) alkyl complexes to form monomeric two-coordinate copper(I) systems

INORGANIC CHEMISTRY, 44(24), 8647–8649.

By: L. Goj n, E. Blue n, C. Munro-Leighton n, T. Gunnoe n & J. Petersen  n

TL;DR: Solid-state X-ray crystal structures of the anilido, ethoxide, and phenoxide complexes confirm that they are monomeric systems. (via Semantic Scholar)
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